Lateral Adsorbate Interactions Inhibit HCOO- While Promoting CO Selectivity for CO2 Electrocatalysis on Ag

2018 ◽  
Author(s):  
Divya Bohra ◽  
Isis Ledezma-Yanez ◽  
Guanna Li ◽  
Wiebren De Jong ◽  
Evgeny A. Pidko ◽  
...  
Keyword(s):  
Electrochemical Reduction ◽  
Experimental Approach ◽  
Decisive Role ◽  
Experimental Methods ◽  
Reaction Intermediates ◽  
Intermediate Species ◽  
Experimental Knowledge ◽  
Complex Interactions ◽  
Ag Catalysts

<p>The analysis presented in this manuscript helps bridge an important fundamental discrepancy between the existing theoretical and experimental knowledge regarding the performance of Ag catalysts for CO<sub>2</sub> electrochemical reduction (CO<sub>2</sub>ER). The results demonstrate how the intermediate species *OCHO is formed readily en-route the HCOO<sup>– </sup>pathway and plays a decisive role in determining selectivity of a predominantly CO producing catalyst such as Ag. Our theoretical and experimental approach develops a better understanding of the nature of competition as well as the complex interactions between the reaction intermediates leading to CO, HCOO<sup>–</sup> and H<sub>2</sub> during CO<sub>2</sub>ER.</p><p><br></p><p>Details of computational and experimental methods are present in the Supporting Information provided. </p><p><br></p><p><br></p>

Lateral Adsorbate Interactions Inhibit HCOO- While Promoting CO Selectivity for CO2 Electrocatalysis on Ag

2018 ◽  
Author(s):  
Divya Bohra ◽  
Isis Ledezma-Yanez ◽  
Guanna Li ◽  
Wiebren De Jong ◽  
Evgeny A. Pidko ◽  
...  
Keyword(s):  
Electrochemical Reduction ◽  
Experimental Approach ◽  
Decisive Role ◽  
Experimental Methods ◽  
Reaction Intermediates ◽  
Intermediate Species ◽  
Experimental Knowledge ◽  
Complex Interactions ◽  
Ag Catalysts

<p>The analysis presented in this manuscript helps bridge an important fundamental discrepancy between the existing theoretical and experimental knowledge regarding the performance of Ag catalysts for CO<sub>2</sub> electrochemical reduction (CO<sub>2</sub>ER). The results demonstrate how the intermediate species *OCHO is formed readily en-route the HCOO<sup>– </sup>pathway and plays a decisive role in determining selectivity of a predominantly CO producing catalyst such as Ag. Our theoretical and experimental approach develops a better understanding of the nature of competition as well as the complex interactions between the reaction intermediates leading to CO, HCOO<sup>–</sup> and H<sub>2</sub> during CO<sub>2</sub>ER.</p><p><br></p><p>Details of computational and experimental methods are present in the Supporting Information provided. </p><p><br></p><p><br></p>

Electrodeposited Ag catalysts for the electrochemical reduction of CO 2 to CO

2017 ◽  
Vol 208 ◽  
pp. 35-43 ◽  
Author(s):  
Yu Seok Ham ◽  
Seunghoe Choe ◽  
Myung Jun Kim ◽  
Taeho Lim ◽  
Soo-Kil Kim ◽  
...  
Keyword(s):  
Electrochemical Reduction ◽  
Ag Catalysts

scholarly journals Dimensioning a Call Center: Simulation or Queue Theory?

2009 ◽  
Vol 2 (2) ◽  
pp. 34 ◽  
Author(s):  
Marco Aurélio Carino Bouzada
Keyword(s):  
Analytical Method ◽  
Analytical Methods ◽  
Call Center ◽  
Experimental Approach ◽  
Call Centers ◽  
Experimental Methods ◽  
New Approach ◽  
Alternative Methodology ◽  
Queue Theory ◽  
Set Up

The objective of this paper is to establish a dichotomy - opposing analytical methods (such as Queue Theory) to experimental methods (such as Simulation) and discussing their adequateness to complex operations - set up in the matter of dimensioning the handling capacity of a large brazilian call centers company. The literature related to the application of such methods at call centers is reviewed, and the way the question is treated nowadays by the company is described. Then an experimental approach is suggested to be implemented as an alternative methodology to deal with the issue, instead of the analytical method in use. The results obtained are used to justify the adequacy of the experimental approach to the modern call centers operation, as long as it is possible to have the model closer to reality. The main implication points to a better understanding of the operation achieved with the new approach

scholarly journals In situ cryo-electron tomography reveals filamentous actin within the microtubule lumen

2020 ◽  
Vol 219 (9) ◽  
Author(s):  
Danielle M. Paul ◽  
Judith Mantell ◽  
Ufuk Borucu ◽  
Jennifer Coombs ◽  
Katherine J. Surridge ◽  
...  
Keyword(s):  
Experimental Approach ◽  
Electron Tomography ◽  
Filamentous Actin ◽  
Significant Development ◽  
Cellular Processes ◽  
In Situ Study ◽  
Complex Interactions ◽  
Cryo Electron Tomography ◽  
And Migration

Microtubules and filamentous (F-) actin engage in complex interactions to drive many cellular processes from subcellular organization to cell division and migration. This is thought to be largely controlled by proteins that interface between the two structurally distinct cytoskeletal components. Here, we use cryo-electron tomography to demonstrate that the microtubule lumen can be occupied by extended segments of F-actin in small molecule–induced, microtubule-based, cellular projections. We uncover an unexpected versatility in cytoskeletal form that may prompt a significant development of our current models of cellular architecture and offer a new experimental approach for the in situ study of microtubule structure and contents.

Molecular Structure of Nitro- and Nitrito-Copper Complexes as Reaction Intermediates in Electrochemical Reduction of Nitrite to Dinitrogen Oxide

1995 ◽  
Vol 68 (2) ◽  
pp. 581-589 ◽  
Author(s):  
Nobutoshi Komeda ◽  
Hirotaka Nagao ◽  
Yoshinori Kushi ◽  
Gin-ya Adachi ◽  
Masatatsu Suzuki ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Electrochemical Reduction ◽  
Copper Complexes ◽  
Reaction Intermediates ◽  
Dinitrogen Oxide

The experimental investigation of syllable structure

2014 ◽  
Vol 9 (2) ◽  
pp. 170-195 ◽  
Author(s):  
Bruce L. Derwing ◽  
David Eddington
Keyword(s):  
Experimental Investigation ◽  
Experimental Approach ◽  
State Of The Art ◽  
Theoretical Perspective ◽  
Experimental Methods ◽  
Syllable Structure ◽  
Illustrative Case ◽  
Key Factors ◽  
The One ◽  
Theoretical Issues

This paper is a selective state-of-the-art report on a variety of issues related to the adoption of experimental methods to the study of syllable structure. The rationale for an experimental approach is presented in the first section, followed by a brief section on of some of the main theoretical issues involved. Section three then presents a recap of the most important empirical findings, focusing on the key factors involved, rather than the details of the specific results. Section four then presents an illustrative case where the experimental results seem to conflict, along with discussion of some of the factors that are likely responsible for this. Finally, in the last section, an appeal is made for a deeper theoretical perspective than the one that has guided research in this area heretofore.

scholarly journals In situ cryo-electron tomography reveals filamentous actin within the microtubule lumen

2019 ◽  
Author(s):  
Danielle M Paul ◽  
Judith Mantell ◽  
Ufuk Borucu ◽  
Jennifer Coombs ◽  
Katherine J Surridge ◽  
...  
Keyword(s):  
Experimental Approach ◽  
Electron Tomography ◽  
Filamentous Actin ◽  
Significant Development ◽  
Cellular Processes ◽  
Complex Interactions ◽  
Cryo Electron Tomography ◽  
And Migration ◽  
Microtubule Structure

AbstractMicrotubules and filamentous (F-) actin engage in complex interactions to drive many cellular processes from subcellular organisation to cell division and migration. This is thought to be largely controlled by proteins that interface between the two structurally distinct cytoskeletal components. Here, we use cryo-electron tomography to demonstrate that the microtubule lumen can be occupied by extended segments of F-actin in small-molecule induced, microtubule-based cellular projections. We uncover an unexpected versatility in cytoskeletal form that may prompt a significant development of our current models of cellular architecture and offer a new experimental approach for the in-situ study of microtubule structure and contents.

scholarly journals NEW SILK: Studying experimental touchpoints between material science, synthetic biology, design and art

2018 ◽  
pp. 34-43
Author(s):  
Kirsi Niinimäki ◽  
Camilla Groth ◽  
Pirjo Kääriäinen
Keyword(s):  
Synthetic Biology ◽  
Knowledge Construction ◽  
Material Science ◽  
Knowledge Exchange ◽  
Experimental Methods ◽  
First Year ◽  
New Materials ◽  
Experimental Knowledge ◽  
Material Agency ◽  
Materials Research

This article presents a study in which new materials are developed through experimental knowledge construction and knowledge exchange between different disciplines. The New Silk research project (2017-2020) is the building block for the research. New Silk aims to produce new types of silk-like materials in the context of synthetic biology. In this article we discuss the initial experimental touchpoints between material science, synthetic biology, design and art encountered during the project’s first year. Firstly, the study shows that shared material experiences in the setting of workshops build foundational understanding of perceived material agency leading to discussion on material activity and research ethics. Secondly, our research identified that all of these disciplines, material science, synthetic biology, design and art, approach materials research through experimental methods, even if the goal of the research differs in each discipline.

Economic analysis of the environmental sustainability of agriculture: recent studies using quasi-experimental methods

2022 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Wei Zhang
Keyword(s):  
Environmental Sustainability ◽  
Agricultural Production ◽  
Experimental Approach ◽  
Experimental Methods ◽  
Review Article ◽  
Economic Research ◽  
Agricultural Sustainability ◽  
Spatial And Temporal Variation ◽  
Content Type ◽  
Quasi Experimental

PurposeThe purpose of this review article is to demonstrate how the quasi-experimental approach has been used to study environmental and natural resource issues related to agricultural production.Design/methodology/approachThis review article first provides a short introduction to the quasi-experimental approach using the potential outcomes framework and then uses studies on the environmental sustainability of agricultural production to illustrate how quasi-experimental methods have been applied. Papers reviewed consist of studies that estimate the environmental externalities from agricultural production, evaluate agri-environmental and other related policies and programs, and demonstrate issues related to on-farm resource use and climate adaptation.FindingsDifference-in-differences (DID) and two-way fixed effects methods that utilize the spatial and temporal variation in panel data are widely used to estimate the causal impact of changes in agricultural production and policy on the environment. Utilizing the discontinuities and limits created by agricultural policies and regulations, local treatment effects on land and other input use are estimated using regression discontinuity (RD) or instrumental variable (IV) methods with cross-sectional data.Originality/valueChallenges faced by the food systems have made agricultural sustainability more critical than ever. Over the past three decades, the quasi-experimental approach has become the powerhouse of applied economic research. This review article focuses on quasi-experimental studies on the environmental sustainability of agriculture to provide methodological insights and to highlight gaps in the economics literature of agricultural sustainability.

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