Dissolution of carbon steel scrap in hydrochloric acid

1968 ◽  
Vol 46 (4) ◽  
pp. 264-268 ◽  
Author(s):  
Tyson Rigg
2018 ◽  
Vol 10 (1) ◽  
pp. 102-115
Author(s):  
Cinthia E. B. Maia ◽  
Gilberto A. Romeiro ◽  
Márcia C. C. Veloso ◽  
Mariane F. dos Santos ◽  
Marcos V. da Silva Santana ◽  
...  

Molecules ◽  
2021 ◽  
Vol 26 (12) ◽  
pp. 3535
Author(s):  
Naba Jasim Mohammed ◽  
Norinsan Kamil Othman ◽  
Mohamad Fariz Mohamad Taib ◽  
Mohd Hazrie Samat ◽  
Solhan Yahya

Extracts from plant materials have great potential as alternatives to inorganic corrosion inhibitors, which typically have harmful consequences. Experimental and theoretical methodologies studied the effectiveness of agricultural waste, namely, date palm seed extract as a green anti-corrosive agent in 0.5 M hydrochloric acid. Experimental results showed that immersion time and temperature are closely related to the effectivity of date palm seed as a corrosion inhibitor. The inhibition efficiency reduced from 95% to 91% at 1400 ppm when the immersion time was increased from 72 h to 168 h. The experimental results also indicated that the inhibition efficiency decreased as the temperature increased. The presence of a protective layer of organic matter was corroborated by scanning electron microscopy. The adsorption studies indicated that date palm seed obeyed Langmuir adsorption isotherm on the carbon steel surface, and Gibbs free energy values were in the range of −33.45 to −38.41 kJ·mol−1. These results suggested that the date palm seed molecules interacted with the carbon steel surface through mixture adsorption. Theoretical calculations using density functional theory showed that the capability to donate and accept electrons between the alloy surface and the date palm seed inhibitor molecules is critical for adsorption effectiveness. The HOMO and LUMO result indicated that the carboxyl (COOH) group and C=C bond were the most active sites for the electron donation-acceptance type of interaction and most auxiliary to the adsorption process over the Fe surface.


RSC Advances ◽  
2017 ◽  
Vol 7 (40) ◽  
pp. 24576-24588 ◽  
Author(s):  
H. S. Gadow ◽  
M. M. Motawea

The inhibitive effect and adsorption behavior of ginger roots extract (GRE) on the corrosion of carbon steel in 1.0 M HCl solution at different temperatures were investigated.


2021 ◽  
Vol 180 ◽  
pp. 109195
Author(s):  
K. Kousar ◽  
M.S. Walczak ◽  
T. Ljungdahl ◽  
A. Wetzel ◽  
H. Oskarsson ◽  
...  

2021 ◽  
Vol 98 ◽  
pp. 8-13
Author(s):  
Dung Ngo Quoc ◽  
◽  
Viet Nguyen Hoang

MS1200 steel grade is now widely utilized in the automotive sector because it is a good solution for the current trend of vehicle chassis frame construction. This research presents a technology procedure for producing MS1200 steel grade from low carbon steel scrap and sponge iron – a product of MIREX Vietnam. The smelting using up to 30 % sponge iron briquettes combined with low carbon scrap, FeSi, FeMn, FeCr, FeTi,… was realized in a medium frequency induction furnace. The heat treatment for forged steel was performed to obtain required properties. The steel product has the following properties: tensile strength σb = 1280 MPa, yield strength σ0.2 = 990 MPa and impact toughness ak = 769 J/mm2, that meets the need of industrial use.


2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
K. S. Shaju ◽  
K. Joby Thomas ◽  
Vinod P. Raphael ◽  
Aby Paul

The corrosion inhibition efficiency of a potential polynuclear Schiff base, (s)-2-(anthracene-9 (10H)-ylidene amino)-5-guanidinopentanoic acid (A9Y5GPA), on carbon steel (CS) in 1 M hydrochloric acid solution has been investigated using weight loss measurements, electrochemical impedance spectroscopy (EIS), and potentiodynamic polarization studies. The corrosion inhibition efficiencies of parent amine [(s)-2-amino-5-guanidinopentanoic acid] and parent ketone (anthracene-9 (10H)-one) on carbon steel in 1.0 M hydrochloric acid solution have also been investigated using weight loss studies. The electrochemical and weight loss data established that the inhibition efficiency on CS increases with the increase in the concentration of inhibitor, A9Y5GPA. The adsorption of A9Y5GPA obeys the Langmuir adsorption isotherm. Thermodynamic parameters (Kads, ΔGads0) were calculated using the adsorption isotherm. Activation parameters of the corrosion process (Ea, ΔH* and ΔS*) were also calculated from the corrosion rates obtained from temperature studies. Tafel plot analysis revealed that A9Y5GPA acts as a mixed-type inhibitor. A probable inhibition mechanism was also proposed. Surface morphology of the carbon steel specimens in the presence and absence of the inhibitor was evaluated by SEM analysis.


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