New Applications of Spin-Crossover Complexes: Microwave Absorption, Chirooptical Switching and Enantioselective Detection

2020 ◽  
pp. 119-143
Author(s):  
Olesia I. Kucheriv ◽  
Viktor V. Oliynyk ◽  
Volodymyr V. Zagorodnii ◽  
Vilen L. Launets ◽  
Igor O. Fritsky ◽  
...  
Keyword(s):  
Microwave Absorption ◽  
Spin Crossover ◽  
Spin Crossover Complexes ◽  
New Applications

scholarly journals Tunable microwave absorption of switchable complexes operating near room temperature

RSC Advances ◽  
2020 ◽  
Vol 10 (36) ◽  
pp. 21621-21628
Author(s):  
Olesia I. Kucheriv ◽  
Viktor V. Oliynyk ◽  
Volodymyr V. Zagorodnii ◽  
Vilen L. Launets ◽  
Olena V. Penkivska ◽  
...  
Keyword(s):  
Microwave Absorption ◽  
Room Temperature ◽  
Spin Crossover ◽  
Microwave Switches ◽  
Tunable Microwave ◽  
Spin Crossover Complexes

Iron(ii) spin-crossover complexes are shown to be effective microwave switches operating near room temprature.

A New Family of Anionic FeIII Spin Crossover Complexes Featuring a Weak-Field N2 O4 Coordination Octahedron

2015 ◽  
Vol 22 (4) ◽  
pp. 1253-1257 ◽  
Author(s):  
Kazuyuki Takahashi ◽  
Kiko Kawamukai ◽  
Mitsunobu Okai ◽  
Tomoyuki Mochida ◽  
Takahiro Sakurai ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Weak Field ◽  
New Family ◽  
Spin Crossover Complexes

Relevance of supramolecular interactions, texture and lattice occupancy in the designer iron(II) spin crossover complexes

2009 ◽  
Vol 182 (6) ◽  
pp. 1365-1376 ◽  
Author(s):  
Anil D. Naik ◽  
Bernard Tinant ◽  
Kai Muffler ◽  
Juliusz A. Wolny ◽  
Volker Schünemann ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Supramolecular Interactions ◽  
Spin Crossover Complexes

Asymmetric Design of Spin-Crossover Complexes to Increase the Volatility for Surface Deposition

2021 ◽  
Author(s):  
Miguel Gakiya-Teruya ◽  
Xuanyuan Jiang ◽  
Duy Le ◽  
Ökten Üngör ◽  
Abdullah J. Durrani ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Surface Deposition ◽  
Spin Crossover Complexes

Targeted structural modification of spin crossover complexes: pyridine vs pyrazine

2017 ◽  
Vol 30 (4) ◽  
pp. 296-304 ◽  
Author(s):  
Humphrey L. C. Feltham ◽  
Matthew G. Cowan ◽  
Jonathan A. Kitchen ◽  
Guy N. L. Jameson ◽  
Sally Brooker
Keyword(s):  
Structural Modification ◽  
Spin Crossover ◽  
Spin Crossover Complexes

scholarly journals CASPT2 molecular geometries of Fe(II) spin-crossover complexes

2021 ◽  
Author(s):  
Brian A. Finney ◽  
Sabyasachi Roy Chowdhury ◽  
Clara Kirkvold ◽  
Bess Vlaisavljevich
Keyword(s):  
Spin Crossover ◽  
Spin Crossover Complexes ◽  
Analytical Gradients

Using fully internally contracted (FIC)-CASPT2 analytical gradients, geometry optimizations of spin-crossover complexes are reported. This approach is tested on a series of Fe(II) complexes with different sizes, ranging from 13...

Preparation of dihydroquinazoline carbohydrazone Fe(ii) complexes for spin crossover

2016 ◽  
Vol 40 (5) ◽  
pp. 4534-4542 ◽  
Author(s):  
Fu-Xing Shen ◽  
Wei Huang ◽  
Takashi Yamamoto ◽  
Yasuaki Einaga ◽  
Dayu Wu
Keyword(s):  
Spin Crossover ◽  
Spin Crossover Complexes

Mononuclear spin-crossover complexes of dihydroquinazoline derivatives were synthesized to enable the spin crossover phenomenon via the variation of the solvent, anion and substituent.

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