The Long Story and the Brilliant Future of Crystallized Porous Solids

2009 ◽  
pp. 87-134 ◽  
Author(s):  
Gérard Férey
Keyword(s):  
Porous Solids

Controlling Gas Selectivity in Molecular Porous Liquids by Tuning the Cage Window Size

2019 ◽  
Author(s):  
Benjamin Egleston ◽  
Konstantin V. Luzyanin ◽  
Michael C. Brand ◽  
Rob Clowes ◽  
Michael E. Briggs ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Chemical Synthesis ◽  
Field Gradient ◽  
Window Size ◽  
Standard Approach ◽  
Porous Solids ◽  
Pulsed Field Gradient Nmr ◽  
Pulsed Field ◽  
Cage Molecules ◽  
Gas Selectivity

Control of pore window size is the standard approach for tuning gas selectivity in porous solids. Here, we present the first example where this is translated into a molecular porous liquid formed from organic cage molecules. Reduction of the cage window size by chemical synthesis switches the selectivity from Xe-selective to CH<sub>4</sub>-selective, which is understood using <sup>129</sup>Xe, <sup>1</sup>H, and pulsed-field gradient NMR spectroscopy.

Controlling Gas Selectivity in Molecular Porous Liquids by Tuning the Cage Window Size

2019 ◽  
Author(s):  
Benjamin Egleston ◽  
Konstantin V. Luzyanin ◽  
Michael C. Brand ◽  
Rob Clowes ◽  
Michael E. Briggs ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Chemical Synthesis ◽  
Field Gradient ◽  
Window Size ◽  
Standard Approach ◽  
Porous Solids ◽  
Pulsed Field Gradient Nmr ◽  
Pulsed Field ◽  
Cage Molecules ◽  
Gas Selectivity

Control of pore window size is the standard approach for tuning gas selectivity in porous solids. Here, we present the first example where this is translated into a molecular porous liquid formed from organic cage molecules. Reduction of the cage window size by chemical synthesis switches the selectivity from Xe-selective to CH<sub>4</sub>-selective, which is understood using <sup>129</sup>Xe, <sup>1</sup>H, and pulsed-field gradient NMR spectroscopy.

Two Consecutive Magneto-Structural Gas-Solid Transformations with Single-Crystal Retention in Non-Porous Molecular Materials

2018 ◽  
Author(s):  
Julia Miguel-Donet ◽  
Javier López-Cabrelles ◽  
Nestor Calvo Galve ◽  
Eugenio Coronado ◽  
Guillermo Minguez Espallargas
Keyword(s):  
Solid State ◽  
Single Crystal ◽  
Structural Rearrangement ◽  
Magnetic Behaviour ◽  
Porous Solids ◽  
Potential Applications ◽  
Hcl Gas ◽  
Porous Coordination Polymer ◽  
Gas Molecules ◽  
Magnetostructural Transformation

<p>Modification of the magnetic properties in a solid-state material upon external stimulus has attracted much attention in the recent years for their potential applications as switches and sensors. Within the field of coordination polymers, gas sorption studies typically focus on porous solids, with the gas molecules accommodating in the channels. Here we present a 1D non-porous coordination polymer capable of incorporating HCl gas molecules, which not only causes a reordering of its atoms in the solid state but also provokes dramatic changes in the magnetic behaviour. Subsequently, a further solid-gas transformation can occur with the extrusion of HCl gas molecules causing a second structural rearrangement which is also accompanied by modification in the magnetic path between the metal centres. Unequivocal evidence of the two-step magnetostructural transformation is provided by X-ray single-crystal diffraction.</p>

scholarly journals The Effect of Void Arrangement on the Pattern Transformation of Porous Soft Solids under Biaxial Loading

Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1205
Author(s):  
Hai Qiu ◽  
Ying Li ◽  
Tianfu Guo ◽  
Shan Tang ◽  
Zhaoqian Xie ◽  
...  
Keyword(s):  
Biaxial Loading ◽  
Tensile Deformation ◽  
Biaxial Stress ◽  
Porous Solids ◽  
Biaxial Compression ◽  
Structural Topology ◽  
Soft Solids ◽  
Tension And Compression ◽  
Inclined Angle ◽  
Pattern Transformation

Structural topology and loading condition have important influences on the mechanical behaviors of porous soft solids. The porous solids are usually set to be under uniaxial tension or compression. Only a few studies have considered the biaxial loads, especially the combined loads of tension and compression. In this study, porous soft solids with oblique and square lattices of circular voids under biaxial loadings were studied through integrated experiments and numerical simulations. For the soft solids with oblique lattices of circular voids, we found a new pattern transformation under biaxial compression, which has alternating elliptic voids with an inclined angle. This kind of pattern transformation is rarely reported under uniaxial compression. Introducing tensile deformation in one direction can hamper this kind of pattern transformation under biaxial loading. For the soft solids with square lattices of voids, the number of voids cannot change their deformation behaviors qualitatively, but quantitatively. In general, our present results demonstrate that void morphology and biaxial loading can be harnessed to tune the pattern transformations of porous soft solids under large deformation. This discovery offers a new avenue for designing the void morphology of soft solids for controlling their deformation patterns under a specific biaxial stress-state.

Fractal structure of porous solids characterized by adsorption

1995 ◽  
Vol 51 (14) ◽  
pp. 8709-8714 ◽  
Author(s):  
S. J. Sze ◽  
T. Y. Lee
Keyword(s):  
Fractal Structure ◽  
Porous Solids

Characterisation of Porous Solids

1980 ◽  
Vol 38 (2) ◽  
pp. 251-252
Author(s):  
D. Dollimore
Keyword(s):  
Porous Solids

Novel organic porous solids with channel and layered structures from 1,3,5-triazine-2,4,6-triaminehexaacetic acid and its calcium salt

2000 ◽  
pp. 1351-1352 ◽  
Author(s):  
S. N. Ghanashyam Acharya ◽  
K. Venkatesan ◽  
Santanu Bhattacharya ◽  
R. Srinivasa Gopalan ◽  
G. U. Kulkarni
Keyword(s):  
Calcium Salt ◽  
Layered Structures ◽  
Porous Solids

Adsorption of Pure Gases and Mixtures on Porous Solids up to High Pressures

Adsorption ◽  
2005 ◽  
Vol 11 (3-4) ◽  
pp. 379-384 ◽  
Author(s):  
Reiner Staudt ◽  
Alexander Herbst ◽  
Silvio Beutekamp ◽  
Peter Harting
Keyword(s):  
High Pressures ◽  
Porous Solids

Fluid dynamic characterisation of porous solids in catalytic fixed-bed reactors

2012 ◽  
Vol 154 ◽  
pp. 170-174 ◽  
Author(s):  
T. Horneber ◽  
C. Rauh ◽  
A. Delgado
Keyword(s):  
Fluid Dynamic ◽  
Fixed Bed ◽  
Porous Solids ◽  
Fixed Bed Reactors
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