Controlled/living polymerization of 2-(diethylamino)ethyl methacrylate and its block copolymer withtert-butyl methacrylate by atom transfer radical polymerization

2003 ◽  
Vol 41 (17) ◽  
pp. 2688-2695 ◽  
Author(s):  
Leong-Huat Gan ◽  
Palaniswamy Ravi ◽  
Bao Wei Mao ◽  
Kam-Chiu Tam
Keyword(s):  
Block Copolymer ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Living Polymerization ◽  
Butyl Methacrylate ◽  
Atom Transfer ◽  
Ethyl Methacrylate

Atom Transfer Radical Polymerization of iso-Butyl Methacrylate in Microemulsion with Cationic and Non-Ionic Emulsifiers

2008 ◽  
Vol 29 (3) ◽  
pp. 264-264
Author(s):  
Yasuyuki Kagawa ◽  
Masahiro Kawasaki ◽  
Per B. Zetterlund ◽  
Hideto Minami ◽  
Masayoshi Okubo
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Butyl Methacrylate ◽  
Atom Transfer

scholarly journals Versatile Multi-Functional Block Copolymers Made by Atom Transfer Radical Polymerization and Post-Synthetic Modification: Switching from Volatile Organic Compound Sensors to Polymeric Surfactants for Water Rheology Control via Hydrolysis

Nanomaterials ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 458 ◽  
Author(s):  
Federico Di Sacco ◽  
Andrea Pucci ◽  
Patrizio Raffa
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Oil Recovery ◽  
Water Solution ◽  
Butyl Methacrylate ◽  
Atom Transfer ◽  
Resistance Variation ◽  
Volatile Organic ◽  
Functionalization Of Carbon Nanotubes ◽  
Volatile Organic Compound Sensors

Novel, multipurpose terpolymers based on styrene (PS), tert-butyl methacrylate (tBMA) and glycidyl methacrylate (GMA), have been synthesized via Atom Transfer Radical Polymerization (ATRP). Post-synthetic modification with 1-pyrenemethylamine (AMP) allows non-covalent functionalization of carbon nanotubes, eventually yielding a conductive nanocomposite materials capable of interacting with different Volatile Organic Compounds (VOCs) by electrical resistance variation upon exposure. Moreover, facile hydrolysis of the tBMA group yields polyelectrolytic macrosurfactants with remarkable thickening properties for promising applications in water solution, such as Enhanced Oil Recovery (EOR).

ATRP Synthesis of PS-b-PtBMA and Preparation of Porous Film

2013 ◽  
Vol 364 ◽  
pp. 679-683
Author(s):  
Chang Hao Yan ◽  
Zhi Jiao Zhang ◽  
Hai Yan Chen ◽  
Zhong Yi Xie ◽  
Ting Zhu ◽  
...  
Keyword(s):  
Block Copolymer ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Catalyst System ◽  
Porous Film ◽  
Atom Transfer ◽  
H Nmr ◽  
Breath Figure ◽  
Breath Figure Method ◽  
End Group

The polystyrene with end group of Br was synthesized by using MBrP as the initiator, CuBr/ PMDETA as the catalyst system according to atom transfer radical polymerization (ATRP). The effect of reaction temperature was studied and the system was confirmed as the active polymerization. Then PS-Br and CuBr/ PMDETA were respectively used as macroinitiator and catalyst to polymerize tBMA according to atom transfer radical polymerization (ATRP). The structure of the product was characterized by GPCFTIR1H-NMR. The amphiphilic block copolymer was obtained after hydrolysis. And the honeycomb porous film was prepared by PS-b-PMAA through using breath figure method.

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