Hybrid mineral@silsesquioxane particles for water remediation: synthesis, characterization and application as adsorbent of As(V) and other water pollutants

2018 ◽  
Vol 53 (18) ◽  
pp. 12781-12794 ◽  
Author(s):  
Carolina V. Waiman ◽  
Ignacio E. dell’Erba ◽  
Carlos A. Chesta ◽  
María Lorena Gómez
Author(s):  
Michael Arkas ◽  
Ioannis Anastopoulos ◽  
Dimitrios Giannakoudakis ◽  
Ioannis Pashalidis ◽  
Theodora Katsika ◽  
...  

Radially polymerized dendritic compounds are nowadays an established polymer category next to their linear, branched and cross-linked counterparts. Their uncommon tree-like architecture is characterized by adjustable internal cavities and external groups. They are therefore exceptional absorbents and this attainment of high concentrations into their interior renders them ideal reac-tion media. In this framework they are applied in many environmentally benign implementa-tions. One of the most important among them is water purification though pollutant decomposi-tion. Simple and composite catalysts and photo-catalysts containing dendritic polymers and ap-plied in water remediation will be discussed jointly with some unconventional solutions and fu-ture prospects.


2016 ◽  
Vol 44 (2) ◽  
pp. 156-166 ◽  
Author(s):  
Zeinab El-Bouhy ◽  
Rasha Reda ◽  
Asmaa El-Azony

Author(s):  
Agnieszka Kołodziejczak-Radzimska ◽  
Long D. Nghiem ◽  
Teofil Jesionowski

Abstract Purpose of Review Untreated wastewater discharge can significantly and negatively impact the state of the environment. Rapid industrialization and economic development have directly contributed to land and water pollution resulting from the application of many chemicals such as organic dyes, pharmaceuticals, and industrial reagents. The removal of these chemicals before effluent discharge is crucial for environmental protection. This review aims to explore the importance of functionalized materials in the preparation of biocatalytic systems and consider their application in eliminating water pollutants. Recent Findings Wastewater treatment methods can be classified into three groups: (i) chemical (e.g., chemical oxidation and ozonation), (ii) physical (e.g., membrane separation and ion exchange), and (iii) biological processes. Biological treatment is the most widely used method due to its cost-effectiveness and eco-friendliness. In particular, the use of immobilized enzymes has recently become more attractive as a result of scientific progress in advanced material synthesis. The selection of an appropriate support plays an important role in the preparation of such biologically active systems. Recent studies have demonstrated the use of various materials for enzyme immobilization in the purification of water. Summary This review identifies and discusses different biocatalytic systems used in the enzymatic degradation of various water pollutants. Materials functionalized by specific groups can serve as good support matrices for enzyme immobilization, providing chemical and thermal stability to support catalytic reactions. Enzymatic biocatalysis converts the pollutants into simpler products, which are usually less toxic than their parents. Due to immobilization, the enzyme can be used over multiple cycles to reduce the cost of wastewater treatment. Future studies in this field should focus on developing new platforms for enzyme immobilization in order to improve degradation efficiency.


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