Petrogenesis of tholeiite associations in Kudi ophiolite (western Kunlun Mountains, northwestern China): implications for the evolution of back-arc basins

2002 ◽  
Vol 143 (4) ◽  
pp. 471-483 ◽  
Author(s):  
Zhihong Wang ◽  
Shu Sun ◽  
Jiliang Li ◽  
Quanlin Hou
2020 ◽  
Vol 115 (7) ◽  
pp. 1559-1588
Author(s):  
Bang-Lu Zhang ◽  
Chang-Le Wang ◽  
Leslie J. Robbins ◽  
Lian-Chang Zhang ◽  
Kurt O. Konhauser ◽  
...  

Abstract The Upper Carboniferous Ortokarnash manganese ore deposit in the West Kunlun orogenic belt of the Xinjiang province in China is hosted in the Kalaatehe Formation. The latter is composed of three members: (1) the 1st Member is a volcanic breccia limestone, (2) the 2nd Member is a sandy limestone, and (3) the 3rd Member is a dark gray to black marlstone containing the manganese carbonate mineralization, which, in turn, is overlain by sandy and micritic limestone. This sequence represents a single transgression-regression cycle, with the manganese deposition occurring during the highstand systems tract. Geochemical features of the rare earth elements (REE+Y) in the Kalaatehe Formation suggest that both the manganese ore and associated rocks were generally deposited under an oxic water column with Post-Archean Australian Shale (PAAS)-normalized REE+Y patterns displaying characteristics of modern seawater (e.g., light REE depletion and negative Ce anomalies). The manganese ore is dominated by fine-grained rhodochrosite (MnCO3), dispersed in Mn-rich silicates (e.g., friedelite and chlorite), and trace quantities of alabandite (MnS) and pyrolusite (MnO2). The replacement of pyrolusite by rhodochrosite suggests that the initial manganese precipitates were Mn(IV)-oxides. Precipitation within an oxic water column is supported by shale-normalized REE+Y patterns from the carbonate ores that are characterized by large positive Ce (>3.0) anomalies, negative Y (~0.7) anomalies, low Y/Ho ratios (~20), and a lack of fractionation between the light and heavy rare earth elements ((Nd/Yb)PAAS ~0.9). The manganese carbonate ores are also 13C-depleted, further suggesting that the Mn(II) carbonates formed as a result of Mn(III/IV)-oxide reduction during burial diagenesis.


Ophiolite belts are found in Tibet along the Zangbo, Banggong and Jinsha River Sutures and in the Anyemaqen mountains, the eastern extension of the Kunlun mountains. Where studied, the Zangbo Suture ophiolites are characterized by: apparently thin crustal sequences (3-3.5 k m ); an abundance of sills and dykes throughout the crustal and uppermost mantle sequences; common intraoceanic melanges and unconformities; and an N-MORB petrological and geochemical composition. The ophiolites probably formed within the main neo-Tethyan ocean and the unusual features may be due to proximity to ridge-transform intersections, rather than to genesis at very slow -spreading ridges as the current consensus suggests. The Banggong Suture ophiolites have a supra-subduction zone petrological and geochemical composition — although at least one locality in the Ado Massif shows MORB characteristics. However, it is also apparent that the dykes and lavas show a regional chemical zonation, from boninites and primitive island arc tholeiites in the south of the ophiolite belt, through normal island arc tholeiites in the central belt to island arc tholeiites transitional to N-MORB in the north. The ophiolites could represent fragments of a fore-arc, island arc, back-arc complex developed above a Jurassic, northward-dipping subduction zone and emplaced in several stages during convergence of the Lhasa and Qiangtang terranes. The ophiolites of the Jinsha River Suture have a N-MORB composition where analysed, but more information is needed for a proper characterization. The Anyemaqen ophiolites, where studied, have a within-plate tholeiite composition and may have originated at a passive margin: it is not, however, certain whether true oceanic lithosphere, as opposed to strongly attenuated continental lithosphere, existed in this region.


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