Analysis of Temperature Dependence of Electrical Conductivity in La2NiO4.14 Single Crystal

2005 ◽  
Vol 18 (5-6) ◽  
pp. 749-752 ◽  
Author(s):  
Nathalie Poirot ◽  
François Gervais
2003 ◽  
Vol 68 (7) ◽  
pp. 1233-1242 ◽  
Author(s):  
Orhan Turkoglu ◽  
Mustafa Soylak ◽  
Ibrahim Belenli

Chloro(phenyl)glyoxime, a vicinal dioxime, and its Ni(II), Cu(II) and Co(II) complexes were prepared. XRD patterns of the complexes point to similar crystal structures. IR and elemental analysis data revealed the 1:2 metal-ligand ratio in the complexes. The Co(II) complex is a dihydrate. Temperature dependence of electrical conductivity of the solid ligand and its complexes was measured in the temperature range 25-250 °C; it ranged between 10-14-10-6 Ω-1 cm-1 and increased with rising temperature. The activation energies were between 0.61-0.80 eV. The Co(II) complex has lower electric conductivity than the Ni(II) and Cu(II) complexes. This difference in the conductivity has been attributed to differences in the stability of the complexes.


2015 ◽  
Vol 31 (15) ◽  
pp. 1860-1866 ◽  
Author(s):  
Y. H. Yang ◽  
J. J. Yu ◽  
X. F. Sun ◽  
T. Jin ◽  
H. R. Guan

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