Practical considerations in the determination of compound-specific amino acid δ15N values in animal and plant tissues by gas chromatography-combustion-isotope ratio mass spectrometry, following derivatisation to theirN-acetylisopropyl esters

2012 ◽  
Vol 26 (19) ◽  
pp. 2328-2334 ◽  
Author(s):  
Amy K. Styring ◽  
Alison Kuhl ◽  
Timothy D. J. Knowles ◽  
Rebecca A. Fraser ◽  
Amy Bogaard ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Amino Acid ◽  
Isotope Ratio ◽  
Isotope Ratio Mass Spectrometry ◽  
Plant Tissues ◽  
Specific Amino Acid

Determination of (13C)urea enrichment by gas chromatography/mass spectrometry and gas chromatography/isotope ratio mass spectrometry

1994 ◽  
Vol 23 (8) ◽  
pp. 510-513 ◽  
Author(s):  
Michel Beylot ◽  
France David ◽  
Yadh Khalfallah ◽  
Sylvie Normand ◽  
Valerie Large ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Isotope Ratio ◽  
Isotope Ratio Mass Spectrometry ◽  
Gas Chromatography Mass Spectrometry ◽  
Chromatography Mass Spectrometry

Determination of the exogenous character of testosterone in bovine urine by gas chromatography-combustion-isotope ratio mass spectrometry†

The Analyst ◽  
1998 ◽  
Vol 123 (12) ◽  
pp. 2617-2620 ◽  
Author(s):  
Véronique Ferchaud ◽  
Bruno Le Bizec ◽  
Fabrice Monteau ◽  
François André
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Isotope Ratio ◽  
Isotope Ratio Mass Spectrometry ◽  
Bovine Urine

Stable Nitrogen Isotope Analysis of Amino Acid Enantiomers by Gas Chromatography/Combustion/Isotope Ratio Mass Spectrometry

1997 ◽  
Vol 69 (5) ◽  
pp. 926-929 ◽  
Author(s):  
Stephen A. Macko ◽  
Maria E. Uhle ◽  
Michael H. Engel ◽  
Vladimir Andrusevich
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Amino Acid ◽  
Isotope Ratio ◽  
Isotope Analysis ◽  
Isotope Ratio Mass Spectrometry ◽  
Nitrogen Isotope ◽  
Stable Nitrogen Isotope ◽  
Amino Acid Enantiomers ◽  
Nitrogen Isotope Analysis

scholarly journals Determination of the δ 2H Values of High Molecular Weight Lipids by High Temperature GC Coupled to Isotope Ratio Mass Spectrometry

2020 ◽  
Author(s):  
Sabine Lengger ◽  
Yuki Weber ◽  
Kyle W. Taylor ◽  
Sebastian H. Kopf ◽  
Robert Berstan ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Molecular Weight ◽  
Gas Chromatography ◽  
High Temperature ◽  
High Molecular Weight ◽  
Isotope Ratio ◽  
Isotope Ratio Mass Spectrometry ◽  
Widespread Interest ◽  
Isotope Analyses

<div>Rationale: The hydrogen isotopic composition of lipids (δ 2Hlipid) is widely used in food</div><div>science and as a proxy for past hydrological conditions. Determining the δ 2H values of large,</div><div>well-preserved triacylglycerides and other uniquely microbial lipids, such as glycerol dialkyl</div><div>glycerol tetraether (GDGT) lipids, is thus of widespread interest but has so far not been </div><div>possible due to their size which prohibits analysis by traditional gas chromatography</div><div>pyrolysis isotope ratio mass spectrometry (GC-P-IRMS).</div><div>Methods: We determined the δ 2H values of large, polar molecules and applied high</div><div>temperature gas chromatography (GC) methods on a modified GC-P-IRMS system. The</div><div>methods were validated using authentic standards of large, functionalised molecules</div><div>(triacylglycerides, TAG), purified reference standards of GDGTs, and compared to δ 2H</div><div>values determined by elemental analyser pyrolysis isotope ratio mass spectrometry (EA-PIRMS); and subsequently applied to the analysis of GDGTs in a sample from a methane</div><div>seep and a Welsh peat.</div><div>Results: δ 2H values of TAGs agreed within error between different between GC-P-IRMS and</div><div>EA-P-IRMS, with GC-P-IRMS showing 3-5 ‰ precision for 10 ng H injected. Archaeal lipid</div><div>GDGTs with up to three cyclisations could be analysed: δ 2H values were not significantly</div><div>different between methods with standard deviations of 5 to 6 ‰. When environmental</div><div>samples were analysed, δ 38 2H values of isoGDGTs were 50 ‰ more negative than those of</div><div>terrestrial brGDGTs.</div><div>Conclusions: Our results indicate that the high temperature GC-P-IRMS (HTGC-P-IRMS)</div><div>method developed here is appropriate to determine the δ 2H values of TAGs, GDGT lipids</div><div>with up to two cyclisations, and potentially other high molecular weight compounds. The</div><div>methodology will widen the current analytical window for biomarker and alimentary light</div><div>stable isotope analyses. Moreover, our initial measurements suggest that bacterial and</div><div>archaeal GDGT δ 2H values can record environmental and ecological conditions</div>

Determination of the natural abundance δ15N of nortropane alkaloids by gas chromatography–isotope ratio mass spectrometry of their ethylcarbamate esters

2009 ◽  
Vol 396 (4) ◽  
pp. 1405-1414 ◽  
Author(s):  
Katarzyna Kosieradzka ◽  
Illa Tea ◽  
Emmanuel Gentil ◽  
Richard J. Robins
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Isotope Ratio ◽  
Isotope Ratio Mass Spectrometry ◽  
Natural Abundance

Determination of low isotopic enrichment ofL-[1-13C]valine by gas chromatography/combustion/isotope ratio mass spectrometry: a robust method for measuring protein fractional synthetic ratesin vivo

1998 ◽  
Vol 33 (7) ◽  
pp. 621-626 ◽  
Author(s):  
Dirk-Jan Reijngoud ◽  
Gerald Hellstern ◽  
Henk Elzinga ◽  
Monique G. de Sain-van der Velden ◽  
Albert Okken ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Isotope Ratio ◽  
Isotope Ratio Mass Spectrometry ◽  
Robust Method ◽  
Isotopic Enrichment

Determination of the origin of urinary norandrosterone traces by gas chromatography combustion isotope ratio mass spectrometry

The Analyst ◽  
2006 ◽  
Vol 131 (9) ◽  
pp. 1021-1026 ◽  
Author(s):  
Moritz Hebestreit ◽  
Ulrich Flenker ◽  
Gregor Fußhöller ◽  
Hans Geyer ◽  
Ute Güntner ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Isotope Ratio ◽  
Isotope Ratio Mass Spectrometry
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