Temperature Control for Proton Exchange Membrane Fuel Cell based on Current Constraint with Consideration of Limited Cooling Capacity

Fuel Cells ◽  
2017 ◽  
Vol 17 (5) ◽  
pp. 662-670 ◽  
Author(s):  
F. Chen ◽  
Y. Yu ◽  
Y. Gao
Processes ◽  
2021 ◽  
Vol 9 (2) ◽  
pp. 235
Author(s):  
Qinghe Li ◽  
Zhiqiang Liu ◽  
Yi Sun ◽  
Sheng Yang ◽  
Chengwei Deng

This paper provides a comprehensive review of the temperature control in proton exchange membrane fuel cells. Proton exchange membrane (PEM) fuel cells inevitably emit a certain amount of heat while generating electricity, and the fuel cell can only exert its best performance in the appropriate temperature range. At the same time, the heat generated cannot spontaneously keep its temperature uniform and stable, and temperature control is required. This part of thermal energy can be classified into two groups. On the one hand, the reaction heat is affected by the reaction process; on the other hand, due to the impedance of the battery itself to the current, the ohmic polarization loss is caused to the battery. The thermal effect of current generates Joule heat, which is manifested by an increase in temperature and a decrease in battery performance. Therefore, it is necessary to design and optimize the battery material structure to improve battery performance and adopt a suitable cooling system for heat dissipation. To make the PEM fuel cell (PEMFC) universal, some extreme situations need to be considered, and a cold start of the battery is included in the analysis. In this paper, the previous studies related to three important aspects of temperature control in proton exchange membrane fuel cells have been reviewed and analyzed to better guide thermal management of the proton exchange membrane fuel cell (PEMFC).


2019 ◽  
Author(s):  
Valentina Guccini ◽  
Annika Carlson ◽  
Shun Yu ◽  
Göran Lindbergh ◽  
Rakel Wreland Lindström ◽  
...  

The performance of thin carboxylated cellulose nanofiber-based (CNF) membranes as proton exchange membranes in fuel cells has been measured in-situ as a function of CNF surface charge density (600 and 1550 µmol g<sup>-1</sup>), counterion (H<sup>+</sup>or Na<sup>+</sup>), membrane thickness and fuel cell relative humidity (RH 55 to 95 %). The structural evolution of the membranes as a function of RH as measured by Small Angle X-ray scattering shows that water channels are formed only above 75 % RH. The amount of absorbed water was shown to depend on the membrane surface charge and counter ions (Na<sup>+</sup>or H<sup>+</sup>). The high affinity of CNF for water and the high aspect ratio of the nanofibers, together with a well-defined and homogenous membrane structure, ensures a proton conductivity exceeding 1 mS cm<sup>-1</sup>at 30 °C between 65 and 95 % RH. This is two orders of magnitude larger than previously reported values for cellulose materials and only one order of magnitude lower than Nafion 212. Moreover, the CNF membranes are characterized by a lower hydrogen crossover than Nafion, despite being ≈ 30 % thinner. Thanks to their environmental compatibility and promising fuel cell performance the CNF membranes should be considered for new generation proton exchange membrane fuel cells.<br>


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