scholarly journals Incorporation of Hydrogen-Bonding Functionalities into the Second Coordination Sphere of Iron-Based Water-Oxidation Catalysts

2013 ◽  
Vol 2013 (22-23) ◽  
pp. 3846-3857 ◽  
Author(s):  
Wesley A. Hoffert ◽  
Michael T. Mock ◽  
Aaron M. Appel ◽  
Jenny Y. Yang
Keyword(s):  
Hydrogen Bonding ◽  
Coordination Sphere ◽  
Water Oxidation ◽  
Oxidation Catalysts ◽  
Iron Based ◽  
Second Coordination Sphere

Fast and Simple Preparation of Iron-Based Thin Films as Highly Efficient Water-Oxidation Catalysts in Neutral Aqueous Solution

2015 ◽  
Vol 127 (16) ◽  
pp. 4952-4957 ◽  
Author(s):  
Yizhen Wu ◽  
Mingxing Chen ◽  
Yongzhen Han ◽  
Hongxia Luo ◽  
Xiaojun Su ◽  
...  
Keyword(s):  
Thin Films ◽  
Aqueous Solution ◽  
Water Oxidation ◽  
Oxidation Catalysts ◽  
Highly Efficient ◽  
Simple Preparation ◽  
Neutral Aqueous Solution ◽  
Iron Based

scholarly journals Hydrogen Bonding Rescues Overpotential in Seven-Coordinated Ru Water Oxidation Catalysts

ACS Catalysis ◽  
2017 ◽  
Vol 7 (10) ◽  
pp. 6525-6532 ◽  
Author(s):  
Roc Matheu ◽  
Mehmed Z. Ertem ◽  
Carolina Gimbert-Suriñach ◽  
Jordi Benet-Buchholz ◽  
Xavier Sala ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Water Oxidation ◽  
Oxidation Catalysts

Iron-Based Molecular Water Oxidation Catalysts: Abundant, Cheap, and Promising

2018 ◽  
Vol 14 (1) ◽  
pp. 31-43 ◽  
Author(s):  
Tianqi Liu ◽  
Biaobiao Zhang ◽  
Licheng Sun
Keyword(s):  
Water Oxidation ◽  
Molecular Water ◽  
Oxidation Catalysts ◽  
Iron Based

Mononuclear Ruthenium–Water Oxidation Catalysts: Discerning between Electronic and Hydrogen-Bonding Effects

2013 ◽  
Vol 52 (7) ◽  
pp. 3591-3593 ◽  
Author(s):  
Somnath Maji ◽  
Isidoro López ◽  
Fernando Bozoglian ◽  
J. Benet-Buchholz ◽  
Antoni Llobet
Keyword(s):  
Hydrogen Bonding ◽  
Water Oxidation ◽  
Oxidation Catalysts

In need of a second-hand? The second coordination sphere of ruthenium complexes enables water oxidation with improved catalytic activity

2020 ◽  
Vol 49 (45) ◽  
pp. 16034-16046
Author(s):  
Tiago A. Matias ◽  
Artur F. Keppler ◽  
Fernando H. Bartoloni
Keyword(s):  
Catalytic Activity ◽  
Coordination Sphere ◽  
Water Oxidation ◽  
Ruthenium Complexes ◽  
Proton Acceptor ◽  
Ru Complexes ◽  
Second Coordination Sphere

A ligand dangling arm, acting as an intramolecular proton acceptor, drastically increasing the catalytic activity of Ru-complexes for water oxidation.

Ru(ii) water oxidation catalysts with 2,3-bis(2-pyridyl)pyrazine and tris(pyrazolyl)methane ligands: assembly of photo-active and catalytically active subunits in a dinuclear structure

2020 ◽  
Vol 49 (10) ◽  
pp. 3341-3352
Author(s):  
Alice de Palo ◽  
Giuseppina La Ganga ◽  
Francesco Nastasi ◽  
Massimo Guelfi ◽  
Marco Bortoluzzi ◽  
...  
Keyword(s):  
Experimental Study ◽  
Water Molecule ◽  
Coordination Sphere ◽  
Water Oxidation ◽  
Oxidation Catalysts ◽  
Catalytically Active ◽  
Active Subunits ◽  
Dinuclear Structure

A combined DFT and experimental study indicates that one water molecule is allowed to enter the first coordination sphere of a one-site catalyst, thus activating water oxidation.

scholarly journals Second Coordination Sphere Effects in an Evolved Ru Complex Based on Highly Adaptable Ligand Results in Rapid Water Oxidation Catalysis

2020 ◽  
Vol 142 (11) ◽  
pp. 5068-5077 ◽  
Author(s):  
Nataliia Vereshchuk ◽  
Roc Matheu ◽  
Jordi Benet-Buchholz ◽  
Muriel Pipelier ◽  
Jacques Lebreton ◽  
...  
Keyword(s):  
Coordination Sphere ◽  
Water Oxidation ◽  
Oxidation Catalysis ◽  
Ru Complex ◽  
Water Oxidation Catalysis ◽  
Second Coordination Sphere
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