Determination of Proton Affinity Distributions for Chemical Systems in Aqueous Environments Using a Stable Numerical Solution of the Adsorption Integral Equation

1995 ◽  
Vol 172 (2) ◽  
pp. 341-346 ◽  
Author(s):  
Jacek Jagiełło ◽  
Teresa J. Bandosz ◽  
Karol Putyera ◽  
James A. Schwarz
Keyword(s):  
Integral Equation ◽  
Numerical Solution ◽  
Proton Affinity ◽  
Chemical Systems ◽  
Aqueous Environments ◽  
Adsorption Integral Equation

scholarly journals Flow injection analysis of water. Part 1: Automatic preconcentration determination of sulphate, ammonia and iron(II)/iron(III)

1993 ◽  
Vol 15 (4) ◽  
pp. 141-146 ◽  
Author(s):  
J. S. Cosano ◽  
M. D. Luque de Castro ◽  
M. Valcárcel
Keyword(s):  
Flow Injection ◽  
Good Reproducibility ◽  
Chemical Systems ◽  
Sequential Determination ◽  
On Line ◽  
Exchange Material ◽  
Iron Complexation ◽  
Simple Flow ◽  
Ammonia Formation

This paper describes a simple flow-injection (FI) manifold for the determination of a variety of species in industrial water. The chemical systems involved in the determination of ammonia (formation of Indophenol Blue), sulfate (precipitation with Ba(II)), and iron (complexation with 1,10-phenanthroline with the help of a prior redox reaction for speciation) were selected so that a common manifold could be used for the sequential determination of batches of each analyte. A microcolumn of a suitable ion exchange material was used for on-line preconcentration of each analyte prior to injection; linear ranges for the determination of the analytes at the ng/ml levels were obtained with good reproducibility. The manifold and methods are ready for full automation.

Rods falling near a vertical wall

1977 ◽  
Vol 83 (2) ◽  
pp. 273-287 ◽  
Author(s):  
W. B. Russel ◽  
E. J. Hinch ◽  
L. G. Leal ◽  
G. Tieffenbruck
Keyword(s):  
Integral Equation ◽  
Viscous Fluid ◽  
Numerical Solution ◽  
Vertical Wall ◽  
Numerical Results ◽  
Slender Body ◽  
Asymptotic Results ◽  
Slender Body Theory ◽  
Friction Coefficients ◽  
Body Theory

As an inclined rod sediments in an unbounded viscous fluid it will drift horizontally but will not rotate. When it approaches a vertical wall, the rod rotates and so turns away from the wall. Illustrative experiments and a slender-body theory of this phenomenon are presented. In an incidental study the friction coefficients for an isolated rod are found by numerical solution of the slender-body integral equation. These friction coefficients are compared with the asymptotic results of Batchelor (1970) and the numerical results of Youngren ' Acrivos (1975), who did not make a slender-body approximation.

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