Focused Microbiome Shifts in Reconstructed Wetlands Correlated with Elevated Cu Concentrations Originating from Micronized Copper Azole Treated Wood

Author(s):  
Jay R. Reichman ◽  
Mark G. Johnson ◽  
Paul T. Rygiewicz ◽  
Bonnie M. Smith ◽  
Michael A. Bollman ◽  
...  
Keyword(s):  
Forests ◽  
2019 ◽  
Vol 11 (1) ◽  
pp. 41 ◽  
Author(s):  
Darrel Nicholas ◽  
Amy Rowlen ◽  
David Milsted

Treated wood timbers employed in ground contact are often installed with a cement collar to firmly fix the structural wood post in place. Few prior studies have determined the effect of concrete on decay efficacy on treated wood, however. Treated wood nominal 4 × 4 posts were installed at four locations, with the upper ground-contact portion of each post encased in concrete, and the samples removed at various times for pH measurements. The wood alkalinity quickly increased at all four sites for the portion of the treated wood in concrete contact compared to the wood in ground contact without concrete. In laboratory decay tests employing three decay fungi, untreated wood which was first exposed or unexposed to concrete had no consistent difference in decay susceptibility. For wood treated with three different commercial copper/organic systems, cement exposure had no effect on wood treated with an amine copper azole system, while treatment with amine copper quat showed a statistically significant fungal efficacy enhancement for cement-exposed samples with both copper-tolerant fungi. Conversely, with a micronized copper azole preservative, cement exposure resulted in reduced fungal efficacy compared to treated samples which were not cement-exposed for all three decay fungi.


2012 ◽  
Vol 33 (18) ◽  
pp. 2111-2118 ◽  
Author(s):  
Amélie Janin ◽  
Pauline Riche ◽  
Jean-François Blais ◽  
Guy Mercier ◽  
Paul Cooper ◽  
...  

Holzforschung ◽  
2005 ◽  
Vol 59 (5) ◽  
pp. 581-588 ◽  
Author(s):  
Levi Waldron ◽  
Paul A. Cooper ◽  
Tony Y. Ung

Abstract An approach to modeling leaching and leaching impacts of preservative components from treated wood is presented based on three simple laboratory determinations: the amount of preservative component available for leaching (Le), equilibrium dissociation of preservative into free water in wood (Di) and diffusion coefficients for component leaching in different wood directions (D). In this study, the following inorganic wood preservative systems were investigated: chromated copper arsenate (CCA), the copper component of copper azole (CA) and alkaline copper quaternary (ACQ), and boron in disodium octaborate tetrahydrate (DOT). Aggressive leaching of finely ground wood showed that amounts of preservative compounds available for leaching were highest for borates, followed by copper in copper amine systems and arsenic in CCA, copper in CCA and chromium in CCA. The equilibrium dissociation or solubility of components in free water in the wood was much higher for borates and copper amine, followed by copper and arsenic in CCA and chromium in CCA. Use of the applicable diffusion coefficient (D) and Di or Le values in a diffusion model allows the prediction of total amount leached and emission or flux rate at different times of exposure for products with different dimensions and geometries. The approach was tested and generally validated through application of the model to results of laboratory water spray leaching of full-size lumber samples. The approach explains the rapid leaching of boron compounds (large diffusion coefficient and high initial dissociated concentration) compared to other preservative components and predicts that ACQ will have higher initial leaching rates compared to CCA and CA, but the latter preservatives will continue to leach copper at a measurable rate for a much longer time. The practical implications and limitations of the approach are discussed.


2017 ◽  
Vol 598 ◽  
pp. 413-420 ◽  
Author(s):  
Jennifer L. Griggs ◽  
Kim R. Rogers ◽  
Clay Nelson ◽  
Todd Luxton ◽  
William E. Platten ◽  
...  

Holzforschung ◽  
2010 ◽  
Vol 64 (3) ◽  
Author(s):  
Cihat Tascioglu ◽  
Kunio Tsunoda

Abstract Vacuum-impregnation with copper azole was applied as a post-treatment to five commercially available wood-based composites with thicknesses of approximately 12 mm, such as softwood plywood (SWP), hardwood plywood (HWP), medium density fiberboard (MDF), oriented strand board (OSB), and particleboard (PB). Untreated and treated composites were tested for their resistance to decay fungi (brown rot fungus Fomitopsis palustris and white rot fungus Trametes versicolor) and the subterranean termite Coptotermes formosanus by Japanese standardized laboratory test methods. Untreated MDF was highly resistant to both biological attacks and seemed to require no preservative treatment under less hazardous conditions, i.e., under protected and above-ground applications, with possible occasional wetting. PB was ranked second, and needed further protection only against C. formosanus. Copper azole did not adequately protect SWP from F. palustris and termite. OSB was not protected either against F. palustris and T. versicolor even at a concentration level of 1 kg copper azole per m3 in contrary to blocks of Cryptomeria japonica sapwood, which was protected at these concentration levels. The biological resistance of HWP was reasonably improved by copper azole. The performance of wood-based composites treated with copper azole, which was inferior to the biological resistance of treated C. japonica sapwood blocks, might depend on the thickness or layer profile, density as a result of porosity, uneven distribution of the preservative in the composites, and the susceptibility of the component raw materials.


2009 ◽  
Author(s):  
Qirong Fu ◽  
Dimitris Argyropolous ◽  
Lucian Lucia ◽  
David Tilotta ◽  
Stan Lebow

2010 ◽  
Vol 25 (3) ◽  
pp. 372-379 ◽  
Author(s):  
Taina Lamminmäki ◽  
Henna Lampinen ◽  
Sari Hyvärinen ◽  
Kirsi Kataja
Keyword(s):  

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