The effect of B1 field inhomogeneity and the nonselective inversion profile on the kinetics of FAIR-based perfusion MRI

2005 ◽  
Vol 53 (6) ◽  
pp. 1355-1362 ◽  
Author(s):  
Janneke Schepers ◽  
Matthias J. P. van Osch ◽  
Lambertus W. Bartels ◽  
Sean N. Heukels ◽  
Max A. Viergever ◽  
...  
2011 ◽  
Vol 29 (5) ◽  
pp. 608-619 ◽  
Author(s):  
Weitian Chen ◽  
Atsushi Takahashi ◽  
Eric Han

2011 ◽  
Vol 209 (2) ◽  
pp. 300-305 ◽  
Author(s):  
Jian Feng ◽  
Jeffrey A. Reimer
Keyword(s):  

2013 ◽  
Vol 38 (2) ◽  
pp. 454-459 ◽  
Author(s):  
Kyunghyun Sung ◽  
Bruce L. Daniel ◽  
Brian A. Hargreaves
Keyword(s):  
3 Tesla ◽  
Dce Mri ◽  

2020 ◽  
Author(s):  
Kathrin Aebischer ◽  
Nino Wili ◽  
Zdeněk Tošner ◽  
Matthias Ernst

Abstract. Radio-frequency (rf) field inhomogeneity is a common problem in NMR which leads to non-ideal rotations of spins in parts of the sample. Often, a physical volume restriction of the sample is used to reduce the effects of rf-field inhomogeneity especially in solid-state NMR where spacers are inserted to reduce the sample volume to the centre of the coil. We show that band-selective pulses in the spin-lock frame can be used to apply B1-field selective inversions to spins that experience selected parts of the rf-field distribution. Any frequency band-selective pulse can be used for this purpose but we chose the family of I-BURP pulses (H. Geen, R. Freeman, Band-Selective Radiofrequency Pulses, J. Magn. Reson. 93 (1991) 93–141) for the measurements demonstrated here. As an example, we show that the implementation of such pulses improves homonuclear frequency-switched Lee-Goldburg decoupling in solid-state NMR.


2020 ◽  
Vol 1 (2) ◽  
pp. 187-195
Author(s):  
Kathrin Aebischer ◽  
Nino Wili ◽  
Zdeněk Tošner ◽  
Matthias Ernst

Abstract. Radio-frequency (rf) field inhomogeneity is a common problem in NMR which leads to non-ideal rotations of spins in parts of the sample. Often, a physical volume restriction of the sample is used to reduce the effects of rf-field inhomogeneity, especially in solid-state NMR where spacers are inserted to reduce the sample volume to the centre of the coil. We show that band-selective pulses in the spin-lock frame can be used to apply B1-field selective inversions to spins that experience selected parts of the rf-field distribution. Any frequency band-selective pulse can be used for this purpose, but we chose the family of I-BURP pulses (Geen and Freeman, 1991) for the measurements demonstrated here. As an example, we show that the implementation of such pulses improves homonuclear frequency-switched Lee–Goldburg decoupling in solid-state NMR.


Author(s):  
J. F. DeNatale ◽  
D. G. Howitt

The electron irradiation of silicate glasses containing metal cations produces various types of phase separation and decomposition which includes oxygen bubble formation at intermediate temperatures figure I. The kinetics of bubble formation are too rapid to be accounted for by oxygen diffusion but the behavior is consistent with a cation diffusion mechanism if the amount of oxygen in the bubble is not significantly different from that in the same volume of silicate glass. The formation of oxygen bubbles is often accompanied by precipitation of crystalline phases and/or amorphous phase decomposition in the regions between the bubbles and the detection of differences in oxygen concentration between the bubble and matrix by electron energy loss spectroscopy cannot be discerned (figure 2) even when the bubble occupies the majority of the foil depth.The oxygen bubbles are stable, even in the thin foils, months after irradiation and if van der Waals behavior of the interior gas is assumed an oxygen pressure of about 4000 atmospheres must be sustained for a 100 bubble if the surface tension with the glass matrix is to balance against it at intermediate temperatures.


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