Eocene animal trace fossils in 1.7-billion-year-old metaquartzites

The Paleoproterozoic (1.7 Ga [billion years ago]) metasedimentary rocks of the Mount Barren Group in southwestern Australia contain burrows indistinguishable from ichnogenera Thalassinoides, Ophiomorpha, Teichichnus, and Taenidium, known from firmgrounds and softgrounds. The metamorphic fabric in the host rock is largely retained, and because the most resilient rocks in the sequence, the metaquartzites, are too hard for animal burrowing, the trace fossils have been interpreted as predating the last metamorphic event in the region. Since this event is dated at 1.2 Ga, this would bestow advanced animals an anomalously early age. We have studied the field relationships, petrographic fabric, and geochronology of the rocks and demonstrate that the burrowing took place during an Eocene transgression over a weathered regolith. At this time, the metaquartzites of the inundated surface had been weathered to friable sandstones or loose sands (arenized), allowing for animal burrowing. Subsequent to this event, there was a resilicification of the quartzites, filling the pore space with syntaxial quartz cement forming silcretes. Where the sand grains had not been dislocated during weathering, the metamorphic fabric was seemingly restored, and the rocks again assumed the appearance of hard metaquartzites impenetrable to animal burrowing.

Progressive Low-Grade Metamorphism Reconstructed from the Raman Spectroscopy of Carbonaceous Material and an EBSD Analysis of Quartz in the Sanbagawa Metamorphic Event, Central Japan

Low-grade metamorphic temperature conditions associated with the Sanbagawa metamorphic event were estimated by the Raman spectroscopy of carbonaceous material (RSCM) in pelitic rocks and an electron backscatter diffraction (EBSD) analysis of the quartz in siliceous rocks. Analytical samples were collected from the Sanbagawa metamorphic complex, the Mikabu greenstones, and the Chichibu accretionary complex in the eastern Kanto Mountains, central Japan. Previously, low-grade Sanbagawa metamorphism was only broadly recognized as pumpellyite–actinolite facies assigned to the chlorite zone. The RSCM results indicate metamorphic temperatures of 358 °C and 368 °C for the chlorite zone and 387 °C for the garnet zone of the Sanbagawa metamorphic complex, 315 °C for the Mikabu greenstones, and 234–266 °C for the Chichibu accretionary complex. From the EBSD analyses, the diameter of the quartz grains calculated by the root mean square (RMS) approximation ranges from 55.9 to 69.0 μm for the Sanbagawa metamorphic complex, 9.5 to 23.5 μm for the Mikabu greenstones, and 2.9 to 7.3 μm for the Chichibu accretionary complex. The opening angles of the c-axis fabric approximate 40–50°, presenting temperatures of 324–393 °C for the Sanbagawa metamorphic complex and the Mikabu greenstones. The temperature conditions show a continuous increase with no apparent gaps from these low-grade metamorphosed rocks. In addition, there exists an empirical exponential relationship between the estimated metamorphic temperatures and the RMS values of the quartz grains. In this study, integrated analyses of multiple rock types provided valuable information on progressive low-grade metamorphism and a similar approach may be applied to study other metamorphic complexes.

Refining the Paleoproterozoic tectonothermal history of the Penokean Orogen: New U-Pb age constraints from the Pembine-Wausau terrane, Wisconsin, USA

An enduring problem in the assembly of Laurentia is uncertainty about the nature and timing of magmatism, deformation, and metamorphism in the Paleoproterozoic Wisconsin magmatic terranes, which have been variously interpreted as an intra-oceanic arc, foredeep or continental back-arc. Resolving these competing models is difficult due in part to a lack of a robust time-frame for magmatism in the terranes. The northeast part of the terranes in northern Wisconsin (USA) comprise mafic and felsic volcanic rocks and syn-volcanic granites thought to have been emplaced and metamorphosed during the 1890−1830 Ma Penokean orogeny. New in situ U-Pb geochronology of igneous zircon from the volcanic rocks (Beecher Formation), and from two tonalitic plutons (the Dunbar Gneiss and Newingham Tonalite) intruding the volcanic rocks, yielded crystallization ages ranging from 1847 ± 10 Ma to 1842 ± 7 Ma (95% confidence). Thus, these rocks record a magmatic episode that is synchronous with bimodal volcanism in the Wausau domain and Marshfield terrane farther south. Our results, integrated with published data into a time-space diagram, highlight two bimodal magmatic cycles, the first at 1890−1860 Ma and the second at 1845−1830 Ma, developed on extended crust of the Superior Craton. The magmatic episodes are broadly synchronous with volcanogenic massive sulfide mineralization and deposition of Lake Superior banded iron formations. Our data and interpretation are consistent with the Penokean orogeny marking west Pacific-style accretionary orogenesis involving lithospheric extension of the continental margin, punctuated by transient crustal shortening that was accommodated by folding and thrusting of the arc-back-arc system. The model explains the shared magmatic history of the Pembine-Wausau and Marshfield terranes. Our study also reveals an overprinting metamorphic event recorded by reset zircon and new monazite growth dated at 1775 ± 10 Ma suggesting that the main metamorphic event in the terranes is related to the Yavapai-interval accretion rather than the Penokean orogeny.

Zircon U–Pb Dating and Lu-Hf Isotope of the Retrograded Eclogite from Chicheng, Northern Hebei Province, China

We report zircon U–Pb ages and Lu-Hf isotopic data from two sample of the retrograded eclogite in the Chicheng area. Two groups of the metamorphic zircons from the Chicheng retrograded eclogite were identified: group one shows characteristics of depletion in LREE and flat in HREE curves and exhibit no significant Eu anomaly, and this may imply that they may form under eclogite facies metamorphic condition; group two is rich in HREE and shows slight negative Eu anomaly indicated that they may form under amphibolite facies metamorphic condition. Zircon Lu-Hf isotopic of εHf from the Chicheng eclogite has larger span range from 6.0 to 18.0, which suggests that the magma of the eclogite protolith may be mixed with partial crustal components. The peak eclogite facies metamorphism of Chicheng eclogite may occur at 348.5–344.2 Ma and its retrograde metamorphism of amphibolite fancies may occur at ca. 325.0 Ma. The Hongqiyingzi Complex may experience multistage metamorphic events mainly including Late Archean (2494–2448 Ma), Late Paleoproterozoic (1900–1734 Ma, peak age = 1824.6 Ma), and Phanerozoic (495–234 Ma, peak age = 323.7 Ma). Thus, the metamorphic event (348.5–325 Ma) of the Chicheng eclogite is in accordance with the Phanerozoic metamorphic event of the Hongqiyingzi Complex. The eclogite facies metamorphic age of the eclogite is in accordance with the metamorphism (granulite facies or amphibolite facies) of its surrounding rocks, which implied that the tectonic subduction and exhumation of the retrograded eclogite may cause the regional metamorphism of garnet biotite plagioclase gneiss.

Zircon U-Pb and Lu-Hf record from the Archean Lewisian Gneiss Complex, NW Scotland

<p>The Lewisian Gneiss Complex (LGC) in NW Scotland, a classic example of Archean lower crust, is mostly composed of deformed and metamorphosed tonalite–trondhjemite–granodiorite (TTG) gneisses, gneissose granite sheets, and subordinate mafic, ultramafic, and metasedimentary lithologies. It has been traditionally subdivided into three regions that are interpreted to record discrete ages and metamorphic histories, and which are separated by crustal-scale shear zones. A smear of concordant U–Pb zircon ages from the granulite-facies central region has been interpreted to record metamorphic resetting of earlier magmatic and granulite facies metamorphic ages during a subsequent high-temperature metamorphic event. Here, we present U–Pb and Hf isotope data collected via laser-ablation split-stream (LASS) analyses of zircon cores from twenty-seven felsic meta-igneous rocks from the northern, southern, and central regions of the LGC, as well as U–Pb data from zircon rims within most of those samples.</p><p>In samples from the northern and southern regions, the crystallization age (i.e., from zircon cores) was calculated from the upper-intercept age, yielding age range of 2.82-2.63 Ga for the northern, and 3.11–2.63 Ga for the southern region. Zircons in these samples generally have thin or no rims, suggesting an absence of a prolonged high-grade (granulite facies) metamorphic event in those regions. In the central region, zircon cores yield U–Pb crystallization ages between ca. 3.0 Ga and 2.7 Ga, while zircon rims define a continuous spread of ages from ca. 2.8 to 2.4 Ga. Overall, the central region exhibits a continuous and overlapping smear of zircon core and rim ages, suggesting a protracted thermal event in which high-ultrahigh temperature conditions were maintained for >200 m.y., and that discrete magmatic and metamorphic ‘events’ are difficult to identify. Nevertheless, an estimation of the crystallization age of each sample is crucial for interpreting their Lu–Hf isotopic signature. Zircon cores from the tonalite–trondhjemite gneisses have broadly chondritic compositions with a range of calculated mean initial εHf of +2.5 to –1.2, potentially reflecting a mixture of juvenile material and reworked crust, with one outlier at εHf<sub>i</sub> = +4.5 perhaps indicating a renewed influx of juvenile magma. Granite gneisses also have near-chondritic values, although the range is larger and the two youngest granite gneisses have slightly sub-chondritic εHf<sub>i</sub> (–1.5 and –2.5), which indicates that pre-existing crust was involved in their formation. Since there is no significant difference in the Hf isotopic composition between rocks from the three regions, or between the TTG and granite gneisses, we suggest that the broadly chondritic εHf<sub>i</sub> in most of our samples reflects mixing of both depleted mantle and evolved crust during their generation. Despite the similarity of the U-Pb and εHf data from the three regions, the data do not allow to unambiguously discriminate whether the LGC is composed of different levels of a once continuous Archean continent or discrete microcontinents that were amalgamated in the late Archean to Paleoproterozoic.</p>

Unraveling potential biases in U-Pb detrital zircon record induced by high-temperature metamorphism (> 850 ºC)

<p>Detrital zircon records are prone to several sources of bias that can compromise sediment provenance investigations based on U-Pb ages. High-temperature metamorphism (>850 ºC) is herewith addressed as a natural cause of bias since U-Pb zircon data from rocks submitted to these extreme, often prolonged conditions, frequently display protracted apparent concordant geochronological U-Pb records. The resulting spectrum can originate from disturbance of the primary U-Pb zircon system, likewise from subsequent recrystallization and crystallization processes during multiple and/or prolonged metamorphic events. Consequently, a high-grade metamorphosed igneous rock can exhibit a zircon age spectrum similar to that produced by polymict sedimentary rocks, thereby inducing provenance misinterpretations if this rock becomes a source for a sediment. A polymict sedimentary source that undergoes such high temperatures could potentially generate an even more intricate spectrum. Archean, Neoproterozoic and Paleozoic metamorphic rocks from the literature, dated by different techniques (SIMS and LA-ICP-MS), are employed as examples to demonstrate the resulting complications.  The compilation shows that (1) high-temperature metamorphism may generate age peaks of unclear or lacking geological meaning, and (2) the interpretation of detrital zircon age spectra depends on the timing of the metamorphic event (pre- or post-depositional). When high-temperature metamorphic rocks are eroded in uplifted areas, the youngest population of a detrital spectrum represents the maximum depositional age through metamorphic zircon from the source. If a sedimentary succession was subjected to high-temperature metamorphic conditions after deposition, its youngest zircon population more likely records the metamorphism, and the maximum depositional age, as well as older sources cannot be directly accessed. To evaluate the presence of high-temperature metamorphism-related bias in a given detrital zircon sample, we suggest a workflow for data acquisition and interpretation, combining a multi-proxy approach with: in situ U-Pb dating coupled with Hf analyses to retrieve the isotopic composition of the sources, and the integration of a petrochronological investigation to typify fingerprints of the (ultra)high-temperature metamorphic event.</p>