Air-oxidation kinetics of hafnium alloys containing platinum and palladium

1984 ◽  
Vol 6 (1) ◽  
pp. 3-13
Author(s):  
J. R. Ogren
2016 ◽  
Vol 35 (4) ◽  
pp. 353-359
Author(s):  
S. Liu ◽  
Q. Q. Guo ◽  
L. L. Liu ◽  
L. Xu ◽  
Y. Y. Liu

AbstractThe oxidation behavior of Ti-5Al-2.5Sn and Ti-6Al-4V produced by hot isostatic pressing (HIP) has been studied at 650–850°C in air for 24 h. The oxidation kinetics of both alloys followed the parabolic law with good approximation, except for Ti-5Al-2.5Sn oxidized at 850°C. Multi-layered scales formed on both alloys at 750°C and 850°C. Ternary additions of Sn and V accounted for the different morphology of the scales formed on these two alloys. In addition, the oxidation behavior of HIP alloys is compared with that of the corresponding cast alloys and the scaling mechanism is discussed.


Author(s):  
Suverna Trivedi ◽  
Ram Prasad ◽  
S. Chadha

This paper describes the kinetics of catalytic air oxidation of propane. The kinetics data were collected in a plug flow tubular reactor. The experiments were performed over the NiCo2O4 catalyst prepared by co-precipitation method followed by calcination at 400 oC. The kinetic data were collected under the following conditions: 200 mg of catalyst, 2.5 % of propane in air, total flow rate of 60 mL/min, and temperature ranges of 130-170 oC. The data were fitted to the power law rate equation. The activation    energy and frequency factor were found to be 59.3 kJ/g mol and 2.9×108 (mol)0.47.L0.53/g cat.h, respectively. Copyright © 2017 BCREC Group. All rights reservedReceived: 20th November 2016; Revised: 26th February 2017; Accepted: 26th February 2017How to Cite: Trivedi, S., Prasad, R., Chadha, S. (2017). Oxidation Kinetics of Propane-Air Mixture over NiCo2O4 Catalyst Emitted from LPG Vehicles. Bulletin of Chemical Reaction Engineering & Catalysis, 12 (2): 191-196 (doi:10.9767/bcrec.12.2.798.191-196)Permalink/DOI: http://dx.doi.org/10.9767/bcrec.12.2.798.191-196 


2009 ◽  
Vol 283-286 ◽  
pp. 209-213 ◽  
Author(s):  
Dong Ya Huang ◽  
Xiang Jin Zhao ◽  
Tao Zhang ◽  
Vincent Ji

The isothermal oxidation behavior of Zr58Nb3Cu16Ni13Al10 bulk metallic glass (BMG) under dry air in the glassy state and the supercooled liquid state (SLS) was studied by the thermogravimetric method. The oxidation rate and thickness growth speed in the SLS were both hugely higher than in the glassy state. The oxidation kinetics of BMG in both states for 1.5 hours was different, the parabolic law was followed in the glassy state at 300°C and 350°C, contrarily the linear law was followed in SLS at 400 °C. After the oxidation for 126 hours in SLS, the oxidation kinetics possessed two stages, the linear stage and the parabolic stage. The diffusion of the Cu2+ ion and CuZr intermetallic alloys were detected by GIXRD.


1998 ◽  
Author(s):  
J. Abrefah ◽  
H.C. Buchanan ◽  
W.M. Gerry ◽  
W.J. Gray ◽  
S.C. Marschman

2020 ◽  
Author(s):  
Camilo A. Mesa ◽  
Ludmilla Steier ◽  
Benjamin Moss ◽  
Laia Francàs ◽  
James E. Thorne ◽  
...  

<p><i>Operando</i> spectroelectrochemical analysis is used to determine the water oxidation reaction kinetics for hematite photoanodes prepared using four different synthetic procedures. Whilst these photoanodes exhibit very different current / voltage performance, their underlying water oxidation kinetics are found to be almost invariant. Lower photoanode performance was found to correlate with the observation of optical signals indicative of charge accumulation in mid-gap oxygen vacancy states, indicating these states do not contribute directly to water oxidation.</p>


1998 ◽  
Vol 32 (19) ◽  
pp. 2990-2996 ◽  
Author(s):  
Lukas Emmenegger ◽  
D. Whitney King ◽  
Laura Sigg ◽  
Barbara Sulzberger

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