Fluid dynamics of frozen precipitation at the air–water interface

Precipitation in the forms of snow, hail, and rain plays a critical role in the exchange of mass, momentum and heat at the surfaces of lakes and seas. However, the microphysics of these interactions are not well understood. Motivated by recent observations, we study the physics of the impact of a single frozen canonical particle, such as snow and hail, onto the surface of a liquid bath using a numerical model. The descent, melting, bubble formation and thermal transport characteristics of this system are examined. Three distinct response regimes, namely particle impact, ice melting and vortex ring descent, have been identified and characterized. The melting rate and air content of the snow particle are found to be leading factors affecting the formation of a coherent vortex ring, the vertical descent of melted liquid and the vortex-induced transportation of the released gas bubble to lower depths. It is found that the water temperature can substantially alter the rate of phase change and subsequent flow and thermal transport, while the particle temperature has minimal effect on the process. Finally, the effects of the Reynolds, Weber and Stefan numbers are examined and it is shown that the Reynolds number modifies the strength of the vortex ring and induces the most significant effect on the flow dynamics of the snow particle. Also, the change of Weber number primarily alters the initial phases of snow–bath interaction while modifying the Stefan number of the snow particle essentially determines the system response in its later stages.

Fractionation of O₂∕N₂ and Ar∕N₂ in the Antarctic ice sheet during bubble formation and bubble–clathrate hydrate transition from precise gas measurements of the Dome Fuji ice core

The variations of δO2/N2 and δAr/N2 in the Dome Fuji ice core were measured from 112 m (bubbly ice) to 2001 m (clathrate hydrate ice). Our method, combined with the low storage temperature of the samples (−50 ∘C), successfully excludes post-coring gas-loss fractionation signals from our data. From the bubbly ice to the middle of the bubble–clathrate transition zone (BCTZ) (112–800 m) and below the BCTZ (>1200 m), the δO2/N2 and δAr/N2 data exhibit orbital-scale variations similar to local summer insolation. The data in the lower BCTZ (800–1200 m) have large scatter, which may be caused by millimeter-scale inhomogeneity of air composition combined with finite sample lengths. The insolation signal originally recorded at the bubble close-off remains through the BCTZ, and the insolation signal may be reconstructed by analyzing long ice samples (more than 50 cm for the Dome Fuji core). In the clathrate hydrate zone, the scatter around the orbital-scale variability decreases with depth, indicating diffusive smoothing of δO2/N2 and δAr/N2. A simple gas diffusion model was used to reproduce the smoothing and thus constrain their permeation coefficients. The relationship between δAr/N2 and δO2/N2 is markedly different for the datasets representing bubble close-off (slope ∼ 0.5), bubble–clathrate hydrate transformation (∼1), and post-coring gas loss (∼0.2), suggesting that the contributions of the mass-independent and mass-dependent fractionation processes are different for those cases. The method and data presented here may be useful for improving the orbital dating of deep ice cores over the multiple glacial cycles and further studying non-insolation-driven signals (e.g., atmospheric composition) of these gases.

Dynamics of spiral waves and bubble formation in a closed chemical system of thin photosensitive excitable media

Spiral waves have been observed in a thin layer of excitable media. Especially, electrical spiral waves in cardiac tissues connect to cardiac tachycardia and life-threatening fibrillations. The Belousov-Zhabotinsky (BZ) reaction is the most widely used system to study the dynamics of spiral waves in experiments. When the light sensitive Ru(bpy)3 2+ is used as the catalyst, the BZ reaction becomes photosensitive and the excitability of the reaction can be controlled by varying the illumination intensity. However, the typical photosensitive BZ reaction produces many CO2 bubbles so the spiral waves are always studied in thin layer media with opened top surfaces to release the bubbles. In this work, we develop new chemical recipes of the photosensitive BZ reaction which produces less bubbles. To observe the production of bubbles, we investigate the dynamics of spiral waves in a closed thin layer system. The results show that both the speed of spiral waves and the number of bubbles increase with the concentration of sulfuric acid (H2SO4) and sodium bromate (NaBrO3). For high initial concentrations of both reactants, the size of bubbles increases with time until the wave structures are destroyed. We expect that the chemical recipes reported here can be used to study complicated dynamics of three-dimensional spiral waves in thick BZ media where the bubbles cannot escape.

Catalase test for bacterial identification v1

Catalase is an enzyme that catalyzes the rapid decomposition of hydrogen peroxide into water and oxygen (2H2O2 + Catalase → 2H2O + O2). Organisms that do not present the catalase enzyme such as group B Streptoccoccus can not degrade hydrogen peroxide and therefore no bubble formation is observed.