scholarly journals In Situ Monitoring of Lithium Metal Anodes and Their Solid Electrolyte Interphases by Transmission Electron Microscopy

2021 ◽  
Vol 2 (6) ◽  
pp. 2170016
Author(s):  
Chih-Yao Chen ◽  
Tetsuya Tsuda ◽  
Yoshifumi Oshima ◽  
Susumu Kuwabata
Keyword(s):  
Electron Microscopy ◽  
Transmission Electron Microscopy ◽  
Solid Electrolyte ◽  
In Situ Monitoring ◽  
Lithium Metal ◽  
Transmission Electron ◽  
Lithium Metal Anodes ◽  
Metal Anodes

In Situ Monitoring of the Seeding and Growth of Silver Metal–Organic Nanotubes by Liquid-Cell Transmission Electron Microscopy

ACS Nano ◽  
2020 ◽  
Vol 14 (7) ◽  
pp. 8735-8743 ◽  
Author(s):  
Karthikeyan Gnanasekaran ◽  
Kristina M. Vailonis ◽  
David M. Jenkins ◽  
Nathan C. Gianneschi
Keyword(s):  
Electron Microscopy ◽  
Transmission Electron Microscopy ◽  
In Situ Monitoring ◽  
Transmission Electron ◽  
Cell Transmission ◽  
Metal Organic ◽  
Liquid Cell ◽  
Organic Nanotubes ◽  
Silver Metal

In Situ Solid Electrolyte Interphase from Spray Quenching on Molten Li: A New Way to Construct High‐Performance Lithium‐Metal Anodes

2018 ◽  
Vol 31 (3) ◽  
pp. 1806470 ◽  
Author(s):  
Sufu Liu ◽  
Xinhui Xia ◽  
Shengjue Deng ◽  
Dong Xie ◽  
Zhujun Yao ◽  
...  
Keyword(s):  
Solid Electrolyte ◽  
High Performance ◽  
Solid Electrolyte Interphase ◽  
Lithium Metal ◽  
Lithium Metal Anodes ◽  
Metal Anodes

In situ fluorinated solid electrolyte interphase towards long-life lithium metal anodes

Nano Research ◽  
2020 ◽  
Vol 13 (2) ◽  
pp. 430-436 ◽  
Author(s):  
Shan-Min Xu ◽  
Hui Duan ◽  
Ji-Lei Shi ◽  
Tong-Tong Zuo ◽  
Xin-Cheng Hu ◽  
...  
Keyword(s):  
Solid Electrolyte ◽  
Solid Electrolyte Interphase ◽  
Lithium Metal ◽  
Lithium Metal Anodes ◽  
Long Life ◽  
Metal Anodes

Direct Visualization of Solid Electrolyte Interphase Formation in Lithium-Ion Batteries with In Situ Electrochemical Transmission Electron Microscopy

2014 ◽  
Vol 20 (4) ◽  
pp. 1029-1037 ◽  
Author(s):  
Raymond R. Unocic ◽  
Xiao-Guang Sun ◽  
Robert L. Sacci ◽  
Leslie A. Adamczyk ◽  
Daan Hein Alsem ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Transmission Electron Microscopy ◽  
Solid Electrolyte ◽  
Solid Electrolyte Interphase ◽  
Lithium Ion ◽  
Transport Processes ◽  
Self Healing ◽  
Transmission Electron ◽  
Li Ion

AbstractComplex, electrochemically driven transport processes form the basis of electrochemical energy storage devices. The direct imaging of electrochemical processes at high spatial resolution and within their native liquid electrolyte would significantly enhance our understanding of device functionality, but has remained elusive. In this work we use a recently developed liquid cell for in situ electrochemical transmission electron microscopy to obtain insight into the electrolyte decomposition mechanisms and kinetics in lithium-ion (Li-ion) batteries by characterizing the dynamics of solid electrolyte interphase (SEI) formation and evolution. Here we are able to visualize the detailed structure of the SEI that forms locally at the electrode/electrolyte interface during lithium intercalation into natural graphite from an organic Li-ion battery electrolyte. We quantify the SEI growth kinetics and observe the dynamic self-healing nature of the SEI with changes in cell potential.

In Situ Generation of Artificial Solid‐Electrolyte Interphases on 3D Conducting Scaffolds for High‐Performance Lithium‐Metal Anodes

2020 ◽  
Vol 10 (8) ◽  
pp. 1903339 ◽  
Author(s):  
Pengbo Zhai ◽  
Yi Wei ◽  
Jing Xiao ◽  
Wei Liu ◽  
Jinghan Zuo ◽  
...  
Keyword(s):  
Solid Electrolyte ◽  
High Performance ◽  
Lithium Metal ◽  
Lithium Metal Anodes ◽  
In Situ Generation ◽  
Metal Anodes

scholarly journals Application of In Situ Liquid Cell Transmission Electron Microscopy in Corrosion Studies: A Critical Review of Challenges and Achievements

CORROSION ◽  
10.5006/3369 ◽  
2019 ◽  
Vol 76 (1) ◽  
pp. 4-17 ◽  
Author(s):  
Ali Kosari ◽  
Henny Zandbergen ◽  
Frans Tichelaar ◽  
Peter Visser ◽  
Herman Terryn ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Transmission Electron Microscopy ◽  
Real Life ◽  
In Situ Monitoring ◽  
Ex Situ ◽  
Transmission Electron ◽  
Corrosion Studies ◽  
Cell Transmission ◽  
Liquid Cell

Identifying corrosion initiation events in metals and alloys demands techniques that can provide temporal and spatial resolution simultaneously. Transmission electron microscopy (TEM) enables one to obtain microstructural and chemical descriptors of materials at atomic/nanoscopic level and has been used in corrosion studies of many metal-electrolyte combinations. Conventionally, ex situ and quasi in situ TEM studies of pre- and post-corroded samples were performed, but possible experimental artifacts such as dehydrated surfaces might not fully represent the real interfacial conditions as compared to those when actually immersed in the electrolyte. Recent advances in liquid cell transmission electron microscopy (LC-TEM) allows for in situ monitoring morphological and even compositional evolutions in materials resulting from interaction with gas or liquid environments. Corrosion science, as a challenging field of research, can benefit from this unparalleled opportunity to investigate many complicated corroding systems in aqueous environments at high resolution. However, “real life” corrosion with LC-TEM is still not straightforward in implementation and there are limitations and challenging experimental considerations for conducting reliable examinations. Thus, this study has been devoted to discussing the challenges of in situ LC-TEM wherein state-of-the-art achievements in the field of relevance are reviewed.

Green in Situ Growth Solid Electrolyte Interphase Layer with High Rebound Resilience for Long-Life Lithium Metal Anodes

2019 ◽  
Vol 11 (46) ◽  
pp. 43200-43205 ◽  
Author(s):  
Na Wu ◽  
Ya-Ru Shi ◽  
Ting Jia ◽  
Xue-Ning Du ◽  
Ya-Xia Yin ◽  
...  
Keyword(s):  
Solid Electrolyte ◽  
Solid Electrolyte Interphase ◽  
Interphase Layer ◽  
In Situ Growth ◽  
Lithium Metal ◽  
Lithium Metal Anodes ◽  
Long Life ◽  
Metal Anodes
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