The state of anthraquinone in sulfuric acid (UV and IR spectra)

1967 ◽  
Vol 1 (6) ◽  
pp. 565-568
Author(s):  
V. V. Kozlov ◽  
Yu. A. Kolesnik ◽  
L. A. Kazitsyna
1970 ◽  
Vol 12 (3) ◽  
pp. 393-396
Author(s):  
K. A. Nuridzhanyan ◽  
V. G. Blinova

1987 ◽  
Vol 41 (1) ◽  
pp. 74-79
Author(s):  
A. Obaid ◽  
S. Basahl ◽  
A. Diefallah ◽  
R. Abu-Eittah

Solids of 3-iodo-, 3–5–di-iodotyrosine and 3,5-di-iodothyronine were irradiated by 60Co-gamma irradiation for a period of about twenty hours. The effects of irradiation were investigated through a study of the UV and IR spectra of irradiated samples. UV spectra showed the presence of a new band at 360 nm which was assigned to the formation of IO−. IR spectra showed a strong carbonyl absorption and the removal of the carboxylate band in the case of thyronine only. For comparison, the spectra of the studied compounds were investigated before irradiation.


2011 ◽  
Vol 402 ◽  
pp. 51-56 ◽  
Author(s):  
Fa Xin Xiao ◽  
Dao Cao ◽  
Jian Wei Mao ◽  
Xiao Ni Shen

This paper aims to discover the mechanism of removal of arsenic and bismuth from copper electrolyte under the function of antimony. The precipitate was obtained from a synthetic copper electrolyte containing 185g/L sulfuric acid, 45g/LCu2+, 10g/LAs, 0.5g/LBi and 1.2g/LSb. The structure, morphology and component of the precipitate are clarified by methods of chemical analysis, SEM, XRD, TEM and IR spectroscopy. The precipitate consists of 27.08% arsenic, 15.12% antimony, 12.08% bismuth. There are many irregular blocks, and dendritic particles on the surface.The characteristic bands in the IR spectra of the precipitate are O–H, As–OH, As–O, As–OX (X=As, Sb, Bi), Sb–OH and O–As–O. The precipitate is a mixture of microcrystalline of BiSb2O7, Bi12As2O23, SbAsO4 and (Sb,As)2O3 by XRD and electronic diffraction. The impurities of As, Sb and Bi are removed from copper electrolyte by antimony attributing to these precipitate.


ChemInform ◽  
2010 ◽  
Vol 26 (31) ◽  
pp. no-no
Author(s):  
K. JOHNSSON ◽  
A. ENGDAHL ◽  
B. NELANDER
Keyword(s):  

1962 ◽  
Vol 39 (3) ◽  
pp. 385-394 ◽  
Author(s):  
Wilhelm Dirscherl ◽  
Helmut Thomas ◽  
Herbert Schriefers

ABSTRACT In rat livers perfused with 3-methoxy-4-hydroxy-mandelic acid, formerly believed to be the endproduct of the metabolism of adrenaline and noradrenaline, three metabolites were detected by paper chromatography. After further purification by column chromatography, one of these substances was identified by melting point, shape of crystals, UV- and IR-spectra as vanillic acid. Perfusion with vanillic acid yielded only one metabolite in very small quantities. Because of its properties it is assumed to be a conjugate of vanillic acid. Hence vanillic acid, isolated in 1959 from human urine by Dirscherl & Schmidtmann, is the actual endproduct of the metabolism of adrenaline and noradrenaline.


1979 ◽  
Vol 34 (8) ◽  
pp. 1101-1106 ◽  
Author(s):  
A. G. Galinos ◽  
J. K . Kouinis ◽  
P. V. Ioannou ◽  
Th. F . Zafiropoulos ◽  
S. P. Perlepes

The preparation of sixteen new etherate, pyridine and aniline compounds of complex halo and pseudohalo acids of Zn(II) is reported.The study of some physical and chemical properties as well as the UV and IR spectra of these compounds are discussed. Tetrahedral structures are proposed for all compounds in the solid state


1976 ◽  
Vol 31 (8) ◽  
pp. 1099-1105 ◽  
Author(s):  
A. Scheffler ◽  
W. Preetz

The preparation of mer-[OsX3B3], X = Cl, Br, I; B = pyridine, 3-resp. 4-picoline, pyrimidine, pyrazine, methylpyrazine, and the chromatographic isolation of four basemixed stereoisomers mer-[OsX3(py)n(mepyz)3-n], n= 1, 2, as solid crystalline products is described. Mass spectra and ligand exchange reactions confirm the structure of these complexes. The UV and IR spectra are discussed.


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