ChemInform Abstract: Synthesis of Metal Sulfides from Metal Complex Compounds with Sulfur- Containing Organic Ligands as Anions

ChemInform ◽  
2010 ◽  
Vol 25 (12) ◽  
pp. no-no
Author(s):  
S. V. LARIONOV
2009 ◽  
Vol 59 (12) ◽  
Author(s):  
Mihaela Flondor ◽  
Ioan Rosca ◽  
Doina Sibiescu ◽  
Mihaela-Aurelia Vizitiu ◽  
Daniel-Mircea Sutiman ◽  
...  

In this paper the synthesis and the study of some complex compounds of Fe(III) with ligands derived from: 2-(4-chloro-phenylsulfanyl)-1-(2-hydroxy-3,5-diiodo-phenyl)-ethanone (HL1), 1-(3,5-dibromo-2-hydroxy-phenyl)-2-phenylsulfanyl-ethanone(HL2), and 2-(4-chloro-phenylsulfanyl)-1-(3,5-dibromo-2-hydroxy-phenyl)-ethanone (HL3) is presented. The characterization of these complexes is based on method as: the elemental chemical analysis, IR and ESR spectroscopy, M�ssbauer, the thermogravimetric analysis and X-ray diffraction. Study of the IR and chemical analysis has evidenced that the precipitates form are a complexes and the combination ratio of M:L is 1:2. The central atoms of Fe(III) presented paramagnetic properties and a octaedric hybridization. Starting from this precipitation reactions, a method for the gravimetric determination of Fe(III) with this organic ligands has been possible. Based on the experimental data on literature indications, the structural formulae of the complex compounds are assigned.


1978 ◽  
Vol 12 (1) ◽  
pp. 81-84
Author(s):  
N. A. Ostapkevich ◽  
E. K. D'yachenko ◽  
K. N. Lyubomirova ◽  
M. A. Abramovich

Physica B+C ◽  
1977 ◽  
Vol 86-88 ◽  
pp. 655-656 ◽  
Author(s):  
I.S. Jacobs ◽  
H.R. Hart ◽  
L.V. Interrante ◽  
J.W. Bray ◽  
J.S. Kasper ◽  
...  

2012 ◽  
Vol 10 (3) ◽  
pp. 28-34
Author(s):  
Denis Vladimirovich Sosin ◽  
Andrey Viktorovich Yevseyev ◽  
Edgar Andreyevich Parfenov ◽  
Vitaliy Andreyevich Pravdivtsev ◽  
Marina Anatolyevna Yevseyeva ◽  
...  

In experiments on mice undergone to an acute hypercapnic hypoxia and an acute hypobaric hypoxia a screening of antihypoxants among new selenium containing metal complex substances was performed after their intra-abdominal and oral introductions. It was found that substances πQ1983 and πQ2170 on both models of hypoxia make the defensive effects surpassing actions well-known antihypoxants such as amthizole and bemythil. It was shown that antihypoxiс affects of studied substances depend on their caused hypothermia. For the first time the protective action of selenium containing metal complex compounds was demonstrated after their introduction per os.


2019 ◽  
Vol 17 (1) ◽  
pp. 81-86
Author(s):  
V.M. Farzaliyev ◽  
◽  
M.P. Bayramov ◽  
S.Kh. Jafarzadeh ◽  
P.Sh. Mammadova ◽  
...  

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