Ruthenium Supported on High-Surface-Area Zirconia as an Efficient Catalyst for the Base-Free Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid

ChemSusChem ◽  
2018 ◽  
Vol 11 (13) ◽  
pp. 2083-2090 ◽  
Author(s):  
Christian M. Pichler ◽  
Mohammad G. Al-Shaal ◽  
Dong Gu ◽  
Hrishikesh Joshi ◽  
Wirawan Ciptonugroho ◽  
...  

2020 ◽  
Vol 8 (35) ◽  
pp. 18318-18326 ◽  
Author(s):  
Hailong Peng ◽  
Yangcenzi Xie ◽  
Zicheng Xie ◽  
Yunfeng Wu ◽  
Wenkun Zhu ◽  
...  

Porous high entropy alloy CrMnFeCoNi exhibited remarkable catalytic activity and stability toward p-nitrophenol hydrogenation. The enhanced catalytic performance not only resulted from the high surface area, but also from exposed high-index facets with terraces.



2015 ◽  
Vol 29 (4) ◽  
pp. 234-239 ◽  
Author(s):  
Manne Annapurna ◽  
T. Parsharamulu ◽  
P. Vishnuvardhan Reddy ◽  
M. Suresh ◽  
Pravin R. Likhar ◽  
...  


RSC Advances ◽  
2015 ◽  
Vol 5 (43) ◽  
pp. 33923-33929 ◽  
Author(s):  
Hasimur Rahaman ◽  
Radha M. Laha ◽  
Dilip K. Maiti ◽  
Sujit Kumar Ghosh

Self-assembled high surface area Mn2O3 nanorods have been fabricated through an effective polymer–surfactant interaction and their outstanding catalytic property for the selective transformation of alcohols to aldehydes has been discovered.



2017 ◽  
Vol 536 ◽  
pp. 18-26 ◽  
Author(s):  
R. Sanchis ◽  
D. Delgado ◽  
S. Agouram ◽  
M.D. Soriano ◽  
M.I. Vázquez ◽  
...  


2009 ◽  
Vol 17 (1) ◽  
pp. 85-90 ◽  
Author(s):  
Mandana Akia ◽  
Seyed Mahdi Alavi ◽  
Mehran Rezaei ◽  
Zi-Feng Yan


2004 ◽  
Vol 47 (2) ◽  
pp. 111-126 ◽  
Author(s):  
H ROTTER ◽  
M LANDAU ◽  
M CARRERA ◽  
D GOLDFARB ◽  
M HERSKOWITZ


2020 ◽  
Vol 8 ◽  
Author(s):  
Yu Jin Park ◽  
Jooyoung Lee ◽  
Yoo Sei Park ◽  
Juchan Yang ◽  
Myeong Je Jang ◽  
...  


Catalysts ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 388 ◽  
Author(s):  
Mohammad Peymani ◽  
Seyed Alavi ◽  
Hamidreza Arandiyan ◽  
Mehran Rezaei

A Ni loaded catalyst on mesoporous ceria, with a large surface area, prepared through the surfactant-assisted precipitation and impregnation method was investigated as an efficient catalyst for propane partial oxidation to produce synthesis gas. The results show that 2.5 wt% Ni/CeO2 had the optimum Ni loading, exhibiting the highest catalytic propane conversion. It also showed excellent stability, with no obvious activity drop after a 10 h time-on-stream reaction and slightly decreased in H2 and CO yields. The investigation of the reactant composition effect on carbon formation showed that by decreasing the C/O2 ratio the content of accumulated carbon decreased and propane conversion increased. The good activity of the Ni/CeO2 can be ascribed to the high surface area and rich surface defects of the ceria support and a high dispersion of active sites (Ni nanoparticles).





Author(s):  
Kailun Yang ◽  
Recep Kas ◽  
Wilson A. Smith

<p>This study evaluated the performance of the commonly used strong buffer electrolytes, i.e. phosphate buffers, during CO<sub>2</sub> electroreduction in neutral pH conditions by using in-situ surface enhanced infrared absorption spectroscopy (SEIRAS). Unfortunately, the buffers break down a lot faster than anticipated which has serious implications on many studies in the literature such as selectivity and kinetic analysis of the electrocatalysts. Increasing electrolyte concentration, surprisingly, did not extend the potential window of the phosphate buffers due to dramatic increase in hydrogen evolution reaction. Even high concentration phosphate buffers (1 M) break down within the potentials (-1 V vs RHE) where hydrocarbons are formed on copper electrodes. We have extended the discussion to high surface area electrodes by evaluating electrodes composed of copper nanowires. We would like highlight that it is not possible to cope with high local current densities on these high surface area electrodes by using high buffer capacity solutions and the CO<sub>2</sub> electrocatalysts are needed to be evaluated by casting thin nanoparticle films onto inert substrates as commonly employed in fuel cell reactions and up to now scarcely employed in CO<sub>2</sub> electroreduction. In addition, we underscore that normalization of the electrocatalytic activity to the electrochemical active surface area is not the ultimate solution due to concentration gradient along the catalyst layer.This will “underestimate” the activity of high surface electrocatalyst and the degree of underestimation will depend on the thickness, porosity and morphology of the catalyst layer. </p> <p> </p>



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