ChemInform Abstract: Modular Chemistry: Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal-Organic Carboxylate Frameworks

ChemInform ◽  
2010 ◽  
Vol 32 (27) ◽  
pp. no-no ◽  
Author(s):  
Mohamed Eddaoudi ◽  
David B. Moler ◽  
Hailian Li ◽  
Banglin Chen ◽  
Theresa M. Reineke ◽  
...  
Keyword(s):  
Secondary Building Units ◽  
Metal Organic ◽  
Highly Porous

Modular Chemistry:  Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal−Organic Carboxylate Frameworks

2001 ◽  
Vol 34 (4) ◽  
pp. 319-330 ◽  
Author(s):  
Mohamed Eddaoudi ◽  
David B. Moler ◽  
Hailian Li ◽  
Banglin Chen ◽  
Theresa M. Reineke ◽  
...  
Keyword(s):  
Secondary Building Units ◽  
Metal Organic ◽  
Highly Porous

scholarly journals Advances in Enzyme and Ionic Liquid Immobilization for Enhanced in MOFs for Biodiesel Production

Molecules ◽  
2021 ◽  
Vol 26 (12) ◽  
pp. 3512
Author(s):  
Reem Shomal ◽  
Babatunde Ogubadejo ◽  
Toyin Shittu ◽  
Eyas Mahmoud ◽  
Wei Du ◽  
...  
Keyword(s):  
Organic Ligands ◽  
Biodiesel Production ◽  
Catalyst Stability ◽  
Promising Candidate ◽  
Catalytic Systems ◽  
Highly Porous Materials ◽  
High Tunability ◽  
Catalytic Sites ◽  
Metal Organic ◽  
Highly Porous

Biodiesel is a promising candidate for sustainable and renewable energy and extensive research is being conducted worldwide to optimize its production process. The employed catalyst is an important parameter in biodiesel production. Metal–organic frameworks (MOFs), which are a set of highly porous materials comprising coordinated bonds between metals and organic ligands, have recently been proposed as catalysts. MOFs exhibit high tunability, possess high crystallinity and surface area, and their order can vary from the atomic to the microscale level. However, their catalytic sites are confined inside their porous structure, limiting their accessibility for biodiesel production. Modification of MOF structure by immobilizing enzymes or ionic liquids (ILs) could be a solution to this challenge and can lead to better performance and provide catalytic systems with higher activities. This review compiles the recent advances in catalytic transesterification for biodiesel production using enzymes or ILs. The available literature clearly indicates that MOFs are the most suitable immobilization supports, leading to higher biodiesel production without affecting the catalytic activity while increasing the catalyst stability and reusability in several cycles.

Recent progress in the design and synthesis of zeolite-like metal–organic frameworks (ZMOFs)

2021 ◽  
Author(s):  
Xinyao Liu ◽  
Yunling Liu
Keyword(s):  
Building Block ◽  
High Stability ◽  
Recent Progress ◽  
Metal Organic Frameworks ◽  
Excellent Performance ◽  
Design And Synthesis ◽  
Molecular Building Block ◽  
Secondary Building Units ◽  
Metal Organic

ZMOFs are a subset of MOFs that exhibit zeolite-like topologies. Using molecular building block strategy, many ZMOFs with high stability and excellent performance can be rationally designed and synthesized using different secondary building units.

Unusual pore structure and sorption behaviour in a hexanodal zinc–organic framework material

2014 ◽  
Vol 50 (14) ◽  
pp. 1678-1681 ◽  
Author(s):  
Jinjie Qian ◽  
Feilong Jiang ◽  
Linjie Zhang ◽  
Kongzhao Su ◽  
Jie Pan ◽  
...  
Keyword(s):  
Pore Structure ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Sorption Behaviour ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework

A highly porous metal–organic framework structurally consists of three topological kinds of 3-connected 1,3,5-benzenetricarboxylate ligands, Zn2(COO)4, Zn3O(COO)6 and Zn4O(COO)6 SBUs, featuring a new 3,3,3,4,4,6-c hexanodal topology.

Supermolecular Building Blocks (SBBs) for the Design and Synthesis of Highly Porous Metal-Organic Frameworks

2008 ◽  
Vol 130 (6) ◽  
pp. 1833-1835 ◽  
Author(s):  
Farid Nouar ◽  
Jarrod F. Eubank ◽  
Till Bousquet ◽  
Lukasz Wojtas ◽  
Michael J. Zaworotko ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Building Blocks ◽  
Design And Synthesis ◽  
Metal Organic ◽  
Highly Porous

ChemInform Abstract: Secondary Building Units, Nets and Bonding in the Chemistry of Metal-Organic Frameworks

ChemInform ◽  
2009 ◽  
Vol 40 (29) ◽  
Author(s):  
David J. Tranchemontagne ◽  
Jose L. Mendoza-Cortes ◽  
Michael O'Keeffe ◽  
Omar M. Yaghi
Keyword(s):  
Metal Organic Frameworks ◽  
Secondary Building Units ◽  
Metal Organic

A Novel (3,4,9)-Connected 3D Metal–Organic Framework Based on the Non-Planar Tricarboxyl Tecton and Zn5O4-Cluster SBU

2015 ◽  
Vol 68 (1) ◽  
pp. 161 ◽  
Author(s):  
Zhuo-Wei Wang ◽  
Hui Zhao ◽  
Min Chen ◽  
Min Hu
Keyword(s):  
Thermal Stability ◽  
Benzoic Acid ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Crystalline Material ◽  
Tripodal Ligand ◽  
Secondary Building Units ◽  
Metal Organic ◽  
Organic Framework

Combination of a non-planar tripodal ligand 3,4-bi(4-carboxyphenyl)-benzoic acid (H3L) and Zn5O4-cluster secondary building units affords a highly connected three-dimensional metal–organic framework, {[Zn5(μ3-OH)3(μ2-OH)L2(H2O)2](H2O)2}n (1), which exhibits an unusual (3,4,9)-connected (42.5)(3.43.52)(32.45.511.613.73.82) topological net. The thermal stability and solid luminescence of the crystalline material have also been investigated.

Quantum Rotations and Chiral Polarization of Qubit Prototype Molecules in a Highly Porous Metal–Organic Framework: 1H NMR T1 Study

2011 ◽  
Vol 115 (42) ◽  
pp. 20460-20465 ◽  
Author(s):  
Svyatoslav P. Gabuda ◽  
Svetlana G. Kozlova ◽  
Denis G. Samsonenko ◽  
Danil N. Dybtsev ◽  
Vladimir P. Fedin
Keyword(s):  
1H Nmr ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Metal Organic ◽  
1H Nmr T1 ◽  
Highly Porous ◽  
Organic Framework
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