Redox reactions of heme-containing metalloproteins: dynamic effects of self-assembled monolayers on thermodynamics and kinetics of cytochrome c electron-transfer reactions

2000 ◽  
Vol 209 (1) ◽  
pp. 263-331 ◽  
Author(s):  
Milan Fedurco
Keyword(s):  
Electron Transfer ◽  
Cytochrome C ◽  
Redox Reactions ◽  
Transfer Reactions ◽  
Self Assembled Monolayers ◽  
Dynamic Effects ◽  
Electron Transfer Reactions ◽  
Thermodynamics And Kinetics ◽  
Assembled Monolayers ◽  
Kinetics Of

scholarly journals REDOX REACTIONS INVOLVING N-ALKYL-DIHYDRONICOTINAMIDES

1994 ◽  
Vol 2 (2) ◽  
pp. 121-135
Author(s):  
Nadir Ana Wiederkehr
Keyword(s):  
Methylene Blue ◽  
Electron Transfer ◽  
Cytochrome C ◽  
Redox Reactions ◽  
Alkyl Chain ◽  
Alkyl Chain Length ◽  
Transfer Reactions ◽  
Micellar Media ◽  
Electron Transfer Reactions ◽  
Kinetics Of

Electron transfer reactions involving a series of N-alkyl-dihydronicotinamides (R-NAH) as donors were studied in homogenous solvents and in micellar media. In particular, the redox chemistry and kinetics of the reduction of methylene blue and cytochrome-C, by varying the alkyl chain length (R = C4, C8, C12) were investigated The schemes proposed for functionalized surfactants of nicotinamide suggest photochemical conversion based on light-induced electron-transfer reactions.

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