Physico-Chemical Concepts on the Fate of Organic Compounds

Author(s):  
James W. Moore ◽  
S. Ramamoorthy
2020 ◽  
pp. 204-220
Author(s):  
Zawawi Daud ◽  
Halizah Awang

In this chapter, the performance of combined treatment of municipal landfill leachate is reviewed. Although individual physico-chemical treatments are suitable for the removal of heavy metals and hydrolyzation of some organic compounds, a combination of two physico-chemical treatments or physico-chemical and biological is required for optimum treatment of stabilized landfill leachate. A combination of two physico-chemical treatments can give optimum results in removal of recalcitrant organic compounds from stabilized leachate, as reflected by a significant decrease of the COD values after treatment. On the other hand, a combination of physico-chemical and biological treatments is required to achieve effective removal of NH3-N and COD with a substantial amount of biodegradable organic matter. In many cases, physico-chemical treatments are suitable for pre-treatment of stabilized leachate. The objective of this paper is to highlight various types of integrated leachate treatments as it has been difficult to get optimum efficiency from single approached treatment.


2022 ◽  
pp. 7-29
Author(s):  
Ari Laaksonen ◽  
Jussi Malila

2006 ◽  
Vol 4 (1) ◽  
pp. 21-28 ◽  
Author(s):  
Jean Spinks ◽  
Suzanne Phillips ◽  
Priscilla Robinson ◽  
Paul Van Buynder

In early 2003, after a prolonged drought period, extensive bushfires occurred in the east of Victoria affecting 1.5 million hectares of land. At the time, smoke and ash from bushfires, settling on roofs, contained pollutants that could potentially contaminate rainwater collected and stored in tanks for domestic use. The major concerns include polycyclic aromatic hydrocarbons (PAHs) from incomplete combustion of organic matter and arsenic from burnt copper chrome arsenate (CCA) treated wood. An increase in microbial contamination through altered nutrient levels was also hypothesised. A pilot study of 49 rainwater tank owners was undertaken in north-east Victoria. A rainwater tank sample was taken and analysed for a variety of parameters including organic compounds, microbiological indicators, metals, nutrients and physico-chemical parameters. A survey was administered concurrently. A number of results were outside the Australian Drinking Water Guideline (ADWG) values for metals and microbiological indicator organisms, but not for any tested organic compounds. PAHs and arsenic are unlikely to be elevated in rainwater tanks as a result of bushfires, but cadmium may be of concern.


2013 ◽  
Vol 11 (2) ◽  
pp. 799-813 ◽  
Author(s):  
Cécile Raillard ◽  
Valérie Héquet ◽  
Bifen Gao ◽  
Heyok Choi ◽  
Dionysios D. Dionysiou ◽  
...  

Abstract The photocatalytic oxidation of seven typical indoor volatile organic compounds (VOCs) is experimentally investigated using novel nanocrystalline TiO2 dip-coated catalysts. Not only the role of hydrophilicity of the reactants but also other physico-chemical properties and molecular descriptors are studied and related to kinetic and equilibrium constants. The main objective of this work consists in establishing simple relationships that will be useful to deepen the understanding of gas-phase heterogeneous photocatalytic mechanisms and for the prediction of degradation rates of these VOCs using an indoor air treatment process.


Beverages ◽  
2018 ◽  
Vol 4 (4) ◽  
pp. 77 ◽  
Author(s):  
Wendy Parr ◽  
Alex Maltman ◽  
Sally Easton ◽  
Jordi Ballester

Tasting minerality in wine is highly fashionable, but it is unclear what this involves. The present review outlines published work concerning how minerality in wine is perceived and conceptualised by wine professionals and consumers. Studies investigating physico-chemical sources of perceived minerality in wine are reviewed also. Unusually, for a wine sensory descriptor, the term frequently is taken to imply a genesis: the sensation is the taste of minerals in the wine that were transported through the vine from the vineyard rocks and soils. Recent studies exploring tasters’ definitions of minerality in wine support this notion. However, there are reasons why this cannot be. First, minerals in wine are nutrient elements that are related distantly only to vineyard geological minerals. Second, mineral nutrients in wine normally have minuscule concentrations and generally lack flavour. Results of reviewed studies overall demonstrate marked variability in both wine professionals’ and wine consumers’ definitions and sensory-based judgments of minerality in wine, although there is some consensus in terms of the other wine attributes that associate with the term mineral. The main wine composition predictors of perceived minerality involve a complex combination of organic compounds dependent on grape ripeness and/or derived from wine fermentations and redox status.


1994 ◽  
Vol 9 (6) ◽  
pp. 1596-1603 ◽  
Author(s):  
S. Jans ◽  
S. Kalbitzer ◽  
P. Oberschachtsiek ◽  
M. Behar

Cd-arachidat in the form of Langmuir-Blodgett films and thick photoresist layers of AZ5412H have been exposed to 15N-ion beams. The physico-chemical state of these targets as a function of the 15N fluence has been monitored by the 15N nuclear reaction with the respective H component. In this way, radiolytic changes in H distribution and bonding have been measured. In particular, diffusion and desorption processes have quantitatively been followed up to fluences of about 1 × 1016 N/cm2 at temperatures as low as 40 K. The correlated changes in H bonding, obtained by analyzing the concomitant Doppler widths as a function of the 15N fluence, consist of both decomposition and restoration of C-H and H-H molecular groups.


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