Viscosity enhancement In non-Newtonian flow of dilute polymer solutions through crystallographic porous media

2003 ◽  
Vol 42 (6) ◽  
pp. 516-526 ◽  
Author(s):  
Simon J. Haward ◽  
Jeffrey A. Odell
2021 ◽  
Vol 5 (2) ◽  
pp. 22
Author(s):  
Karthik Nagarajan ◽  
Shing Bor Chen

Driven transport of dilute polymer solutions through porous media has been simulated using a recently proposed novel dissipative particle dynamics method satisfying the no-penetration and no-slip boundary conditions. The porous media is an array of overlapping spherical cavities arranged in a simple cubic lattice. Simulations were performed for linear, ring, and star polymers with 12 arms for two cases with the external force acting on (I) both polymer and solvent beads to model a pressure-driven flow; (II) polymer beads only, similar to electrophoresis. When the external force is in the direction of a principal axis, the extent of change in the polymers’ conformation and their alignment with the driving force is more significant for case I. These effects are most pronounced for linear chains, followed by rings and stars at the same molecular weight. Moreover, the polymer mean velocity is affected by its molecular weight and architecture as well as the direction and strength of the imposed force.


2002 ◽  
Vol 469 ◽  
pp. 237-256 ◽  
Author(s):  
ANKE LINDNER ◽  
DANIEL BONN ◽  
EUGENIA CORVERA POIRÉ ◽  
MARTINE BEN AMAR ◽  
JACQUES MEUNIER

We study the viscous fingering or Saffman–Taylor instability in two different dilute or semi-dilute polymer solutions. The different solutions exhibit only one non-Newtonian property, in the sense that other non-Newtonian effects can be neglected. The viscosity of solutions of stiff polymers has a strong shear rate dependence. Relative to Newtonian fluids, narrower fingers are found for rigid polymers. For solutions of flexible polymers, elastic effects such as normal stresses are dominant, whereas the shear viscosity is almost constant. Wider fingers are found in this case. We characterize the non-Newtonian flow properties of these polymer solutions completely, allowing for separate and quantitative investigation of the influence of the two most common non-Newtonian properties on the Saffman–Taylor instability. The effects of the non-Newtonian flow properties on the instability can in all cases be understood quantitatively by redefining the control parameter of the instability.


1999 ◽  
Vol 2 (3) ◽  
pp. 251-262
Author(s):  
P. Gestoso ◽  
A. J. Muller ◽  
A. E. Saez

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