Characterization of Chemically Modified Gold/Silver Superatoms in the Gas Phase

Author(s):  
Kiichirou Koyasu ◽  
Keisuke Hirata ◽  
Tatsuya Tsukuda
2019 ◽  
Vol 21 (32) ◽  
pp. 17463-17474 ◽  
Author(s):  
Keisuke Hirata ◽  
Ryohei Tomihara ◽  
Kuenhee Kim ◽  
Kiichirou Koyasu ◽  
Tatsuya Tsukuda

This perspective summarizes our recent efforts in the application of gas-phase characterization methods to ligand-protected Au/Ag clusters chemically synthesized with atomic precision.


2018 ◽  
Vol 68 (12) ◽  
pp. 2799-2803
Author(s):  
Maria Daniela Pop ◽  
Oana Brincoveanu ◽  
Mihaela Cristea ◽  
George Octavian Buica ◽  
Marius Enachescu ◽  
...  

Preparation and microscopy characterization of polymer modified glassy carbon electrodes based on (5-[(azulen-1-yl) methylene]-2-thioxothiazolidin-4-one (L) were reported. Atomic Force Microscopy was used to investigate the morphological and mechanical properties of the deposited polyL films onto glassy carbon. The topography images of the analyzed samples exhibited the presence of some columnar shape features onto the layer surfaces. The surface roughness of the layers deposited at constant charge calculated from topography images, increased with the more positive applied potential for controlled potential electrolysis. At different charges, the roughness parameter showed the same behavior for the layers obtained applying a constant potential without having a noticeable influence on the adhesion properties on the substrate. Analysis using scanning electron microscopy shows a relatively uniform surface arrangement of the polymer and the presence of some clusters which are disturbing the planarity. PolyL chemically modified electrodes have been used for heavy metal ions detection with best results for lead.


2020 ◽  
Vol 11 (45) ◽  
pp. 12233-12248
Author(s):  
Haru Hirai ◽  
Shun Ito ◽  
Shinjiro Takano ◽  
Kiichirou Koyasu ◽  
Tatsuya Tsukuda

This perspective summarizes the current status and emerging trends in synthesis and characterization of ligand-protected gold/silver superatoms.


LWT ◽  
2021 ◽  
Vol 142 ◽  
pp. 110983
Author(s):  
Dingpeng Zhou ◽  
Shaowei Liu ◽  
Haoyu Song ◽  
Xue Liu ◽  
Xiaozhi Tang

2021 ◽  
pp. 1-13
Author(s):  
Li Tan ◽  
Ning Wang ◽  
Yingjian Dong ◽  
Siyuan Li ◽  
Xuehan Wang ◽  
...  

2019 ◽  
Vol 150 (14) ◽  
pp. 144304 ◽  
Author(s):  
Anh T. Le ◽  
Sanjay G. Nakhate ◽  
Duc-Trung Nguyen ◽  
Timothy C. Steimle ◽  
Michael C. Heaven
Keyword(s):  

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