Metallic Oxides for Innovative Refrigerant Thermo-Physical Properties: Mathematical Models

Nano-refrigerant is announced to become an excellent refrigerant, which often improves heat transfer efficiency in the cooling systems. Different materials can be applied to be suspended in traditional coolants in the same way as nanoparticles. In this comprehensive research, mathematical modeling was used to investigate the effect of suspended nanoparticles (Al2O3, CuO, SiO2 and ZnO) on 1,1,1,2-Tetrafluoroethane, R-134a. The thermal conductivity, dynamic viscosity, density and specific heat capacity of the nano-refrigerant in an evaporator pipe were investigated. Compared to conventional refrigerants, the maximum increase in thermal conductivity was achieved by Al2O3/R-134a (96.23%) at a volume concentration of 0.04. At the same time, all nano-refrigerant types presented the same viscosity enhancement of(45.89%) at the same conditions. These types of complex thermophysical properties have enhanced the heat transfer tendencies in the pipe. Finally, the nano-refrigerant could be a likely working fluid generally used in the cooling unit to improve high-temperature transfer characteristics and save energy use.

pH-Responsive Rheological Properties and Microstructure Transition in Mixture of Anionic Gemini/Cationic Monomeric Surfactants

Surfactant aggregates have long been considered as a tool to improve drug delivery and have been widely used in medical products. The pH-responsive aggregation behavior in anionic gemini surfactant 1,3-bis(N-dodecyl-N-propanesulfonate sodium)-propane (C12C3C12(SO3)2) and its mixture with a cationic monomeric surfactant cetyltrimethylammonium bromide (CTAB) have been investigated. The spherical-to-wormlike micelle transition was successfully realized in C12C3C12(SO3)2 through decreasing the pH, while the rheological properties were perfectly enhanced for the formation of wormlike micelles. Especially at 140 mM and pH 6.7, the mixture showed high viscoelasticity, and the maximum of the zero-shear viscosity reached 1530 Pa·s. Acting as a sulfobetaine zwitterionic gemini surfactant, the electrostatic attraction, the hydrogen bond and the short spacer of C12C3C12(SO3)2 molecules were all responsible for the significant micellar growth. Upon adding CTAB, the similar transition could also be realized at a low pH, and the further transformation to branched micelles occurred by adjusting the total concentration. Although the mixtures did not approach the viscosity maximum appearing in the C12C3C12(SO3)2 solution, CTAB addition is more favorable for viscosity enhancement in the wormlike-micelle region. The weakened charges of the headgroups in a catanionic mixed system minimizes the micellar spontaneous curvature and enhances the intermolecular hydrogen-bonding interaction between C12C3C12(SO3)2, facilitating the formation of a viscous solution, which would greatly induce entanglement and even the fusion of wormlike micelles, thus resulting in branched microstructures and a decline of viscosity.

Effects of Particle Combinations With Different Wettability on Foam Structure and Stability

Particle addition is an important method to prepare foam metal, and it is of great significance to clarify the mechanism of particle stabilizing liquid metal foam. In this paper, ethanol-water solution system is used to simulate liquid melt foam. By changing the wettability of particles to adjust the distribution position of particles in foam, two types of particles with different wettability are added, which are mixed and optimized in a certain proportion to improve the foam stability as much as possible. The main mechanism is that the large wetting angle particles at the gas-liquid interface to slow down the gas migration, while small wetting angle particles exist in the liquid film, which can reduce the liquid drainage velocity. The experimental results show that the effect of particle wettability on foam structure is greater than that on viscosity enhancement. The particles with large wetting angle are beneficial to the formation and stability of foam, and the particles with small wetting angle cannot stabilize the foam alone. The effect of two types of particle combinations with different wettability on foam stability is better than that of single type of particle. Considering the height and uniformity of the foam structure, the optimal particle combination is finally obtained.

Molecular Rotors with Aggregation-Induced Emission (AIE) as Fluorescent Probes for the Control of Polyurethane Synthesis

In this work, the use of fluorescent molecular rotors such as 9-(2,2-dicyanovinyl)julolidine (DCVJ) and 2,3-bis(4-(phenyl(4-(1,2,2-triphenylvinyl) phenyl)amino)phenyl)fumaronitrile (TPETPAFN) was proposed for the real-time monitoring of polyurethane (PU) formation in a solution of dimethylacetamide starting with 4,4′-methylenediphenyl diisocyanate (MDI) and different polyethylene glycols (PEG400 and PEG600) as diols. Notably, relative viscosity variations were compared with fluorescence changes, recorded as a function of the polymerization progress. The agreement between these two parameters suggested the innovative use of a low-cost fluorescence detection system based on a LED/photodiode assembly directly mountable on the reaction apparatus. The general validity of the proposed experiments enabled the monitoring of polyurethane polymerization and suggested its effective applications to a variety of industrial polymers, showing viscosity enhancement during polymerization.

Dry Tablet Formulation of PLGA Nanoparticles with a Preocular Applicator for Topical Drug Delivery to the Eye

To enhance ocular drug bioavailability, a rapidly dissolving dry tablet containing alginate and drug-loaded poly(lactic-co-glycolic acid) (PLGA) nanoparticles was proposed. For hygienic and easy administration of an accurate drug-dose with this tablet, the use of a preocular applicator was suggested. Herein, a dry tablet was prepared by embedding dexamethasone-loaded PLGA nanoparticles in alginate, which was deposited on the tip of the applicator. The nanoparticles were loaded with 85.45 μg/mg drug and exhibited sustained drug release for 10 h. To evaluate in vivo efficacy, dexamethasone concentration in the aqueous humor was measured after topical administration of the dry tablet, with the applicator, to rabbit eyes and was compared to that achieved with Maxidex®, a commercially-available dexamethasone eye drops. When applied with the preocular applicator, the dry tablet containing alginate could be fully detached and delivered to the eye surface. In fact, it showed up to 2 h of nanoparticle retention on the preocular surface due to tear viscosity enhancement, causing an estimated 2.6-fold increase in ocular drug bioavailability compared to Maxidex®. Therefore, the preocular applicator combined with a dry alginate tablet containing PLGA nanoparticles can be a promising system for aseptically delivering an accurate dose of ophthalmic drug with enhanced bioavailability.

Effects of Temperature and Particles Concentration on the Dynamic Viscosity of Graphene-NiO/Coconut Oil Hybrid Nanofluid: Experimental Study

In practice, lubricants are used to minimize the friction and wear of frictional surfaces. The disposal of mineral-based lubricating oil possesses environmental issues and forced the development of bio-degradable lubricating agents. The simultaneous mono-dispersion of metallic and metal oxides nanomaterials into lubricating agents may concurrently reveal superior thermo-physical and rheological characteristics. This paper proposes an experimental and theoretical investigation on the dynamic viscosity enhancement of flat platelets textured Graphene/NiO-coconut oil hybrid nanofluids. The results reveal that the dynamic viscosity enhancement of hybrid nanofluids increases with nanomaterial concentration and decreases with temperature. The squat hybrid nanomaterial concentration has less collusion probability and dynamic contact between the mono-dispersed hybrid nanomaterials as it has enough interfacing gaps to conquer superficial surface energy. The high nanomaterial concentration revamps the formation of lamellar-composite agglomerated particles and enhances the dynamic viscosity of base fluid. Further, a theoretical correlation is recommended to estimate the dynamic viscosity of hybrid nanofluid with minimum margin of deviation using artificial neural network (ANN).