Nd-Sr Isotopic Study of Magmatic Rocks and 40Ar/39Ar Dating of the Mafic Dike of the Proterozoic Ulan-Sar’dag Ophiolite Mélange (Southern Siberia, East Sayan, Middle Belt, Russia)

We report the first radiogenic Nd-Sr isotope data in the magmatic rocks island-arc ophiolite assemblage from the middle branch of the East Sayan ophiolite complexes to better constrain geodynamic processes in this segment of the CAOB in southern central Siberia. The magmatic rocks belong to the following geochemical types: (1) Ensimatic island-arc boninites; (2) island-arc assemblage; (3) enriched basalts of mid-ocean ridges; and (4) oceanic island-like basalts. The boninites have a positive value εNd (T), which is generated from a depleted mantle source (N-MORB). The island-arc assemblage has negative or slightly positive εNd (T) and was formed from an enriched mantle source due to the subduction of terrigenous rocks. The source of the terrigenous material was most likely the rocks of the Archean TTG (Trondhjemite Tonalite Granodiorite) complex of the Gargan block. Isotopic ratios for E-MOR and OIB-like basalts are characterized by positive or slightly negative values of εNd (T). The mafic dike, which crosscut ophiolite rocks, corresponds to OIB-like basalts. The values of εNd (T), measured 87Sr/86Sr and I (Sr), in the mafic dike correspond to the EM I mantle source. The E-MOR and OIB-like basalts appear to be formed in late-stage asthenospheric mantle melting via the decompression melting processes. The obtained isotope geochemical data for the E-MOR and OIB-like basalts probably indicate the mixing of island-arc melts with asthenospheric melts. We undertook 40Ar/39Ar dating of the mafic dike, which crosscut the ophiolite unit. The mafic dike has a whole-rock 40Ar/39Ar weighted mean plateau age of 799 ± 11 Ma. The dating constrains the minimum age of the ophiolite and island-arc magmatism in the region.

Submarine volcanic activity and giant amygdale formation along the Panama island arc as a precursor to 6000-year-old agate exploitation on Pedro González Island

An extensive deposit of agate occurs in Pedro González Island in the Gulf of Panama. Previous archaeological research showed that the agate was exploited between 6200 and 5600 cal BP to make stone tools found at the oldest known Preceramic human settlement in the Pearl Island archipelago. We constrain here the origin and geological context of the agate through a geological and geochemical study of the island. We show that it includes primary volcanic breccias, lavas, and tuffaceous marine deposits with sedimentary conglomerates and debris flow deposits, which we define as the Pedro González Formation. This formation records submarine to subaerial volcanic activity along an island arc during the Oligo-Miocene, confirming previous regional models that favour progressive emergence of the isthmus in the early Miocene. The igneous rocks have an extreme tholeiitic character that is interpreted to reflect magmatic cessation in eastern Panama during the early Miocene. The agate is hosted in andesitic lavas in unusually large amygdales up to 20–40 cm in diameter, as well as small amygdales (0.1–1.0 cm) in a bimodal distribution, and in veins. The large size of the agates made them suitable for tool manufacture. Field evidence suggests that the formation of large amygdales resulted from subaqueous lava–sediment interaction, in which water released from unconsolidated tuffaceous deposits at the base of lava flows rose through the lavas, coalesced, and accumulated below the chilled lava top, with subsequent hydrothermal mineralization. These amygdales could therefore be regarded as an unusual result of combined peperitic and hydrothermal processes.

Petrology and geochemistry of metapelites from Asenitsa unit, Central Rhodope massif

Asenitsa unit metapelites (Central Rhodope massif) have a high variability in mineral, bulk chemical and trace element composition. Kyanite, staurolite and garnet are the major minerals in schists and show intensive retrograde change. Discrimination diagrams based on immobile trace elements indicate continental island arc or active margin setting of deposition.

Mineralogy, Fluid Inclusions, and Isotopic Study of the Kargah Cu-Pb Polymetallic Vein-Type Deposit, Kohistan Island Arc, Northern Pakistan: Implication for Ore Genesis

The Kargah Cu-Pb polymetallic deposit is a newly discovered ore deposit from the Gilgit-Baltistan region, located in the Kohistan Island Arc, northern Pakistan. However, this area is poorly researched on the ore genesis, and its origin and the evolution of its magmatic-hydrothermal system remain unclear. Three stages of mineralization were identified, including quartz-pyrite, quartz-sulfide, and carbonate representing early, middle, and late stages, respectively. The major ore minerals are pyrite, chalcopyrite, galena, and zincian tetrahedrite with minor native silver, and native gold mainly distributed in pyrite. Here, we present a systematic study on ore geology, hydrothermal alterations, trace element composition of pyrite, fluid inclusions, and isotopes (S and Pb) characteristics to gain insights into the nature of the ore-forming fluids, types of unknown deposits, and hydrothermal fluid evolution. The high Co/Ni ratio (1.3–16.4) and Co content (average 1201 ppm), the low Mo/Ni ratio (0.43–0.94) and Mo contents (average 108 ppm) of both Py-I and Py-II suggest a mafic source for the mineralization. The Au-Ni plots, Co-As-Ni correlation, and the δ34S values range from −2.8 to 6.4‰ (average of 3.4‰) indicating the affiliation of the mineralization with a mantle-derived magmatic-hydrothermal provenance. The Pb isotope data showing the narrow variations in 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb values suggest a single lead source from crustal-derived materials. The microthermometry data suggest that the dominant mechanisms are fluid boiling and mixing for mineral precipitation at temperatures ranging between 155 and 555 °C, and represent an intrusion-related magmatic-hydrothermal environment for the Kargah Cu-Pb polymetallic deposit.

Cr - spinel and clinopyroxene compositions from metagabbro of Nui Ngoc complex in Tam Ky area: evidence of island - arc magma

The hornblende and biotite - bearing metagabbro of the Nui Ngoc complex were exposed into a few small blocks in the southwest Tam Ky city and were viewed as parts of the Tam Ky - Phuoc Son ophiolitic complex (TPO). These rocks were undergone mylonitic deformation and metamorphism. The rocks consist mainly of orthopyroxene, clinopyroxene, plagioclase, olivine, hornblende, biotite and very few microscopic Cr - spinel. The clinopyroxene and Cr - spinel minerals were analyzed for their composition by EPMA, the results showed that: (1) The clinopyroxenes have low Al2O3 (3,2÷3,5 wt %), TiO2 (0,70÷0,82 wt %) contents and (2) the Cr - spinels have low TiO2 (0,23÷0,58 wt %) content and Mg#100* (Mg/ (Mg+Fe2+)) (32÷42) but has medium Cr# (Cr/ (Cr+Al)) (45÷52).These features are similar to those of rocks formed in anoceanic - oceanicsubduction zone that was reported for the plagiogranite of Dieng Bong complex nearby. This study results combined with previous research results in the Tam Ky - Phuoc Son suture zone show the existence of island arc, continental arc, and MOR - magmatic types.

Short-lived intra-oceanic arc-trench system in the North Qaidam belt (NW China) reveals complex evolution of the Proto-Tethyan Ocean

Recognition of any intra-oceanic arc-trench system (IOAS) could provide invaluable information on the tectonic framework and geodynamic evolution of the vanished ocean basin. The Tanjianshan Complex and mafic-ultramafic rocks along the North Qaidam ultra-high pressure metamorphic belt in NW China record the subduction process of the Proto-Tethyan Ocean. Four lithotectonic units, including island arc, ophiolite, forearc basin, and accretionary complex, are recognized based on detailed field investigation. They rest on the northern margin of the Qaidam block and occur as allochthons in fault contact with underlying high-grade metamorphic rocks. The ophiolite unit mainly consists of ultramafic rocks, 527−506 Ma gabbro, 515−506 Ma plagiogranite, dolerite, and massive lava. High-Cr spinels in serpentinite, dolerite with forearc basalt affinity, and boninitic lava collectively indicate a forearc setting. The accretionary complex, exposed to the south of the ophiolite complex and island arc, is highly disrupted and contains repeated slices of basalt, 495−486 Ma tuff, chert, limestone, and mélange. Tuffs with positive zircon εHf(t) values indicate derivation from a nearby juvenile island arc. These lithotectonic units, as well as the back-arc basin, are interpreted to constitute a Cambrian IOAS that formed during the northward subduction of the Proto-Tethyan Ocean. Combined with regional geology, we propose a new geodynamic model involving short-lived Mariana-type subduction and prolonged Andean-type subduction to account for the complex evolution of the Proto-Tethyan Ocean. The reconstruction of a relatively complete IOAS from the North Qaidam belt not only reveals a systematic evolution of intra-oceanic subduction but also advances our understanding of the subduction and accretion history of the Proto-Tethyan Ocean.