ChemInform Abstract: UNSATURATED COMPOUNDS OF THE MAIN GROUP ELEMENTS- THE MOLECULAR STRUCTURE OF THE REACTION PRODUCT OF 1,3-CYCLOOCTADIENE WITH TRIMETHYLALUMINUM AND POTASSIUM

1978 ◽  
Vol 9 (48) ◽  
Author(s):  
A. M. MCPHERSON ◽  
G. STUCKY ◽  
H. LEHMKUHL
Keyword(s):  
Molecular Structure ◽  
Main Group ◽  
Main Group Elements ◽  
Unsaturated Compounds

Mehrfachbindungen zwischen Hauptgruppenelementen und Übergangsmetallen, LXXXIX / Multiple Bonds between Main Group Elements and Transition Metals, LXXXIX

1991 ◽  
Vol 46 (6) ◽  
pp. 747-752 ◽  
Author(s):  
Wolfgang A. Herrmann ◽  
Dieter W. Marz ◽  
Eberhardt Herdtweck
Keyword(s):  
Molecular Structure ◽  
Transition Metals ◽  
Single Crystal ◽  
Main Group ◽  
X Ray Diffraction ◽  
Multiple Bonds ◽  
Main Group Elements ◽  
X Ray ◽  
Clean Synthesis

Reaction of (N-trimethylsilyl)-α-aminopicolin with the rhenium(V) oxohalogenide (η5-C5Me5)ReOCl2 (Me = CH3) exemplifies a simple, clean synthesis of imido-metallosiloxanes, compounds of the structure R3SiO—M=N—R′. The compound (η5-C5Me5)ReCl[OSi(CH3)3](NCH2-2-C5H4N) thus formed under HCl elimination has a square-pyramidal molecular structure (single crystal X-ray diffraction).

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