Facile synthesis of a novel, highly effective, more sustainable and cost-effective cationic bleach activator for cotton: N-[4-(N,N,N)-triethylammoniumchloride-butyryl] caprolactam

A facile synthesis of (±)-heliannuol-D 1, which serves as an allelopathic chemical in nature and a potential lead compound in the search for new herbicides, has been achieved in a linear 11 steps, together with its epimer. The synthesis commenced with 4-methoxy-3-methyl-acetophenone, through the Baeyer-Villiger reaction, lithiation and addition, epoxidation and intramolecular cyclization to give (±)-heliannuol-D (1) and its epimer (1a) in 32.6% overall yield. Our synthetic approach is cost-effective; this will be helpful in applying this kind of compound for the development of a new generation of agrochemicals.

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Polyhedral oligomeric silsesquioxane/polyamide bio-nanocomposite membranes: structure-gas transport properties

RSC Advances ◽

10.1039/c4ra12716a ◽

2015 ◽

Vol 5 (15) ◽

pp. 11272-11283 ◽

Cited By ~ 12

Author(s):

Dhorali Gnanasekaran ◽

A. Shanavas ◽

Walter W. Focke ◽

Rotimi Sadiku

Keyword(s):

Transport Properties ◽

Gas Transport ◽

Polyhedral Oligomeric Silsesquioxane ◽

Cost Effective ◽

Solvent Casting ◽

Nanocomposite Membranes ◽

Casting Method ◽

Facile Synthesis ◽

Gas Transport Properties ◽

Oligomeric Silsesquioxane

Prepared cost-effective and environmentally-friendly POSS/PA by facile synthesis via solvent casting method. Conspectus study and morphology correlation with gas-transport properties. Effective H-bonds of POSS and PA facilitate separation properties.

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Facile synthesis of a polyether-tethered dimeric berberine as a highly effective DNA-cleaving agent in the presence of Cu(ii) ion

MedChemComm ◽

10.1039/c3md00136a ◽

2013 ◽

Vol 4 (10) ◽

pp. 1400 ◽

Cited By ~ 10

Author(s):

Yong-Min Wang ◽

Chun-Qiong Zhou ◽

Jin-Xiang Chen ◽

Yan-Ling Lin ◽

Wei Zeng ◽

...

Keyword(s):

Facile Synthesis ◽

Dna Cleaving ◽

Highly Effective

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S1987 Universal Colorectal Tumor Testing to Identify Families With Lynch Syndrome Could Be Highly Effective and Cost-Effective: Family Participation Holds the Key

Gastroenterology ◽

10.1016/s0016-5085(10)61358-3 ◽

2010 ◽

Vol 138 (5) ◽

pp. S-295

Author(s):

Uri Ladabaum ◽

Grace Wang ◽

Jonathan P. Terdiman ◽

Aime Blanco ◽

Miriam Kuppermann ◽

...

Keyword(s):

Lynch Syndrome ◽

Cost Effective ◽

Colorectal Tumor ◽

Family Participation ◽

Highly Effective

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An Efficient and Facile Synthesis of Novel Triazole C-N Linked Chromone Hybrids

Asian Journal of Chemistry ◽

10.14233/ajchem.2020.22734 ◽

2020 ◽

Vol 32 (7) ◽

pp. 1806-1808

Author(s):

B. Kanakadurga Rao ◽

Y. Jayaprakash Rao

Keyword(s):

Spectral Analysis ◽

Click Chemistry ◽

Low Cost ◽

Cost Effective ◽

Dipolar Cycloaddition ◽

Facile Synthesis ◽

Mass Spectral Analysis ◽

Mass Spectral ◽

Molecular Hybrids

A series of new C3-N1 directly linked chromone/1,2,3-triazole molecular hybrids synthesized by adopting low cost effective CuI catalyzed azide-alkyne 1,3-dipolar cycloaddition (Cu-AAC triazole annulation) from chromone-3-aldehyde via key intermediates 3-azidochromone, synthesized from another intermediate 3-hydroxychromone. These synthetic 1,2,3-triazole embedded chromones are the new addition to the click chemistry family. The structures of final products established by IR, NMR and mass spectral analysis.

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