ChemInform Abstract: Electrochemical Reduction of the Antitumor Anthrapyrazole CI-941: Mechanism of Formation and Isolation of the Leuco Form.

ChemInform ◽  
1990 ◽  
Vol 21 (13) ◽  
Author(s):  
A. ANNE ◽  
J. MOIROUX
Keyword(s):  
Electrochemical Reduction ◽  
Mechanism Of Formation ◽  
Leuco Form

In Situ X-Ray Absorption Studies of the Electrochemical Reduction of Hydroxocobalamin

1997 ◽  
Vol 7 (C2) ◽  
pp. C2-619-C2-620 ◽  
Author(s):  
M. Giorgett ◽  
I. Ascone ◽  
M. Berrettoni ◽  
S. Zamponi ◽  
R. Marassi
Keyword(s):  
Electrochemical Reduction ◽  
X Ray ◽  
Absorption Studies ◽  
X Ray Absorption

Regarding the mechanism of formation of nonmetallic inclusions conglomerates of system Al2O3-MgO

2019 ◽  
Vol 75 (12) ◽  
pp. 1341-1351
Author(s):  
A. A. Safronov ◽  
V. S. Dub ◽  
V. V. Orlov ◽  
K. L. Kosyrev ◽  
A. S. Loskutov ◽  
...  
Keyword(s):  
Nonmetallic Inclusions ◽  
Mechanism Of Formation

Assessment of ability to varnish turbine oils

2020 ◽  
Vol 06 ◽  
pp. 28-33
Author(s):  
I.V. Mitin ◽  
◽  
I.R. Tatur ◽  
K.U. Smirnov ◽  
A.M. Suloev ◽  
...  
Keyword(s):  
Antioxidant Properties ◽  
Mechanism Of Formation ◽  
Critical Situation ◽  
Antioxidant Content ◽  
Turbine Equipment

The reasons for the formation of varnish deposits of turbine oils are determined. It is shown that the performance of turbine oils is determined by methods of ASTM D7843 (MPC) and ASTM D6971 (RUL) can be assessed, the process of formation of varnish deposits, the level of antioxidant properties, antioxidant content of, amend, and extend the oil change, and to predict critical situation in the operation of turbine equipment. The mechanism of formation of varnish deposits in turbine oils is proposed.

Lateral Adsorbate Interactions Inhibit HCOO- While Promoting CO Selectivity for CO2 Electrocatalysis on Ag

2018 ◽  
Author(s):  
Divya Bohra ◽  
Isis Ledezma-Yanez ◽  
Guanna Li ◽  
Wiebren De Jong ◽  
Evgeny A. Pidko ◽  
...  
Keyword(s):  
Electrochemical Reduction ◽  
Experimental Approach ◽  
Decisive Role ◽  
Experimental Methods ◽  
Reaction Intermediates ◽  
Intermediate Species ◽  
Experimental Knowledge ◽  
Complex Interactions ◽  
Ag Catalysts

<p>The analysis presented in this manuscript helps bridge an important fundamental discrepancy between the existing theoretical and experimental knowledge regarding the performance of Ag catalysts for CO<sub>2</sub> electrochemical reduction (CO<sub>2</sub>ER). The results demonstrate how the intermediate species *OCHO is formed readily en-route the HCOO<sup>– </sup>pathway and plays a decisive role in determining selectivity of a predominantly CO producing catalyst such as Ag. Our theoretical and experimental approach develops a better understanding of the nature of competition as well as the complex interactions between the reaction intermediates leading to CO, HCOO<sup>–</sup> and H<sub>2</sub> during CO<sub>2</sub>ER.</p><p><br></p><p>Details of computational and experimental methods are present in the Supporting Information provided. </p><p><br></p><p><br></p>

Photochemical and Electrochemical Reduction of Carbon Dioxide Catalyzed by a Polyoxometalate-Organic Photosensitizer Complex

2018 ◽  
Author(s):  
Chandan Dey ◽  
Ronny Neumann
Keyword(s):  
Carbon Dioxide ◽  
Cyclic Voltammetry ◽  
Formic Acid ◽  
Electrochemical Reduction ◽  
Mass Spectroscopy ◽  
Photochemical Reactions ◽  
Reducing Agent ◽  
Covalent Attachment ◽  
Hybrid Complex ◽  
Open Face

<p>A manganese substituted Anderson type polyoxometalate, [MnMo<sub>6</sub>O<sub>24</sub>]<sup>9-</sup>, tethered with an anthracene photosensitizer was prepared and used as catalyst for CO<sub>2</sub> reduction. The polyoxometalate-photosensitizer hybrid complex, obtained by covalent attachment of the sensitizer to only one face of the planar polyoxometalate, was characterized by NMR, IR and mass spectroscopy. Cyclic voltammetry measurements show a catalytic response for the reduction of carbon dioxide, thereby suggesting catalysis at the manganese site on the open face of the polyoxometalate. Controlled potentiometric electrolysis showed the reduction of CO<sub>2</sub> to CO with a TOF of ~15 sec<sup>-1</sup>. Further photochemical reactions showed that the polyoxometalate-anthracene hybrid complex was active for the reduction of CO<sub>2</sub> to yield formic acid and/or CO in varying amounts dependent on the reducing agent used. Control experiments showed that the attachment of the photosensitizer to [MnMo<sub>6</sub>O<sub>24</sub>]<sup>9-</sup> is necessary for photocatalysis.</p><div><br></div>

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