A Simple Strategy to Construct Amorphous Metal-Free Room Temperature Phosphorescent and Multi-Color Materials

ChemPhysChem ◽  
2018 ◽  
Vol 19 (17) ◽  
pp. 2131-2133 ◽  
Author(s):  
Peng-Zhong Chen ◽  
Yu-Zhe Chen ◽  
Chen-Ho Tung ◽  
Qing-Zheng Yang
Keyword(s):  
Room Temperature ◽  
Amorphous Metal ◽  
Metal Free ◽  
Simple Strategy

Amorphous Metal-Free Room-Temperature Phosphorescent Small Molecules with Multicolor Photoluminescence via a Host–Guest and Dual-Emission Strategy

2018 ◽  
Vol 140 (5) ◽  
pp. 1916-1923 ◽  
Author(s):  
Dengfeng Li ◽  
Feifei Lu ◽  
Jie Wang ◽  
Wende Hu ◽  
Xiao-Ming Cao ◽  
...  
Keyword(s):  
Small Molecules ◽  
Room Temperature ◽  
Amorphous Metal ◽  
Dual Emission ◽  
Metal Free

Metal-free visible-light-induced aerobic oxidation of α-diazoesters leading to α-ketoesters in air

2021 ◽  
Author(s):  
Ruisheng Liu ◽  
Qishun Liu ◽  
Haoran Meng ◽  
Hongyu Ding ◽  
Jindong Hao ◽  
...  
Keyword(s):  
Visible Light ◽  
Room Temperature ◽  
Aerobic Oxidation ◽  
Metal Free

A metal-free and visible-light-induced strategy has been established for the construction of α-ketoesters via aerobic oxidation of α-diazoesters with dioxygen in air at room temperature.

Designed Giant Room‐Temperature Electrocaloric Effects in Metal‐Free Organic Perovskite [MDABCO](NH 4 )I 3 by Phase–Field Simulations

2021 ◽  
pp. 2104393
Author(s):  
Rongzhen Gao ◽  
Xiaoming Shi ◽  
Jing Wang ◽  
Guangzu Zhang ◽  
Houbing Huang
Keyword(s):  
Phase Field ◽  
Room Temperature ◽  
Metal Free

scholarly journals Giant room temperature elastocaloric effect in metal-free thin-film perovskites

2021 ◽  
Vol 7 (1) ◽  
Author(s):  
Cheng Li ◽  
Yu Hui Huang ◽  
Jian-Jun Wang ◽  
Bo Wang ◽  
Yong Jun Wu ◽  
...  
Keyword(s):  
Thin Films ◽  
Solid State ◽  
Room Temperature ◽  
Entropy Change ◽  
Stress Change ◽  
Chemical Doping ◽  
Metal Free ◽  
Organic Ferroelectrics ◽  
Potential Applications ◽  
Unit Stress

AbstractSolid-state refrigeration which is environmentally benign has attracted considerable attention. Mechanocaloric (mC) materials, in which the phase transitions can be induced by mechanical stresses, represent one of the most promising types of solid-state caloric materials. Herein, we have developed a thermodynamic phenomenological model and predicted extraordinarily large elastocaloric (eC) strengths for the (111)-oriented metal-free perovskite ferroelectric [MDABCO](NH4)I3 thin-films. The predicted room temperature isothermal eC ΔSeC/Δσ (eC entropy change under unit stress change) and adiabatic eC ΔTeC/Δσ (eC temperature change under unit stress change) for [MDABCO](NH4)I3 are −60.0 J K−1 kg−1 GPa−1 and 17.9 K GPa−1, respectively, which are 20 times higher than the traditional ferroelectric oxides such as BaTiO3 thin films. We have also demonstrated that the eC performance can be improved by reducing the Young’s modulus or enhancing the thermal expansion coefficient (which could be realized through chemical doping, etc.). We expect these discoveries to spur further interest in the potential applications of metal-free organic ferroelectrics materials towards next-generation eC refrigeration devices.

Visible-light-promoted sulfonylation of thiols with aryldiazonium and sodium metabisulphite leading to unsymmetrical thiosulfonates

2021 ◽  
Author(s):  
Yu-Fen Lv ◽  
Jinyun Luo ◽  
Yuchuan Ma ◽  
Qi Dong ◽  
Lin He
Keyword(s):  
Visible Light ◽  
Room Temperature ◽  
Metal Free ◽  
Sodium Metabisulphite ◽  
Three Component Reaction

A new visible-light-mediated protocol has been proposed for the synthesis of thiosulfonates via metal-free sulfonylation of thiols with aryldiazonium and sodium metabisulphite at room temperature. This mild three-component reaction, simply...

scholarly journals Single-electron detection utilizing coupled nonlinear microresonators

2020 ◽  
Vol 6 (1) ◽  
Author(s):  
Xuefeng Wang ◽  
Xueyong Wei ◽  
Dong Pu ◽  
Ronghua Huan
Keyword(s):  
Scientific Community ◽  
Room Temperature ◽  
Detection Method ◽  
Single Electron ◽  
Nonlinear Coupling ◽  
Electron Charge ◽  
Micromechanical Resonators ◽  
Charge Detection ◽  
Simple Strategy ◽  
Electron Detection

Abstract Since the discovery of the electron, the accurate detection of electrical charges has been a dream of the scientific community. Owing to some remarkable advantages, micro/nanoelectromechanical system-based resonators have been used to design electrometers with excellent sensitivity and resolution. Here, we demonstrate a novel ultrasensitive charge detection method utilizing nonlinear coupling in two micromechanical resonators. We achieve single-electron charge detection with a high resolution up to 0.197 ± 0.056 $${\mathrm{e}}/\sqrt {{\mathrm{Hz}}}$$ e / Hz at room temperature. Our findings provide a simple strategy for measuring electron charges with extreme accuracy.

Diiiodine/Potassium Persulfate Mediated Synthesis of 1,2,3-Thiadiazoles from N-Tosylhydrazones and a Thiocyanate Salt as a Sulfur Source under Transition-Metal-Free Conditions

Synlett ◽  
2021 ◽  
Author(s):  
Yadong Sun ◽  
Ablimit Abdukader ◽  
Yuhan Lu ◽  
Chenjiang Liu
Keyword(s):  
Transition Metal ◽  
Efficient Method ◽  
Room Temperature ◽  
Functional Group ◽  
Ammonium Thiocyanate ◽  
Potassium Persulfate ◽  
Sulfur Source ◽  
Coupling Reactions ◽  
Wide Scope ◽  
Metal Free

AbstractA highly efficient method for the synthesis of 1,2,3-thiadiazoles has been developed by utilizing readily available tosylhydrazones and ammonium thiocyanate with ecofriendly EtOH as the solvent at room temperature. The reaction shows a wide scope of substrates and good functional-group tolerance. This protocol can be scaled up to a gram level and can be applied to coupling reactions with 4-(4-bromophenyl)-1,2,3-thiadiazole as the substrate.

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