Electrostatic effects on the kinetics of photoinduced electron-transfer reactions of the triplet state of zinc cytochrome c with wild-type and mutant forms of Pseudomonas aeruginosa azurin

1999 ◽  
Vol 4 (1) ◽  
pp. 111-121 ◽  
Author(s):  
Ekaterina V. Sokerina ◽  
G. Matthias Ullmann ◽  
Gertie van Pouderoyen ◽  
Gerard W. Canters ◽  
N. M. Kostić
Author(s):  
Nadir Ana Wiederkehr

Electron transfer reactions involving a series of N-alkyl-dihydronicotinamides (R-NAH) as donors were studied in homogenous solvents and in micellar media. In particular, the redox chemistry and kinetics of the reduction of methylene blue and cytochrome-C, by varying the alkyl chain length (R = C4, C8, C12) were investigated The schemes proposed for functionalized surfactants of nicotinamide suggest photochemical conversion based on light-induced electron-transfer reactions.


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