The Kinetic Modeling of Strong Diffusion-Limited Reaction with Cyclization for Three Isomers – Diallyl Ortho-, Iso- and Tere-Phthalate in a Bulk

2007 ◽  
Vol 1 (3) ◽  
pp. 391-404 ◽  
Author(s):  
Iztok Hace
Keyword(s):  
Kinetic Modeling ◽  
Diffusion Limited ◽  
Diffusion Limited Reaction ◽  
Strong Diffusion

Glancing Angle X-Ray Study of Crystallization of Amorphous Ge at the Ge-A1 Interface

1990 ◽  
Vol 202 ◽  
Author(s):  
S. M. Heald ◽  
J. K. D. Jayanetti ◽  
R. C. Budhani
Keyword(s):  
Initial Period ◽  
Time Characteristic ◽  
X Ray Diffraction ◽  
X Ray ◽  
Diffusion Limited ◽  
Glancing Angle ◽  
Lower Temperature ◽  
Kinetics Of ◽  
Diffusion Limited Reaction ◽  
Good Agreement

ABSTRACTThe amorphous to crystalline transformation of Ge in Al/Ge thin film couples has been studied using glancing angle EXAFS, x-ray reflectivity and diffraction. It was found that crystallization occurs at a much lower temperature (118-150 °C) than for bulk Ge, and initiates at the Al/Ge interface. X-ray diffraction studies were made at 152 °C to study the kinetics of the reaction. After an initial period we find good agreement with a square root dependence of the time, characteristic of a diffusion limited reaction.

Transition in the relaxation dynamics of a reversible diffusion-limited reaction

1989 ◽  
Vol 63 (7) ◽  
pp. 700-703 ◽  
Author(s):  
Martin A. Burschka ◽  
Charles R. Doering ◽  
Daniel ben-Avraham
Keyword(s):  
Relaxation Dynamics ◽  
Diffusion Limited ◽  
Diffusion Limited Reaction

The Anomalous Diffusion-limited Reaction Kinetics of a Phototrapping Reaction

1996 ◽  
Vol 464 ◽  
Author(s):  
Eric Monson ◽  
Anna L. Lin ◽  
Raoul Kopelman
Keyword(s):  
Laser Beam ◽  
Two Dimensions ◽  
One Dimensional ◽  
Rate Laws ◽  
Diffusion Limited ◽  
Dimensional Diffusion ◽  
Diffusion Controlled ◽  
Kinetics Of ◽  
Diffusion Limited Reaction ◽  
Classical Constant

AbstractA focused laser beam acts as both a “phototrap”, bleaching fluorophore molecules which diffuse into the beam path, and as a confocal probe, detecting the excited, unbleached fluorophore molecules still present in the trap. With this focused laser beam, we observe anomalous asymptotic rate laws similar to those predicted for a diffusion-controlled elementary trapping reaction, A + T → T, in one and two dimensions. One dimensional diffusion-limited trapping kinetics are approached in capillaries with 10 μm diameters while two dimensional diffusion limited trapping kinetics are observed with unstirred samples having a quasi 2-D geometry. In the presence of stirring, the 2-D samplesexhibit the classical, constant trapping rate over time.

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