A Highly Efficient Catalytic System for Cross-Coupling of Aryl Chlorides and Bromides with Malononitrile Anion by Palladium Carbene Complexes.

ChemInform ◽  
2003 ◽  
Vol 34 (40) ◽  
Author(s):  
Chengwei Gao ◽  
Xiaochun Tao ◽  
Yanlong Qian ◽  
Jiling Huang
Catalysts ◽  
2019 ◽  
Vol 9 (1) ◽  
pp. 86 ◽  
Author(s):  
Xiaogang Li ◽  
Wenbin Zhang ◽  
Leiqing Fu ◽  
Mengping Guo

In this study, a convenient and highly efficient catalytic system for the Suzuki-Miyaura coupling reaction was investigated under mild conditions. A combination of Pd(CH3CN)2Cl2 and pipecolinic acid showed excellent catalytic performance and afforded high turnover numbers; turnover numbers were up to 4.9 × 105 for the coupling reaction of 4-bromobenzoic acid and tetraphenylboron sodium. The catalytic system was also effective for the indexes of 4-bromobenzoic acid, and high turnover numbers were obtained.


2011 ◽  
Vol 353 (9) ◽  
pp. 1591-1600 ◽  
Author(s):  
R. Arundhathi ◽  
D. Damodara ◽  
Pravin R. Likhar ◽  
M. Lakshmi Kantam ◽  
P. Saravanan ◽  
...  

RSC Advances ◽  
2018 ◽  
Vol 8 (25) ◽  
pp. 13643-13648 ◽  
Author(s):  
Hong Ji ◽  
Li-Yang Wu ◽  
Jiang-Hong Cai ◽  
Guo-Rong Li ◽  
Na-Na Gan ◽  
...  

A highly efficient room-temperature strategy for borylation and one-pot two-step borylation/Suzuki–Miyaura cross-coupling reaction of aryl chlorides have been developed.


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