Alcohol Synthesis via Fischer–Tropsch Synthesis over Activated Carbon Supported Alkaline Earth Modified Cobalt Catalyst

2021 ◽  
Author(s):  
Hong Du ◽  
Miao Jiang ◽  
Ziang Zhao ◽  
Yihui Li ◽  
Tao Liu ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Alkaline Earth ◽  
Cobalt Catalyst ◽  
Tropsch Synthesis ◽  
Fischer Tropsch ◽  
Fischer Tropsch Synthesis ◽  
Alcohol Synthesis

scholarly journals Fischer–Tropsch Synthesis: Study of Different Carbon Materials as Cobalt Catalyst Support

Reactions ◽  
2021 ◽  
Vol 2 (1) ◽  
pp. 43-61
Author(s):  
Mingsheng Luo ◽  
Shuo Li ◽  
Zuoxing Di ◽  
He Li ◽  
Qinglong Liu ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Activated Carbon ◽  
Carbon Nanotube ◽  
Cobalt Catalyst ◽  
Carbon Materials ◽  
Carbon Nanofiber ◽  
Tropsch Synthesis ◽  
Fischer Tropsch ◽  
Fischer Tropsch Synthesis ◽  
Reduced Graphene

In this work, cobalt Fischer–Tropsch synthesis (FTS) catalyst supported on various carbon materials, i.e., carbon nanotube (CNT), activated carbon (AC), graphene oxide (GO), reduced graphene oxide (rGO), and carbon nanofiber (CNF), were prepared via impregnation method. Based on TGA, nitrogen physisorption, XRD, Raman spectroscopy, H2-TPR, NH3-TPD, ICP, SEM, and TEM characterization, it is confirmed that Co3O4 particles are dispersed uniformly on the supports of carbon nanotube, activated carbon and carbon nanofiber. Furthermore, the FT catalyst performance for as-prepared catalysts was evaluated in a fixed-bed reactor under the condition of H2:CO = 2:1, 5 SL·h−1·g−1, 2.5 MPa, and 210 °C. Interestingly, the defined three types of carbon materials exhibit superior performance and dispersion compared with graphene oxide and reduced graphene oxide. The thermal stability and pore structure of the five carbon materials vary markedly, and H2-TPR result shows that the metal–support interaction is in the order of Co/GO > Co/CNT > Co/AC > Co/CNF > Co/rGO. In brief, the carbon nanofiber-supported cobalt catalyst showed the best dispersion, the highest CO conversion, and the lowest gas product but the highest heavy hydrocarbons (C5+) selectivity, which can be attributed to the intrinsic property of CNF material that can affect the catalytic performance in a complicated way. This work will open up a new gateway for cobalt support catalysts on various carbon-based materials for Fischer–Tropsch Synthesis.

Effect of addition of zeolite to iron-based activated-carbon-supported catalyst for Fischer–Tropsch synthesis in separate beds and mixed beds

2012 ◽  
Vol 198 (1) ◽  
pp. 280-288 ◽  
Author(s):  
Avinashkumar V. Karre ◽  
Alaa Kababji ◽  
Edwin L. Kugler ◽  
Dady B. Dadyburjor
Keyword(s):  
Activated Carbon ◽  
Supported Catalyst ◽  
Tropsch Synthesis ◽  
Fischer Tropsch ◽  
Fischer Tropsch Synthesis ◽  
Iron Based

High thermal conductive core-shell structured Al 2 O 3 @Al composite supported cobalt catalyst for Fischer-Tropsch synthesis

2016 ◽  
Vol 527 ◽  
pp. 60-71 ◽  
Author(s):  
Da Wang ◽  
Congbiao Chen ◽  
Jungang Wang ◽  
Litao Jia ◽  
Bo Hou ◽  
...  
Keyword(s):  
Cobalt Catalyst ◽  
Tropsch Synthesis ◽  
Core Shell ◽  
Fischer Tropsch ◽  
Fischer Tropsch Synthesis ◽  
Al Composite

Bifunctional cobalt catalyst for the Fischer – Tropsch synthesis of low-freezing diesel fuel – from development to implementation: Part 1. Selection of a commercial sample of the HZSM-5 zeolite component

2021 ◽  
Vol 1 (1-2) ◽  
pp. 30-40
Author(s):  
R. E. Yakovenko ◽  
I. N. Zubkov ◽  
V. G. Bakun ◽  
M. R. Agliullin ◽  
A. N. Saliev ◽  
...  
Keyword(s):  
Diesel Fuel ◽  
Cobalt Catalyst ◽  
Hydrocarbon Composition ◽  
Tropsch Synthesis ◽  
Practical Implementation ◽  
Fischer Tropsch ◽  
Commercial Sample ◽  
Zeolite Sample ◽  
Fischer Tropsch Synthesis ◽  
Composite Mixture

The effect of the quality of various domestic commercial HZSM-5 zeolites on the properties of bifunctional cobalt catalyst represented by a composite mixture was studied in the Fischer – Tropsch synthesis. Activities and selectivities of the catalyst samples were compared. The fractional and hydrocarbon composition of the synthesis products was investigated; viscosity-temperature characteristics of the diesel fuel fraction were estimated. A promising HZSM-5 zeolite sample was selected for practical implementation of the catalytic technology.

Fischer-Tropsch synthesis: Effect of nitric acid pretreatment on graphene-supported cobalt catalyst

2020 ◽  
Vol 599 ◽  
pp. 117608 ◽  
Author(s):  
Mingsheng Luo ◽  
Shuo Li ◽  
Zuoxing Di ◽  
Zhi Yang ◽  
Weichao Chou ◽  
...  
Keyword(s):  
Nitric Acid ◽  
Cobalt Catalyst ◽  
Tropsch Synthesis ◽  
Acid Pretreatment ◽  
Fischer Tropsch ◽  
Fischer Tropsch Synthesis

Fischer–Tropsch synthesis over a novel cobalt catalyst supported on UiO-66

2020 ◽  
Author(s):  
Negin Davoodian ◽  
Ali Nakhaei Pour ◽  
Mohammad Izadyar ◽  
Ali Mohammadi ◽  
Mehdi Vahidi
Keyword(s):  
Cobalt Catalyst ◽  
Tropsch Synthesis ◽  
Fischer Tropsch ◽  
Fischer Tropsch Synthesis
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