ChemInform Abstract: Redox Reactions of Heme-Containing Metalloproteins: Dynamic Effects of Self-Assembled Monolayers on Thermodynamics and Kinetics of Cytochrome c Electron-Transfer Reactions

ChemInform ◽  
2001 ◽  
Vol 32 (4) ◽  
pp. no-no
Author(s):  
Milan Fedurco
Author(s):  
Nadir Ana Wiederkehr

Electron transfer reactions involving a series of N-alkyl-dihydronicotinamides (R-NAH) as donors were studied in homogenous solvents and in micellar media. In particular, the redox chemistry and kinetics of the reduction of methylene blue and cytochrome-C, by varying the alkyl chain length (R = C4, C8, C12) were investigated The schemes proposed for functionalized surfactants of nicotinamide suggest photochemical conversion based on light-induced electron-transfer reactions.


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