ROx Budgets and O3 Formation during Summertime at Xianghe Suburban Site in the North China Plain

2021 ◽  
Author(s):  
Min Xue ◽  
Jianzhong Ma ◽  
Guiqian Tang ◽  
Shengrui Tong ◽  
Bo Hu ◽  
...  
Keyword(s):  
North China Plain ◽  
North China ◽  
The North ◽  
The North China Plain ◽  
Suburban Site

scholarly journals Atmospheric reactivity and oxidation capacity during summer at a suburban site between Beijing and Tianjin

2020 ◽  
Vol 20 (13) ◽  
pp. 8181-8200
Author(s):  
Yuan Yang ◽  
Yonghong Wang ◽  
Putian Zhou ◽  
Dan Yao ◽  
Dongsheng Ji ◽  
...  
Keyword(s):  
North China Plain ◽  
North China ◽  
Transport Model ◽  
Oh Radicals ◽  
Chemical Transport Model ◽  
Oxidation Capacity ◽  
The North ◽  
The North China Plain ◽  
Atmospheric Reactivity ◽  
Suburban Site

Abstract. Hydroxyl (OH) radicals, nitrate (NO3) radicals and ozone (O3) play central roles in the troposphere because they control the lifetimes of many trace gases that result from anthropogenic and biogenic origins. To estimate the air chemistry, the atmospheric reactivity and oxidation capacity were comprehensively analyzed based on a parameterization method at a suburban site in Xianghe in the North China Plain from 6 July 2018 to 6 August 2018. The total OH, NO3 and O3 reactivities at the site varied from 9.2 to 69.6, 0.7 to 27.5 and 3.3×10-4 to 1.8×10-2 s−1 with campaign-averaged values of 27.5±9.7, 2.2±2.6 and 1.2±1.7×10-3 s−1 (± standard deviation), respectively. NOx (NO+NO2) was by far the main contributor to the reactivities of the three oxidants, with average values of 43 %–99 %. Alkenes dominated the OH, NO3 and O3 reactivities towards total nonmethane volatile organic compounds (NMVOCs), accounting for 42.9 %, 77.8 % and 94.0 %, respectively. The total OH, NO3 and O3 reactivities displayed similar diurnal variations with the lowest values during the afternoon but the highest values during rush hours, and the diurnal profile of NOx appears to be the major driver for the diurnal profiles of the reactivities of the three oxidants. A box model (a model to Simulate the concentrations of Organic vapors, Sulfuric Acid and Aerosols; SOSAA) derived from a column chemical transport model was used to simulate OH and NO3 concentrations during the observation period. The calculated atmospheric oxidation capacity (AOC) reached 4.5×108 moleculescm-3s-1, with a campaign-averaged value of 7.8×107 moleculescm-3s-1 dominated by OH (7.7×107 moleculescm-3s-1, 98.2 %), O3 (1.2×106 moleculescm-3s-1, 1.5 %) and NO3 (1.8×105 moleculescm-3s-1, 0.3 %). Overall, the integration of OH, NO3 and O3 reactivities analysis could provide useful insights for NMVOC pollution control in the North China Plain. We suggest that further studies, especially direct observations of OH and NO3 radical concentrations and their reactivities, are required to better understand trace gas reactivity and AOC.

Evolution of boundary layer ozone in Shijiazhuang, a suburban site on the North China Plain

2019 ◽  
Vol 83 ◽  
pp. 152-160 ◽  
Author(s):  
Wei Zhao ◽  
Guiqian Tang ◽  
Huan Yu ◽  
Yang Yang ◽  
Yinghong Wang ◽  
...  
Keyword(s):  
Boundary Layer ◽  
North China Plain ◽  
North China ◽  
The North ◽  
The North China Plain ◽  
Boundary Layer Ozone ◽  
Suburban Site

scholarly journals Dust Properties and Radiative Impacts at a Suburban Site during 2004–2017 in the North China Plain

2019 ◽  
Vol 11 (16) ◽  
pp. 1842 ◽  
Author(s):  
Jinqiang Zhang ◽  
Xiangao Xia ◽  
Xuemei Zong ◽  
Xuehua Fan ◽  
Hongbin Chen ◽  
...  
Keyword(s):  
North China Plain ◽  
North China ◽  
Long Range Transport ◽  
Radiative Effects ◽  
Dust Aerosols ◽  
The North ◽  
The North China Plain ◽  
Range Transport ◽  
Dust Events ◽  
Suburban Site

Aerosols and their radiative effects are of primary interest in climate research because of their vital influence on climate change. Dust aerosols are an important aerosol type in the North China Plain (NCP), mainly as a result of long-range transport, showing substantial spatiotemporal variations. By using measurements from the Aerosol Robotic Network (AERONET) between September 2004 and May 2017, and the space-borne Moderate Resolution Imaging Spectroradiometer (MODIS) and Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) aerosol products, we investigated the properties of dust aerosols and their radiative effects at Xianghe (XH)—a suburban site in the NCP. Dust events occurred most frequently during spring (a total of 105 days) relative to the other three seasons (a total of 41 days) during the periods concerned. The dust aerosol optical depth (AOD) at 675 nm was at a maximum in spring (0.60 ± 0.44), followed (in decreasing order) by those in autumn (0.58 ± 0.39), summer (0.54 ± 0.15), and winter (0.53 ± 0.23). Cooling effects of dust aerosol radiative forcing (RF) at the bottom and top of the atmosphere tended to be strongest in spring (−96.72 ± 45.69 and −41.87 ± 19.66 Wm−2) compared to that in summer (−57.08 ± 18.54 and −25.54 ± 4.45 Wm−2), autumn (−72.01 ± 27.27 and −32.54 ± 15.18 Wm−2), and winter (−79.57 ± 32.96 and −37.05 ± 17.06 Wm−2). The back-trajectory analysis indicated that dust air mass at 500 m that arrived at XH generally originated from the Gobi and other deserts of northern China and Mongolia (59.8%), and followed by northwest China and Kazakhstan (37.2%); few dust cases came from northeast China (3.0%). A single-peaked structure with the maximum occurring at ~2 km was illustrated by all dust events and those sorted by their sources in three directions. Three typical dust events were specifically discussed to better reveal how long-range transport impacted the dust properties and radiative effects over the NCP. The results presented here are expected to improve our understanding of the physical properties of dust aerosols over the NCP and their major transport path and significant impacts on the regional solar radiation budget.

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