scholarly journals A cautionary note on thermal runaway reactions in mixtures of 1-alkyl-3-methylimidazolium ionic liquids and N-methylmorpholine-N-oxide

Cellulose ◽  
2017 ◽  
Vol 24 (5) ◽  
pp. 1927-1932
Author(s):  
Stefan Böhmdorfer ◽  
Takashi Hosoya ◽  
Thomas Röder ◽  
Antje Potthast ◽  
Thomas Rosenau
2016 ◽  
Vol 93 (7) ◽  
pp. 1261-1266 ◽  
Author(s):  
Suguru Kitabayashi ◽  
Masayoshi Nakano ◽  
Kazuyuki Nishikawa ◽  
Nobuyoshi Koga

1986 ◽  
Vol 104 ◽  
pp. 13-29 ◽  
Author(s):  
J.C. Leung ◽  
H.K. Fauske ◽  
H.G. Fisher

2009 ◽  
pp. 6297 ◽  
Author(s):  
R. Vijayaraghavan ◽  
M. Surianarayanan ◽  
V. Armel ◽  
D. R. MacFarlane ◽  
V. P. Sridhar

Vehicles ◽  
2021 ◽  
Vol 3 (3) ◽  
pp. 480-497
Author(s):  
Cagri Un ◽  
Kadir Aydın

With the improvement of lithium-ion battery (LIB) technology, safety is becoming increasingly urgent topic for battery electric vehicles (BEVs). Short circuits, overcharging, high temperatures and overheating can cause thermal runaway reactions and the release of the flammable electrolyte which makes fire suppression very difficult. This study focuses on the mechanism of thermal runaway and fire suppression applications of LIBs. In order to understand this, 10 experiments were carried out. The experiments were divided into as Exp. A and Exp. B. A manual water suppression system was used in Exp. A and an automatic boron-based suppression system (AUT-BOR) was used in Exp. B. LIBs were heated in a controlled manner with a heat source and the effects of thermal runaway and fire suppression were observed. In Exp. A, a large amount of water was required to extinguish the LIB fires. The holes and slits which formed in the LIB after a fire were useful for injecting water. A projectile effect of cylindrical cells was observed in Exp. A. The Exp. B results showed that AUT-BOR mitigates risks effectively and safely. Also, AUT-BOR provides an early fire warning system and spot cooling to prevent thermal runaway reactions while localizing and suppressing the fire. In Exp. B, fire detection and suppression occurred without any explosion.


Materials ◽  
2021 ◽  
Vol 14 (22) ◽  
pp. 6783
Author(s):  
Marita Pigłowska ◽  
Beata Kurc ◽  
Maciej Galiński ◽  
Paweł Fuć ◽  
Michalina Kamińska ◽  
...  

The aspect of safety in electronic devices has turned out to be a huge challenge for the world of science. Thus far, satisfactory power and energy densities, efficiency, and cell capacities have been achieved. Unfortunately, the explosiveness and thermal runaway of the cells prevents them from being used in demanding applications such as electric cars at higher temperatures. The main aim of this review is to highlight different electrolytes used in lithium-ion cells as well as the flammability aspect. In the paper, the authors present liquid inorganic electrolytes, composite polymer–ceramic electrolytes, ionic liquids (IL), polymeric ionic liquids, polymer electrolytes (solvent-free polymer electrolytes (SPEs), gel polymer electrolytes (GPEs), and composite polymer electrolytes (CPEs)), and different flame retardants used to prevent the thermal runaway and combustion of lithium-ion batteries (LIBs). Additionally, various flame tests used for electrolytes in LIBs have been adopted. Aside from a detailed description of the electrolytes consumed in LIBs. Last section in this work discusses hydrogen as a source of fuel cell operation and its practical application as a global trend that supports green chemistry.


2020 ◽  
Vol 56 (79) ◽  
pp. 11819-11822
Author(s):  
R. Vijayaraghavan ◽  
Mega Kar ◽  
N. E. Sivanesh ◽  
V. J. Samuel ◽  
M. Surianarayanan ◽  
...  

Accelerated rate calorimetry has been employed to study the exothermic and thermal runaway behaviour of some aprotic and protic ionic liquids. The aprotic [FSI]− salts are found to be more vulnerable to exothermic decomposition.


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