Investigations of self- and tracer diffusion in poly(ethylene oxides) and in blends of poly(dimethyl/ethylmethyl siloxanes) with the pulsed field gradient NMR

2007 ◽  
pp. 55-57 ◽  
Author(s):  
G. Fleischer
Keyword(s):  
Field Gradient ◽  
Tracer Diffusion ◽  
Pulsed Field Gradient Nmr ◽  
Pulsed Field ◽  
Poly Ethylene

Controlling Gas Selectivity in Molecular Porous Liquids by Tuning the Cage Window Size

2019 ◽  
Author(s):  
Benjamin Egleston ◽  
Konstantin V. Luzyanin ◽  
Michael C. Brand ◽  
Rob Clowes ◽  
Michael E. Briggs ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Chemical Synthesis ◽  
Field Gradient ◽  
Window Size ◽  
Standard Approach ◽  
Porous Solids ◽  
Pulsed Field Gradient Nmr ◽  
Pulsed Field ◽  
Cage Molecules ◽  
Gas Selectivity

Control of pore window size is the standard approach for tuning gas selectivity in porous solids. Here, we present the first example where this is translated into a molecular porous liquid formed from organic cage molecules. Reduction of the cage window size by chemical synthesis switches the selectivity from Xe-selective to CH<sub>4</sub>-selective, which is understood using <sup>129</sup>Xe, <sup>1</sup>H, and pulsed-field gradient NMR spectroscopy.

Controlling Gas Selectivity in Molecular Porous Liquids by Tuning the Cage Window Size

2019 ◽  
Author(s):  
Benjamin Egleston ◽  
Konstantin V. Luzyanin ◽  
Michael C. Brand ◽  
Rob Clowes ◽  
Michael E. Briggs ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Chemical Synthesis ◽  
Field Gradient ◽  
Window Size ◽  
Standard Approach ◽  
Porous Solids ◽  
Pulsed Field Gradient Nmr ◽  
Pulsed Field ◽  
Cage Molecules ◽  
Gas Selectivity

Control of pore window size is the standard approach for tuning gas selectivity in porous solids. Here, we present the first example where this is translated into a molecular porous liquid formed from organic cage molecules. Reduction of the cage window size by chemical synthesis switches the selectivity from Xe-selective to CH<sub>4</sub>-selective, which is understood using <sup>129</sup>Xe, <sup>1</sup>H, and pulsed-field gradient NMR spectroscopy.

Lithium-ion diffusivity in complex hydrides: Pulsed-field-gradient NMR studies of LiLa(BH4)3Cl, Li3(NH2)2I and Li-1-CB9H10

2021 ◽  
Vol 362 ◽  
pp. 115585
Author(s):  
A.V. Skripov ◽  
G. Majer ◽  
O.A. Babanova ◽  
R.V. Skoryunov ◽  
A.V. Soloninin ◽  
...  
Keyword(s):  
Field Gradient ◽  
Lithium Ion ◽  
Nmr Studies ◽  
Pulsed Field Gradient Nmr ◽  
Pulsed Field ◽  
Complex Hydrides
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