In-situ high-temperature Raman spectroscopic studies of aluminosilicate liquids

1995 ◽  
Vol 22 (2) ◽  
Author(s):  
Isabelle Daniel ◽  
Philippe Gillet ◽  
BrentT. Poe ◽  
PaulF. McMillan
2019 ◽  
Author(s):  
WENDI Liu ◽  
Yan Yang ◽  
Zeming Qi ◽  
Zhongping Wang ◽  
Weihua Huang ◽  
...  

2001 ◽  
Vol 17 (10) ◽  
pp. 908-912
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Yan Wei ◽  
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Wei Zhi-Xiang ◽  
Wang Li-Li ◽  
...  

2002 ◽  
Vol 47 (9) ◽  
pp. 1475-1480 ◽  
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Li-Jiang Chen ◽  
Xuan Cheng ◽  
Chang-Jian Lin ◽  
Chao-Ming Huang

Materials ◽  
2020 ◽  
Vol 13 (23) ◽  
pp. 5453
Author(s):  
Min Wang ◽  
Changhao Wang ◽  
Jian Wang ◽  
Liming Lu ◽  
Xiaoye Gong ◽  
...  

In situ high-temperature Raman spectra of polycrystalline KBi(MoO4)2 were recorded from room temperature to 1073 K. Thermal stability of the monoclinic KBi(MoO4)2 was examined by temperature-dependent XRD. The monoclinic phase transformed into the scheelite tetragonal structure at 833 K, and then to the monoclinic phase at 773 K. Quantum chemistry ab initio calculation was performed to simulate the Raman spectra of the structure of KBi(MoO4)2 high-temperature melt. The experimental Raman band at 1023 K was deconvoluted into seven Gaussian peaks, and the calculated results were in good agreement with the experimental data. Therefore, the vibrational modes of Raman peaks of molten KBi(MoO4)2 were assigned. It was confirmed that the isolated structure of [Bi(MoO4)2]− monomer, consisting of Mo6+ centers and Bi3+ sub-centers connected by edge-sharing, mainly exists in the melt of KBi(MoO4)2.


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