Assessing a Sand Clay Liner Material for Protecting Highways and Road Shoulders

2021 ◽  
pp. 140-149
Author(s):  
Muawia Dafalla ◽  
Abdullah Shaker ◽  
Abdul Naser Abdul Ghani
Keyword(s):  
Liner Material ◽  
Clay Liner

Ru Passivated and Ru Doped e-TaN surfaces as Combined Barrier and Liner Material for Copper Interconnects: A First Principles Study

2018 ◽  
Author(s):  
Suresh Natarajan ◽  
Cara-Lena Nies ◽  
Michael Nolan
Keyword(s):  
First Principles ◽  
Film Growth ◽  
Early Stage ◽  
Copper Interconnects ◽  
Liner Material ◽  
Critical Dimensions ◽  
Industry Standard ◽  
Cu Film ◽  
Improved Performance ◽  
And Diffusion

<div>As the critical dimensions of transistors continue to be scaled down to facilitate improved performance and device speeds, new ultrathin materials that combine diffusion barrier and seed/liner properties are needed for copper interconnects at these length scales. Ideally, to facilitate coating of high aspect ratio structures, this alternative barrier+liner material should only consist of one or as few layers as possible. We studied TaN, the current industry standard for Cu diffusion barriers, and Ru, which is a</div><div>suitable liner material for Cu electroplating, to explore how combining these two materials in a barrier+liner material influences the adsorption of Cu atoms in the early stage of Cu film growth. To this end, we carried out first-principles simulations of the adsorption and diffusion of Cu adatoms at Ru-passivated and Ru-doped e-TaN(1 1 0) surfaces. For comparison, we also studied the behaviour of Cu and Ru adatoms at the low index surfaces of e-TaN, as well as the interaction of Cu adatoms with the (0 0 1) surface of hexagonal Ru. Our results confirm the barrier and liner properties of TaN and Ru, respectively while also highlighting the weaknesses of both materials. Ru passivated TaN was found to have improved binding with Cu adatoms as compared to the bare TaN and Ru surfaces.</div><div>On the other hand, the energetic barrier for Cu diffusion at Ru passivated TaN surface was lower than at the bare TaN surface which can promote Cu agglomeration. For Ru-doped TaN however, a decrease in Cu binding energy was found in addition to favourable migration of the Cu adatoms toward the doped Ru atom and unfavourable migration away from it or into the bulk. This suggests that Ru doping sites in the TaN surface can act as nucleation points for Cu growth with high migration barrier preventing agglomeration and allow electroplating of Cu. Therefore Ru-doped TaN is proposed as a candidate for a combined barrier+liner material with reduced thickness.</div>

Investigation of a Bulk Metallic Glass as a Shaped Charge Liner Material

2006 ◽  
Author(s):  
William P. Walters ◽  
Laszlo J. Kecskes ◽  
Justin E. Pritchett
Keyword(s):  
Metallic Glass ◽  
Bulk Metallic Glass ◽  
Shaped Charge ◽  
Liner Material

Clay liner materials for land disposal of hazardous non-metal wastes

1996 ◽  
Vol 33 (8) ◽  
pp. 71-77
Author(s):  
I. M.-C. Lo ◽  
H. M. Liljestrand ◽  
J. Khim ◽  
Y. Shimizu
Keyword(s):  
Sorption Capacity ◽  
Organic Anion ◽  
Surface Exchange ◽  
Clay Liner ◽  
Effective Removal ◽  
Exchange Constants ◽  
Anionic Species ◽  
Surface Ligand ◽  
Land Disposal

Simple land disposal systems for hazardous and mixed wastes contain heavy metal cationic species through precipitation and ion exchange mechanisms but typically fail by releasing soluble organic and inorganic anionic species. To enhance the removal of anions from leachate, clays are modified with coatings of iron or aluminium cations to bridge between the anionic surface and the anionic pollutants. A competitive surface ligand exchange model indicates that surface coatings of 10 meq cation/gm montmorillonite under typical leachate conditions increase the inorganic anion sorption capacity by at least a factor of 6 and increase the intrinsic surface exchange constants by more than a factor of 100. Similarly, metal hydroxide coatings on montmorillonite increase the organic anion sorption capacity by a factor of 9 and increase the intrinsic surface exchange constants by a factor of 20. For historical concentrations of non-metal anions in US hazardous and mixed waste leachate, sorption onto natural clay liner materials is dominated by arsenate sorption. With cation coatings, anion exchange provides an effective removal for arsenate, selenate, phenols, cresols, and phthalates. Engineering applications are presented for the use of modified clays as in situ barriers to leachate transport of anionic pollutants as well as for above ground treatment of recovered leachate.

Development and analysis of composite overwrapped pressure vessels for hydrogen storage

2021 ◽  
pp. 002199832110335
Author(s):  
Osman Kartav ◽  
Serkan Kangal ◽  
Kutay Yücetürk ◽  
Metin Tanoğlu ◽  
Engin Aktaş ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
Damage Model ◽  
Pressure Vessels ◽  
Filament Winding ◽  
Burst Pressure ◽  
Fe Model ◽  
Fe Method ◽  
Liner Material ◽  
Mechanical Performances ◽  
Metallic Liner

In this study, composite overwrapped pressure vessels (COPVs) for high-pressure hydrogen storage were designed, modeled by finite element (FE) method, manufactured by filament winding technique and tested for burst pressure. Aluminum 6061-T6 was selected as a metallic liner material. Epoxy impregnated carbon filaments were overwrapped over the liner with a winding angle of ±14° to obtain fully overwrapped composite reinforced vessels with non-identical front and back dome layers. The COPVs were loaded with increasing internal pressure up to the burst pressure level. During loading, deformation of the vessels was measured locally with strain gauges. The mechanical performances of COPVs designed with various number of helical, hoop and doily layers were investigated by both experimental and numerical methods. In numerical method, FE analysis containing a simple progressive damage model available in ANSYS software package for the composite section was performed. The results revealed that the FE model provides a good correlation as compared to experimental strain results for the developed COPVs. The burst pressure test results showed that integration of doily layers to the filament winding process resulted with an improvement of the COPVs performance.

scholarly journals Hydraulic and Swell–Shrink Characteristics of Clay and Recycled Zeolite Mixtures for Liner Construction in Sustainable Waste Landfill

2021 ◽  
Vol 13 (13) ◽  
pp. 7301
Author(s):  
Marcin K. Widomski ◽  
Anna Musz-Pomorska ◽  
Wojciech Franus
Keyword(s):  
Hydraulic Conductivity ◽  
Exchange Capacity ◽  
Saturated Hydraulic Conductivity ◽  
Clay Soils ◽  
Compacted Clay ◽  
Clay Liner ◽  
Compacted Clay Liner ◽  
Drying And Rewetting ◽  
Swelling Characteristics ◽  
Shrinkage And Swelling

This paper presents research considering hydraulic as well as swelling and shrinkage characteristics of potential recycled fine particle materials for compacted clay liner for sustainable landfills. Five locally available clay soils mixed with 10% (by mass) of NaP1 recycled zeolite were tested. The performed analysis was based on determined plasticity, cation exchange capacity, coefficient of saturated hydraulic conductivity after compaction, several shrinkage and swelling characteristics as well as, finally, saturated hydraulic conductivity after three cycles of drying and rewetting of tested specimens and the reference samples. The obtained results showed that addition of zeolite to clay soils allowed reduction in their saturated hydraulic conductivity to meet the required threshold (≤1 × 10−9 m/s) of sealing capabilities for compacted clay liner. On the other hand, an increase in plasticity, swelling, and in several cases in shrinkage, of the clay–zeolite mixture was observed. Finally, none of the tested mixtures was able to sustain its sealing capabilities after three cycles of drying and rewetting. Thus, the studied clayey soils mixed with sustainable recycled zeolite were assessed as promising materials for compacted liner construction. However, the liner should be operated carefully to avoid extensive dissication and cracking.

A prefabricated bentonite clay liner

1991 ◽  
Vol 10 (5-6) ◽  
pp. 569-573
Author(s):  
Martin J. Simpson
Keyword(s):  
Bentonite Clay ◽  
Clay Liner
Sign in / Sign up

Export Citation Format

Share Document