In situ observation of crystal growth in a basalt melt and the development of crystal size distribution in igneous rocks

Author(s):  
Huaiwei Ni ◽  
Hans Keppler ◽  
Nicolas Walte ◽  
Federica Schiavi ◽  
Yang Chen ◽  
...  
2017 ◽  
Vol 50 (4) ◽  
pp. 1021-1027 ◽  
Author(s):  
Christo N. Nanev

Nucleation, nucleus number densities, and the respective supersaturation dependence, crystal growth and Ostwald ripening are reconsidered from the energetics perspective. Supersaturation-dependent critical nucleus sizes are calculated accordingly. It is argued that the logistic time-dependent nucleation resembles one period of a harmonic oscillation. The general conclusion is that a crystallizing system adapts to the distorting influence of the supersaturation imposed, and during crystal nucleation and growth, the system gradually consumes this supersaturation to reach a new equilibrium state at the end of Ostwald ripening (completely exhausted supersaturation). This is an indication that the system responds to the change in its energetic status according to the well known Le Châtelier–Braun principle. The extent to which the nucleation process affects the crystal size distribution (CSD) is also discussed. Slightly altered by the crystal growth, the CSD also preserves some trace of the nucleation stage shape during Ostwald ripening.


CrystEngComm ◽  
2021 ◽  
Author(s):  
Nicholas Mozdzierz ◽  
Moo Sun Hong ◽  
Yongkyu Lee ◽  
Moritz Benisch ◽  
Mo Jiang ◽  
...  

Accompanied with the growth of the biopharmaceuticals market has been an interest in developing processes with increased control of product quality attributes at low manufacturing cost, with one of the...


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