In-situ green synthesis of CuO on 3D submicron-porous/solid copper current collectors as excellent supercapacitor electrode material

2019 ◽  
Vol 30 (4) ◽  
pp. 3545-3551
Author(s):  
Xiaohui Su ◽  
Guangwen Feng ◽  
Lin Yu ◽  
Qiong Li ◽  
Huanhua Zhang ◽  
...  
RSC Advances ◽  
2016 ◽  
Vol 6 (50) ◽  
pp. 43959-43963 ◽  
Author(s):  
Bangning Sun ◽  
Xinping He ◽  
Xijin Leng ◽  
Yang Jiang ◽  
Yudong Zhao ◽  
...  

In this study, we report a binder-free in situ approach to synthesize a polyaniline–NiO composite on a nickel foam as a supercapacitor electrode.


2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Yibing Xie

AbstractA PPY/TiO2/PPY jacket nanotube array was fabricated by coating PPY layer on the external and internal surface of a tube wall-separated TiO2 nanotube array. It shows coaxial triple-walled nanotube structure with two PPY nanotube layers sandwiching one TiO2 nanotube layer. PPY/TiO2/PPY reveals much higher current response than TiO2. The theoretical calculation indicates PPY/TiO2/PPY reveals higher density of states and lower band gap, accordingly presenting higher conductivity and electroactivity, which is consistent with the experimental result of a higher current response. The electroactivity is highly enhanced in H2SO4 rather than Na2SO4 electrolyte due to feasible pronation process of PPY in an acidic solution. PPY/TiO2/PPY could conduct the redox reaction in H2SO4 electrolyte which involves the reversible protonation/deprotonation and HSO4− doping/dedoping process and accordingly contributes to Faradaic pseudocapacitance. The specific capacitance is highly enhanced from 1.7 mF cm−2 of TiO2 to 123.4 mF cm−2 of PPY/TiO2/PPY at 0.1 mA cm−2 in H2SO4 electrolyte. The capacitance also declines from 123.4 to 31.7 mF cm−2 when the current density increases from 0.1 to 1 mA cm−2, presenting the rate capacitance retention of 26.7% due to the semiconductivity of TiO2. A PPY/TiO2/PPY jacket nanotube with high charge storage capacitance is regarded as a promising supercapacitor electrode material.


2021 ◽  
Vol 16 (1) ◽  
Author(s):  
Gopal Krishna Gupta ◽  
Pinky Sagar ◽  
Sumit Kumar Pandey ◽  
Monika Srivastava ◽  
A. K. Singh ◽  
...  

AbstractHerein, we demonstrate the fabrication of highly capacitive activated carbon (AC) using a bio-waste Kusha grass (Desmostachya bipinnata), by employing a chemical process followed by activation through KOH. The as-synthesized few-layered activated carbon has been confirmed through X-ray powder diffraction, transmission electron microscopy, and Raman spectroscopy techniques. The chemical environment of the as-prepared sample has been accessed through FTIR and UV–visible spectroscopy. The surface area and porosity of the as-synthesized material have been accessed through the Brunauer–Emmett–Teller method. All the electrochemical measurements have been performed through cyclic voltammetry and galvanometric charging/discharging (GCD) method, but primarily, we focus on GCD due to the accuracy of the technique. Moreover, the as-synthesized AC material shows a maximum specific capacitance as 218 F g−1 in the potential window ranging from − 0.35 to + 0.45 V. Also, the AC exhibits an excellent energy density of ~ 19.3 Wh kg−1 and power density of ~ 277.92 W kg−1, respectively, in the same operating potential window. It has also shown very good capacitance retention capability even after 5000th cycles. The fabricated supercapacitor shows a good energy density and power density, respectively, and good retention in capacitance at remarkably higher charging/discharging rates with excellent cycling stability. Henceforth, bio-waste Kusha grass-derived activated carbon (DP-AC) shows good promise and can be applied in supercapacitor applications due to its outstanding electrochemical properties. Herein, we envision that our results illustrate a simple and innovative approach to synthesize a bio-waste Kusha grass-derived activated carbon (DP-AC) as an emerging supercapacitor electrode material and widen its practical application in electrochemical energy storage fields.


2021 ◽  
Vol 9 (5) ◽  
pp. 2948-2958
Author(s):  
Bing Wang ◽  
Shuo Liu ◽  
Lin Liu ◽  
Wen-Wei Song ◽  
Yue Zhang ◽  
...  

The three-component PCN-224/PEDOT/PMo12 supercapacitor electrode material is designed to offer high area capacitance, good cycle stability and mechanical flexibility.


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