Biogenic Sulphur in the Marine Boundary Layer of the Arctic- the International Arctic Ocean Expedition, 1991

Abstract. A full year of measurements of surface ozone over the Arctic Ocean far removed from land is presented (81° N – 88° N latitude). The data were obtained during the drift of the French schooner TARA between September 2006 and January 2008, while frozen in the Arctic Ocean. The data confirm that long periods of virtually total absence of ozone occur in the spring (mid March to mid June) after Polar sunrise. At other times of the year ozone concentrations are comparable to other oceanic observations with winter mole fractions of ca. 30–40 nmol mol−1 and summer minima of ca. 20 nmol mol−1. Contrary to earlier observations from ozone sonde data obtained at Arctic coastal observatories, the ambient temperature was well above −20°C during most ODEs (ozone depletion episodes). Backwards trajectory calculations suggest that during these ODEs the air had previously been in contact with the frozen ocean surface for several days and originated largely from the Siberian coast where several large open flaw leads developed in the spring of 2007.

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Summertime observations of elevated levels of ultrafine particles in the high Arctic marine boundary layer

Atmospheric Chemistry and Physics ◽

10.5194/acp-17-5515-2017 ◽

2017 ◽

Vol 17 (8) ◽

pp. 5515-5535 ◽

Cited By ~ 31

Author(s):

Julia Burkart ◽

Megan D. Willis ◽

Heiko Bozem ◽

Jennie L. Thomas ◽

Kathy Law ◽

...

Keyword(s):

Boundary Layer ◽

Ultrafine Particles ◽

Marine Boundary Layer ◽

Ultrafine Particle ◽

High Arctic ◽

Particle Formation ◽

Open Ocean ◽

Biologically Active ◽

The Arctic ◽

Depositional Processes

Abstract. Motivated by increasing levels of open ocean in the Arctic summer and the lack of prior altitude-resolved studies, extensive aerosol measurements were made during 11 flights of the NETCARE July 2014 airborne campaign from Resolute Bay, Nunavut. Flights included vertical profiles (60 to 3000 m above ground level) over open ocean, fast ice, and boundary layer clouds and fogs. A general conclusion, from observations of particle numbers between 5 and 20 nm in diameter (N5 − 20), is that ultrafine particle formation occurs readily in the Canadian high Arctic marine boundary layer, especially just above ocean and clouds, reaching values of a few thousand particles cm−3. By contrast, ultrafine particle concentrations are much lower in the free troposphere. Elevated levels of larger particles (for example, from 20 to 40 nm in size, N20 − 40) are sometimes associated with high N5 − 20, especially over low clouds, suggestive of aerosol growth. The number densities of particles greater than 40 nm in diameter (N > 40) are relatively depleted at the lowest altitudes, indicative of depositional processes that will lower the condensation sink and promote new particle formation. The number of cloud condensation nuclei (CCN; measured at 0.6 % supersaturation) are positively correlated with the numbers of small particles (down to roughly 30 nm), indicating that some fraction of these newly formed particles are capable of being involved in cloud activation. Given that the summertime marine Arctic is a biologically active region, it is important to better establish the links between emissions from the ocean and the formation and growth of ultrafine particles within this rapidly changing environment.

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Ozone variability and halogen oxidation within the Arctic and sub-Arctic springtime boundary layer

Atmospheric Chemistry and Physics ◽

10.5194/acp-10-10223-2010 ◽

2010 ◽

Vol 10 (21) ◽

pp. 10223-10236 ◽

Cited By ~ 92

Author(s):

J. B. Gilman ◽

J. F. Burkhart ◽

B. M. Lerner ◽

E. J. Williams ◽

W. C. Kuster ◽

...

Keyword(s):

Boundary Layer ◽

North Atlantic ◽

Marine Boundary Layer ◽

Transport Model ◽

Arctic Basin ◽

The Arctic ◽

Arctic Boundary Layer ◽

Air Masses ◽

The North ◽

The North Atlantic

Abstract. The influence of halogen oxidation on the variabilities of ozone (O3) and volatile organic compounds (VOCs) within the Arctic and sub-Arctic atmospheric boundary layer was investigated using field measurements from multiple campaigns conducted in March and April 2008 as part of the POLARCAT project. For the ship-based measurements, a high degree of correlation (r = 0.98 for 544 data points collected north of 68° N) was observed between the acetylene to benzene ratio, used as a marker for chlorine and bromine oxidation, and O3 signifying the vast influence of halogen oxidation throughout the ice-free regions of the North Atlantic. Concurrent airborne and ground-based measurements in the Alaskan Arctic substantiated this correlation and were used to demonstrate that halogen oxidation influenced O3 variability throughout the Arctic boundary layer during these springtime studies. Measurements aboard the R/V Knorr in the North Atlantic and Arctic Oceans provided a unique view of the transport of O3-poor air masses from the Arctic Basin to latitudes as far south as 52° N. FLEXPART, a Lagrangian transport model, was used to quantitatively determine the exposure of air masses encountered by the ship to first-year ice (FYI), multi-year ice (MYI), and total ICE (FYI+MYI). O3 anti-correlated with the modeled total ICE tracer (r = −0.86) indicating that up to 73% of the O3 variability measured in the Arctic marine boundary layer could be related to sea ice exposure.

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Seasonal and short-term variability in dimethyl sulfide, sulfur dioxide and biogenic sulfur and sea salt aerosol particles in the arctic marine boundary layer during summer and autumn

Tellus B ◽

10.3402/tellusb.v48i2.15891 ◽

1996 ◽

Vol 48 (2) ◽

pp. 272-299 ◽

Cited By ~ 39

Author(s):

Caroline Leck ◽

Cecilia Persson

Keyword(s):

Boundary Layer ◽

Dimethyl Sulfide ◽

Marine Boundary Layer ◽

Aerosol Particles ◽

Sea Salt ◽

The Arctic ◽

Sulfide Sulfur ◽

Short Term ◽

Sea Salt Aerosol ◽

Short Term Variability

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Controlled meteorological (CMET) free balloon profiling of the Arctic atmospheric boundary layer around Spitsbergen compared to ERA-Interim and Arctic System Reanalyses

Atmospheric Chemistry and Physics ◽

10.5194/acp-16-12383-2016 ◽

2016 ◽

Vol 16 (19) ◽

pp. 12383-12396

Author(s):

Tjarda J. Roberts ◽

Marina Dütsch ◽

Lars R. Hole ◽

Paul B. Voss

Keyword(s):

Boundary Layer ◽

Wind Shear ◽

Marine Boundary Layer ◽

Temperature Inversion ◽

The Arctic ◽

Small Scale ◽

Strong Wind ◽

Free Atmosphere ◽

Free Region ◽

Temperature And Humidity

Abstract. Observations from CMET (Controlled Meteorological) balloons are analysed to provide insights into tropospheric meteorological conditions (temperature, humidity, wind) around Svalbard, European High Arctic. Five Controlled Meteorological (CMET) balloons were launched from Ny-Ålesund in Svalbard (Spitsbergen) over 5–12 May 2011 and measured vertical atmospheric profiles over coastal areas to both the east and west. One notable CMET flight achieved a suite of 18 continuous soundings that probed the Arctic marine boundary layer (ABL) over a period of more than 10 h. Profiles from two CMET flights are compared to model output from ECMWF Era-Interim reanalysis (ERA-I) and to a high-resolution (15 km) Arctic System Reanalysis (ASR) product. To the east of Svalbard over sea ice, the CMET observed a stable ABL profile with a temperature inversion that was reproduced by ASR but not captured by ERA-I. In a coastal ice-free region to the west of Svalbard, the CMET observed a stable ABL with strong wind shear. The CMET profiles document increases in ABL temperature and humidity that are broadly reproduced by both ASR and ERA-I. The ASR finds a more stably stratified ABL than observed but captured the wind shear in contrast to ERA-I. Detailed analysis of the coastal CMET-automated soundings identifies small-scale temperature and humidity variations with a low-level flow and provides an estimate of local wind fields. We demonstrate that CMET balloons are a valuable approach for profiling the free atmosphere and boundary layer in remote regions such as the Arctic, where few other in situ observations are available for model validation.

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