Sulfur isotopic and trace‐element compositions of pyrite from the Zankan iron deposit, West Kunlun Orogenic Belt, China: Possible Early Cambrian banded iron formations

2021 ◽  
Author(s):  
Teng Ding ◽  
Jia Wang ◽  
Tingting Tan ◽  
Chuanlin Zhang ◽  
Xiantao Ye ◽  
...  
2020 ◽  
Vol 132 (9-10) ◽  
pp. 2221-2240 ◽  
Author(s):  
Jiyuan Yin ◽  
Wenjiao Xiao ◽  
Min Sun ◽  
Wen Chen ◽  
Chao Yuan ◽  
...  

Abstract The west Kunlun orogenic belt, located on the northwest margin of the Tibetan Plateau, represents a crucial tectonic junction between the central Asia and Tethys domains. Its evolution was closely related to the Paleozoic subduction and closure of the Proto-Tethys Ocean, which was formed by the breakup of the Rodinia supercontinent following the Neoproterozoic. However, the early evolution of Proto-Tethys oceanic subduction (e.g., subduction initiation timing, polarity, and process) remains controversial. The source of the Early Cambrian granitoids is also unclear. To explore these questions, four Cambrian plutons (i.e., two Tianshuihai monzogranites and south Kunlun diorite and monzogranite) were chosen for geochronological and geochemical studies. Zircon U-Pb dating reveals that these plutons formed at ca. 533–513 Ma and thus represent the oldest arc-related magmatism in the west Kunlun orogenic belt. The Tianshuihai monzogranites have positive εNd(t) values (+0.76 to +1.34) and zircon εHf(t) values of +0.25 to +6.42, with low δ18Ozrn values of +5.11‰ to +7.38‰, suggesting that their source includes juvenile material. These rocks are weakly peraluminous and have relatively old Hf model ages of 1.09–1.48 Ga. Mass balance calculations show that the Tianshuihai monzogranites were derived from partial melting of Mesoproterozoic meta-igneous rocks with the addition of 22% of juvenile material. The south Kunlun monzogranites in this study are weakly peraluminous, and their lowest εNd(t) values are –9.24 to –9.27 and zircon εHf(t) values are –7.80 to –11.2. The oldest Hf model ages are 1.97–2.18 Ga, and the highest zircon δ18Ozrn values are +8.11 to +9.73‰. Their isotopic compositions are different from those of the magmas derived from partial melting of just Paleoproterozoic and Mesoproterozoic basement rocks but can be produced by a mixing source of 32% meta-igneous rock and 68% meta-sedimentary rock. The south Kunlun diorites are characterized by high Sr contents and relatively high Sr/Y (52–63) ratios but low Y, Yb, Cr, and Ni contents, like those of the thickened continental crust-derived adakites. Their Sr-Nd–Hf-O isotopic compositions indicate that their parental magma was derived from a Mesoproterozoic metaigneous basement in the garnet stability field. Based on the newly identified, oldest island arc magmatic records in the west Kunlun orogenic belt, the subduction initiation of the Proto-Tethys oceanic slab must have occurred prior to the Early Cambrian (>533 Ma). Our results, with previously published data, show that the west Kunlun orogenic belt was in an extensional setting during the Early Cambrian and that the magmatism migrated northeastward along the axis of the south Kunlun terrane between 533 Ma and 513 Ma. Therefore, considering the spatial and temporal distribution and petrogenesis of the Early–Middle Cambrian plutons in the west Kunlun orogenic belt, we propose that the Early Cambrian magmatism was most plausibly triggered by asthenospheric upwelling in response to the rollback of southward-subducted Proto-Tethys oceanic slab.


2020 ◽  
Author(s):  
Xiaohua Han ◽  
Elizabeth Tomaszewski ◽  
Ronny Schönberg ◽  
Yongxin Pan ◽  
James Byrne ◽  
...  

<p>There are longstanding and ongoing controversies about the abiogenic or biogenic origin of magnetite in banded iron formations (BIFs). The trace element composition of magnetite was proposed as a promising tracer for distinguishing biogenic from abiogenic magnetite, which, however, remains to be explored quantitatively. Here, we compared the partitioning of trace elements Zinc (Zn) and Nickel (Ni) in both abiogenic and biogenic magnetite produced either by an abiotic reaction of ferrihydrite with by Fe<sup>2+</sup><sub>aq</sub> or by Fe(III)-reducing bacteria <em>Shewanella oneidensis</em> MR-1. We compared the transformation of three different ferrihydrite (Fh) starting materials: 1) Control Fh without added trace elements, 2) ferrihydrite with co-precipitated Zn (ZnFh) and 3) ferrihydrite with co-precipitated Ni (NiFh) – both in either NaHCO<sub>3</sub> or HEPES buffer. We monitored Fe concentration and speciation in both aqueous and solid phases over time using the spectrophotometric ferrozine assay, analyzed Fh transformation products by Mössbauer spectroscopy as well as X-ray diffraction and quantified Zn and Ni in solution and in the minerals by iCAP-Qc quadrupole mass spectrometer after acidic dissolution of the minerals. In summary our results revealed that both Zn and Ni are much more depleted in abiogenic magnetite than those in biogenic magnetite, independent of whether magnetite was precipitated in NaHCO<sub>3</sub> or HEPES buffer. Although further analyses are needed, this suggests that the trace element distribution could be a chemical signature to distinguish biogenic from abiogenic magnetite in BIFs.</p>


2019 ◽  
Vol 506 ◽  
pp. 197-224 ◽  
Author(s):  
Leslie J. Robbins ◽  
Kurt O. Konhauser ◽  
Tyler J. Warchola ◽  
Martin Homann ◽  
Marie Thoby ◽  
...  

2017 ◽  
Vol 130 (5-6) ◽  
pp. 941-951 ◽  
Author(s):  
Kurt O. Konhauser ◽  
Leslie J. Robbins ◽  
Daniel S. Alessi ◽  
Shannon L. Flynn ◽  
Murray K. Gingras ◽  
...  

2019 ◽  
Vol 114 (6) ◽  
pp. 1159-1175 ◽  
Author(s):  
Li-Xing Li ◽  
Jian-Wei Zi ◽  
Hou-Min Li ◽  
Birger Rasmussen ◽  
Simon A. Wilde ◽  
...  

Abstract Although less common than hematite ores, high-grade magnetite ores represent a distinct type of iron mineralization hosted by banded iron formations (BIFs). The Gongchangling iron deposit hosted in ~2.55 Ga BIFs in the North China craton represents one of the most economically important iron deposits in China. Located in mining area II, it is a high-grade (>50 wt % Fe) magnetite deposit and one of the largest of its type in the world. However, the lack of reliable age constraints on iron mineralization has hindered the testing of competing genetic models for the formation of the Gongchangling deposit. In situ U-Pb geochronology of monazite and zircon intergrown with garnet from the proximal alteration zone of a high-grade iron orebody yielded an age of 1.86 Ga, which represents the timing of formation of high-grade magnetite mineralization. This age is coeval with a tectonic extension event recorded in the northeastern North China craton. Our results preclude the previously suggested genetic link between high-grade magnetite mineralization and ~2.50 Ga regional metamorphism. Growth of authigenic monazite and zircon is likely related to the breakdown of detrital zircon, which has undergone metamictization. In combination with previously published data, we propose that the development of zoned alteration associated with the deposit, which is characterized by the garnet-amphibole-magnetite assemblage in the proximal zone changing to a chlorite-quartz–dominated assemblage in the distal zone, can be attributed to a gradual decrease in temperature from >550° to ~250°C and to alteration minerals forming from leaching of the BIFs instead of by replacement of the wall rocks. Magnetite mineralization was controlled by the well-developed faults that cut the BIFs and provided conduits for silica-undersaturated alkaline meteoric fluids. Fluid flow likely took place in an extensional tectonic regime, similar to that invoked elsewhere for hematite mineralization but at greater depths.


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