ChemInform Abstract: N-Heterocyclic Carbene-Palladium Complexes [(NHC)Pd(acac)Cl]: Improved Synthesis and Catalytic Activity in Large-Scale Cross-Coupling Reactions.

ChemInform ◽  
2008 ◽  
Vol 39 (6) ◽  
Author(s):  
Nicolas Marion ◽  
Pierre de Fremont ◽  
Iris M. Puijk ◽  
Elise C. Ecarnot ◽  
Dino Amoroso ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Large Scale ◽  
Cross Coupling ◽  
Palladium Complexes ◽  
Coupling Reactions ◽  
Cross Coupling Reactions

N-Heterocyclic Carbene–Palladium Complexes [(NHC)Pd(acac)Cl]: Improved Synthesis and Catalytic Activity in Large-Scale Cross-Coupling Reactions

2007 ◽  
Vol 349 (14-15) ◽  
pp. 2380-2384 ◽  
Author(s):  
Nicolas Marion ◽  
Pierre de Frémont ◽  
Iris M. Puijk ◽  
Elise C. Ecarnot ◽  
Dino Amoroso ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Large Scale ◽  
Cross Coupling ◽  
Palladium Complexes ◽  
Coupling Reactions ◽  
Cross Coupling Reactions

Highly selective Suzuki reaction catalysed by a molecular Pd-P-MOF catalyst under mild conditions: role of ligands and palladium speciation

2022 ◽  
Author(s):  
Daniele Cartagenova ◽  
Stephan Bachmann ◽  
Kurt Püntener ◽  
Michelangelo Scalone ◽  
Mark A Newton ◽  
...  
Keyword(s):  
Large Scale ◽  
State Of The Art ◽  
Suzuki Reaction ◽  
Cross Coupling ◽  
Palladium Complexes ◽  
Fine Chemicals ◽  
Coupling Reactions ◽  
Mild Conditions ◽  
Cross Coupling Reactions

Cross-coupling reactions are a fundamental tool in the large scale synthesis of pharma-, agro- and fine chemicals. Homogeneous palladium complexes remain the state-of-the-art catalysts even though the use of heterogeneous...

Effect on orthometallation of NHC palladium complexes toward the catalytic activity studies in Suzuki coupling reaction

2017 ◽  
Vol 46 (47) ◽  
pp. 16394-16398 ◽  
Author(s):  
Ming-Tsz Chen ◽  
Zing-Lun Kao
Keyword(s):  
Catalytic Activity ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Suzuki Coupling ◽  
Palladium Complexes ◽  
Coupling Reactions ◽  
Suzuki Coupling Reaction ◽  
Cross Coupling Reactions

Herein, we report an approach to improve catalytic activity for cross-coupling reactions.

Palladium Complexes with Metallocene-Bridged Bidentate Diphosphine Ligands:  Synthesis, Structure, and Catalytic Activity in Amination and Cross-Coupling Reactions

2006 ◽  
Vol 25 (11) ◽  
pp. 2750-2760 ◽  
Author(s):  
Oleg V. Gusev ◽  
Tat'yana A. Peganova ◽  
Alexander M. Kalsin ◽  
Nikolai V. Vologdin ◽  
Pavel V. Petrovskii ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Cross Coupling ◽  
Palladium Complexes ◽  
Diphosphine Ligands ◽  
Coupling Reactions ◽  
Cross Coupling Reactions

Lewis Acid-Promoted Suzuki Reaction using Palladium Chloride Anchored on a Polymer as a Catalyst

2008 ◽  
Vol 61 (8) ◽  
pp. 610 ◽  
Author(s):  
Guozhi Fan ◽  
Hanjun Zhang ◽  
Siqing Cheng ◽  
Zhandong Ren ◽  
Zhijun Hu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Lewis Acid ◽  
Lewis Acids ◽  
Heterogeneous Catalysts ◽  
Suzuki Reaction ◽  
Cross Coupling ◽  
Palladium Chloride ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Recoverable Catalyst

Palladium chloride anchored on polystyrene modified by 5-amino-1,10-phenanthroline was prepared and used as an efficient recoverable catalyst for Suzuki cross-coupling reactions. The heterogeneous catalysts can be easily separated from the reaction mixture and reused for five cycles without significant Pd leaching and loss of catalytic activity. Rate enhancement in the Suzuki reaction by Lewis acids was also studied.

A cyano-bridged copper(ii)–copper(i) mixed-valence coordination polymer as a source of copper oxide nanoparticles with catalytic activity in C–N, C–O and C–S cross-coupling reactions

2014 ◽  
Vol 38 (9) ◽  
pp. 4267-4274 ◽  
Author(s):  
Manoj Trivedi ◽  
Sanjeev kumar Ujjain ◽  
Raj Kishore Sharma ◽  
Gurmeet Singh ◽  
Abhinav Kumar ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Coordination Polymer ◽  
Copper Oxide ◽  
Mixed Valence ◽  
Cross Coupling ◽  
Copper Oxide Nanoparticles ◽  
Cuo Nanoparticles ◽  
Oxide Nanoparticles ◽  
Coupling Reactions ◽  
Cross Coupling Reactions

A cyano-bridged Cu(ii)–Cu(i) complex was synthesized and transformed into CuO nanoparticles. Their catalytic activity in C–N, C–O, and C–S cross-coupling reactions was explored.

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