Flame retardancy, mechanical, and thermal properties of waterborne polyurethane conjugated with a novel phosphorous-nitrogen intumescent flame retardant

2015 ◽  
Vol 38 (3) ◽  
pp. 452-462 ◽  
Author(s):  
Peikun Zhang ◽  
Yazhou He ◽  
Saiqi Tian ◽  
Haojun Fan ◽  
Yi Chen ◽  
...  
2011 ◽  
Vol 399-401 ◽  
pp. 1376-1380
Author(s):  
Li Hua You ◽  
Yin Yin Hui ◽  
Xiang Ning Shi ◽  
Zhi Han Peng

In this study, a novel phosphorus-nitrogen containing intumescent flame retardant (P-N IFR) poly(melamine 2-carboxyethyl(phenyl) phosphate)(PMCEP) was prepared via the reaction of 2-carboxyethyl (phenyl) phosphinic acid (CEPPA) and melamine (MEL) in two-steps. Meanwhile, the molecular structure of the chemical compound was determined by FTIR,1H-NMR and elemental analysis; and the thermal properties was investigated by means of TGA. Combustion studies revealed high limiting oxygen index (LOI) indicative of better flame-retardancy properties for PBT resin.


2017 ◽  
Vol 29 (1) ◽  
pp. 96-105 ◽  
Author(s):  
Warunee Wattanatanom ◽  
Sireerat Churuchinda ◽  
Pranut Potiyaraj

Purpose The purpose of this paper is to investigate the potential use of the layer-by-layer (LbL) assembly as an intumescent flame retardant for polyester, cotton and their blended fabrics. Design/methodology/approach In this study, polyester (PET), cotton and their blends were applied with the flame retardant coating via the LbL assembly technique. The flame retardancy, melt dripping, thermal properties and morphology of coated polyester fabrics were then examined. Findings The scanning electron micrograph of uncoated and coated fabrics revealed that the LbL assembly coating on the fabric surface was successful. The assessment of the flame retardancy and thermal properties of the coated fabrics showed that the after-flame time and melt dripping during the vertical burning test decreased. The char residue at temperatures ranging from 450 to 800°C during thermogravimetric analysis was enhanced as compared with the uncoated fabric. Furthermore, the morphology of the char residual of coated fabrics was rougher and bulkier than the uncoated fabrics, suggesting the typical behavior of intumescence. Social implications The LbL technique generally uses much fewer chemicals, thus making this flame retardant finishing much more environmentally friendly. It is also expected that these fabrics will show better touch characteristics. These fabrics may be tested for their comfort compared to that of conventional coating to enable their use on an industrial scale. Originality/value This work demonstrated the ability to apply an effective intumescent coating on polyester, cotton and blend fabric. In order to maintain fabric handle property, the Lbl coating technique is also employed.


RSC Advances ◽  
2015 ◽  
Vol 5 (21) ◽  
pp. 16328-16339 ◽  
Author(s):  
Rui-Min Li ◽  
Cong Deng ◽  
Cheng-Liang Deng ◽  
Liang-Ping Dong ◽  
Hong-Wei Di ◽  
...  

The water resistance, flame retardancy and mechanical properties of POE intumescent flame-retardant systems were improved simultaneously.


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