ChemInform Abstract: Alkynylation of Aryl Halides with Perfluoro-Tagged Palladium Nanoparticles Immobilized on Silica Gel under Aerobic, Copper- and Phosphine-Free Conditions in Water.

ChemInform ◽  
2009 ◽  
Vol 40 (45) ◽  
Author(s):  
Roberta Bernini ◽  
Sandro Cacchi ◽  
Giancarlo Fabrizi ◽  
Giovanni Forte ◽  
Francesco Petrucci ◽  
...  
Keyword(s):  
Silica Gel ◽  
Palladium Nanoparticles ◽  
Aryl Halides

Alkynylation of aryl halides with perfluoro-tagged palladium nanoparticles immobilized on silica gel under aerobic, copper- and phosphine-free conditions in water

2009 ◽  
Vol 7 (11) ◽  
pp. 2270 ◽  
Author(s):  
Roberta Bernini ◽  
Sandro Cacchi ◽  
Giancarlo Fabrizi ◽  
Giovanni Forte ◽  
Francesco Petrucci ◽  
...  
Keyword(s):  
Silica Gel ◽  
Palladium Nanoparticles ◽  
Aryl Halides

Palladium chloride catalyzed photochemical Heck reaction

2013 ◽  
Vol 91 (5) ◽  
pp. 348-351 ◽  
Author(s):  
Suresh B. Waghmode ◽  
Sudhir S. Arbuj ◽  
Bina N. Wani ◽  
C.S. Gopinath
Keyword(s):  
Visible Light ◽  
Heck Reaction ◽  
Palladium Nanoparticles ◽  
Bond Formation ◽  
Aryl Halides ◽  
Palladium Chloride ◽  
Carbon Bond ◽  
Excellent Yield ◽  
Carbon Carbon Bond ◽  
Uv Visible

PdCl2 catalyzed carbon–carbon bond formation (Heck reaction) between substituted aryl halides and olefins was carried out without a ligand, under irradiation with UV–visible light. The results demonstrated that UV–visible light accelerated the rate of the reaction, leading to an excellent yield of corresponding products. The recovered palladium nanoparticles could be thermally recycled several times. PdCl2 gave excellent conversion up to the fifth addition of substrate.

Sign in / Sign up

Export Citation Format

Share Document