Mechanistic Insight into Charge and Energy Transfers of Luminescent Metal–Organic Frameworks Based Sensors for Toxic Chemicals

2021 ◽  
pp. 2000293
Author(s):  
Brij Mohan ◽  
Sandeep Kumar ◽  
Shixuan Ma ◽  
Hengzhi You ◽  
Peng Ren
Keyword(s):  
Metal Organic Frameworks ◽  
Toxic Chemicals ◽  
Mechanistic Insight ◽  
Energy Transfers ◽  
Metal Organic ◽  
Insight Into

scholarly journals Mechanistic insight into the sensing of nitroaromatic compounds by metal-organic frameworks

2019 ◽  
Vol 2 (1) ◽  
Author(s):  
Amitosh Sharma ◽  
Dongwook Kim ◽  
Jae-Heon Park ◽  
Surajit Rakshit ◽  
Junmo Seong ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Nitroaromatic Compounds ◽  
Mechanistic Insight ◽  
Metal Organic ◽  
Insight Into

Quantum Mechanical Interpretation of the Ultra-Low Energy Methyl-Rotation Dynamics in Porous Metal-Organic Frameworks Probed by Low-Frequency Vibrational Spectroscopy and ab initio Simulations

2018 ◽  
Author(s):  
Qi Li ◽  
Adam J. Zaczek ◽  
Timothy M. Korter ◽  
J. Axel Zeitler ◽  
Michael T. Ruggiero
Keyword(s):  
Ab Initio ◽  
Metal Organic Frameworks ◽  
Low Frequency ◽  
Rotor Dynamics ◽  
Quantum Mechanical ◽  
Valuable Insight ◽  
Void Space ◽  
Ab Initio Simulations ◽  
Metal Organic ◽  
Insight Into

<div>Understanding the nature of the interatomic interactions present within the pores of metal-organic frameworks</div><div>is critical in order to design and utilize advanced materials</div><div>with desirable applications. In ZIF-8 and its cobalt analogue</div><div>ZIF-67, the imidazolate methyl-groups, which point directly</div><div>into the void space, have been shown to freely rotate - even</div><div>down to cryogenic temperatures. Using a combination of ex-</div><div>perimental terahertz time-domain spectroscopy, low-frequency</div><div>Raman spectroscopy, and state-of-the-art ab initio simulations,</div><div>the methyl-rotor dynamics in ZIF-8 and ZIF-67 are fully charac-</div><div>terized within the context of a quantum-mechanical hindered-</div><div>rotor model. The results lend insight into the fundamental</div><div>origins of the experimentally observed methyl-rotor dynamics,</div><div>and provide valuable insight into the nature of the weak inter-</div><div>actions present within this important class of materials.</div>

Insight into the Unique Fluorescence Quenching Property of Metal-Organic Frameworks upon DNA Binding

2017 ◽  
Vol 89 (21) ◽  
pp. 11366-11371 ◽  
Author(s):  
Huai-Song Wang ◽  
Hai-Ling Liu ◽  
Kang Wang ◽  
Ya Ding ◽  
Jing-Juan Xu ◽  
...  
Keyword(s):  
Dna Binding ◽  
Fluorescence Quenching ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Insight Into

New Mechanistic Insight into Stepwise Metal-Center Exchange in a Metal-Organic Framework Based on Asymmetric Zn4Clusters

2014 ◽  
Vol 20 (10) ◽  
pp. 2945-2952 ◽  
Author(s):  
Wei Meng ◽  
Huijun Li ◽  
Zhouqing Xu ◽  
Shanshan Du ◽  
Yunxia Li ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Metal Center ◽  
Mechanistic Insight ◽  
Metal Organic ◽  
Insight Into ◽  
Organic Framework

Insight into the Role and Strategies of Metal–Organic Frameworks in Direct Methanol Fuel Cells: A Review

2021 ◽  
Author(s):  
Srikanth Ponnada ◽  
Maryam Sadat Kiai ◽  
Demudu Babu Gorle ◽  
Annapurna Nowduri ◽  
Rakesh K. Sharma
Keyword(s):  
Fuel Cells ◽  
Direct Methanol Fuel Cells ◽  
Metal Organic Frameworks ◽  
Direct Methanol ◽  
Metal Organic ◽  
Methanol Fuel Cells ◽  
Insight Into

Structural Diversity of Zirconium Metal–Organic Frameworks and Effect on Adsorption of Toxic Chemicals

2020 ◽  
Vol 142 (51) ◽  
pp. 21428-21438
Author(s):  
Yongwei Chen ◽  
Xuan Zhang ◽  
Mohammad Rasel Mian ◽  
Florencia A. Son ◽  
Kun Zhang ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Structural Diversity ◽  
Toxic Chemicals ◽  
Metal Organic ◽  
Zirconium Metal

scholarly journals Synthetic investigation of competing magnetic interactions in 2D metal–chloranilate radical frameworks

2020 ◽  
Vol 11 (23) ◽  
pp. 5922-5928 ◽  
Author(s):  
Kelsey A. Collins ◽  
Richard J. Saballos ◽  
Majed S. Fataftah ◽  
Danilo Puggioni ◽  
James M. Rondinelli ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Magnetic Interactions ◽  
Spin Physics ◽  
Metal Organic ◽  
Synthetic Investigation ◽  
Insight Into

2D metal–organic frameworks provide insight into kagomé spin physics.

Insight into the catalytic properties and applications of metal–organic frameworks in the cyanosilylation of aldehydes

RSC Advances ◽  
2015 ◽  
Vol 5 (97) ◽  
pp. 79355-79360 ◽  
Author(s):  
Zhiguo Zhang ◽  
Jingwen Chen ◽  
Zongbi Bao ◽  
Ganggang Chang ◽  
Huabin Xing ◽  
...  
Keyword(s):  
Catalytic Properties ◽  
Metal Organic Frameworks ◽  
Systematic Investigation ◽  
Metal Organic ◽  
Insight Into

This paper presents a systematic investigation of the cyanosilylation of aldehydes with TMSCN by using several MOFs as catalysts.

Structural Insight into Binary Protein Metal–Organic Frameworks with Ferritin Nanocages as Linkers and Nickel Clusters as Nodes

2020 ◽  
Vol 26 (14) ◽  
pp. 3016-3021 ◽  
Author(s):  
Chunkai Gu ◽  
Hai Chen ◽  
Yingjie Wang ◽  
Tuo Zhang ◽  
Hongfei Wang ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Nickel Clusters ◽  
Metal Organic ◽  
Structural Insight ◽  
Insight Into
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